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How organic chemistry can affect perovskite photovoltaics

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Author(s):
Scalon, Lucas ; Vaynzof, Yana ; Nogueira, Ana Flavia ; Oliveira, Caio C.
Total Authors: 4
Document type: Journal article
Source: CELL REPORTS PHYSICAL SCIENCE; v. 4, n. 5, p. 21-pg., 2023-05-17.
Abstract

Perovskite solar cells are a leading contender in the race to become the next commercially viable photovoltaic technology. Over the past decade, significant advancements have been made in the development and understanding of fundamental device physics principles, deposition techniques, compositional engineering, and passivation strategies. These advancements have resulted in improvements to the photovoltaic performance and stability of the devices. In particular, the integration of organic molecules in different layers of the device has played a key role in driving this progress. Organic molecules have been employed in electron and hole extraction layers, as well as in bulk and surface passivation layers. In this perspective, we provide an overview of the opportunities and potential associated with the use of organic molecules in perovskite solar cells. We propose strategies for the design of highly specific molecules with functionalities tailored to the desired application. Additionally, we highlight the use of chiral organic molecules to introduce asymmetry in the perovskite structure, thereby inducing chiroptical activity in the materials. These properties can be particularly appealing for the interface engineering of perovskite solar cells. (AU)

FAPESP's process: 17/11631-2 - CINE: computational materials design based on atomistic simulations, meso-scale, multi-physics, and artificial intelligence for energy applications
Grantee:Juarez Lopes Ferreira da Silva
Support Opportunities: Research Grants - Research Centers in Engineering Program
FAPESP's process: 21/12104-1 - Unveiling the role of chiral organic spacers on the structural, photophysical, and electronic properties of 2D and 2D/3D perovskite structures
Grantee:Lucas Scalon
Support Opportunities: Scholarships abroad - Research Internship - Doctorate (Direct)
FAPESP's process: 18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis
Grantee:Caio Costa Oliveira
Support Opportunities: Research Grants - Young Investigators Grants
FAPESP's process: 18/21401-7 - Multi-User Equipment approved in grant 2017/11631-2: cluster computational de alto desempenho - ENIAC
Grantee:Juarez Lopes Ferreira da Silva
Support Opportunities: Multi-user Equipment Program
FAPESP's process: 20/04406-5 - Perovskite solar cells from easy, cheap and green sources: a synergistic approach for the synthesis of new organic hole transport materials and the use of more environmental-friendly solvents
Grantee:Lucas Scalon
Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
FAPESP's process: 14/25770-6 - New frontiers in cross-coupling reactions promoted by palladium: combining enantioselective catalysis, C-H activations, new materials and in flux reactions aiming at high efficiency and sustainability in synthetic processes
Grantee:Carlos Roque Duarte Correia
Support Opportunities: Research Projects - Thematic Grants