Characterization of alginate hydrogel electrolytes for use in symmetric supercapacitor based on polypyrrole-modified electrodes

Author(s)

Klobukoski, Vanessa ; Riegel-Vidotti, Izabel C. ; Vidotti, Marcio

• Document type: Journal article
• Source: Electrochimica Acta; v. 465, p. 9-pg., 2023-10-10.

Abstract

The use of biopolymers for the preparation of gel polymer electrolytes (GPEs) to construct high-performance energy storage devices contributes to the development of new sustainable materials. Herein, an alginate-based gel electrolyte was used in the construction of a supercapacitor, to aim for an environmentally friendly device. Alginate was crosslinked with calcium ions (ALG-Ca2}) resulting in gels with good mechanical properties and ionic conductivity, suitable for their use as electrolyte and separator for a symmetric supercapacitor, assembled in a coin cell architecture and using polypyrrole as the electrode. The device presented a specific cell capacitance of 39.5 F g-1 at 0.2 A g - 1, and durability of 70.9% after 2000 galvanostatic charge-discharge (GCD) cycles. Based on these properties, three devices were connected in series and demonstrated to be able to light up a 3.0 V LED. The influence of temperature on supercapacitor performance was verified by varying the temperature from 10 to 60 & DEG;C and evaluating the characteristic cyclic voltammograms and GCD profiles. The devices were able to operate in the temperature range of 10 to 60 & DEG;C, with no loss of their capacity properties. (AU)

• FAPESP's process: 14/50867-3 - INCT 2014: National Institute of Science and Technology in Bioanalysis
• Grantee: Marco Aurelio Zezzi Arruda
• Support Opportunities: Research Projects - Thematic Grants