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Development of storage and supplier device of electric power and methodology of dynamic analysis in operation mode

Grant number: 17/19222-4
Support Opportunities:Scholarships in Brazil - Doctorate (Direct)
Effective date (Start): April 01, 2018
Effective date (End): January 31, 2022
Field of knowledge:Engineering - Electrical Engineering
Principal Investigator:Hudson Giovani Zanin
Grantee:Lenon Henrique da Costa
Host Institution: Faculdade de Engenharia Elétrica e de Computação (FEEC). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Associated research grant:14/02163-7 - Development of supercapacitors devices from graphene, carbon nanotubes and diamonds, AP.JP


This project proposes the development of storage device and electric power supplier as well as a methodology to study these devices in situ. The devices of major interest will be the supercapacitors, which have ideal characteristics to complement the batteries when it is desired to carry out fast processes of charge and discharge of electric energy. The capacitance of these devices affects energy and power storage and delivery and this capacitance is proportional to its electrochemically active area, which justifies studies of preparation of highly porous materials for greater storage and supply of energy. It is known that the electrodes are the heart of this type of device and among the most promising materials are the carbon based because they are excellent conductors, chemically active and stable in different electrolytes. Therefore, in this project will be developed these carbon nanomaterials in different alotropias (0D fullerenes, 1D carbon nanotubes, 2D graphene and 3D diamonds) on different types of collectors (Al, Cu, AISI, Nb, etc.). Such materials will undergo processes of functionalization by plasma (oxygen, ammonia, nitrogen etc), consolidating a wide range of electrodes. The characterization study of these materials will be carried out by Raman spectroscopy, Fourier Transform Infrared (FT-IR) spectroscopy, X-ray excited photoelectron spectroscopy (XPS) and transmission microscopy (TEM) (SEM) and atomic force (AFM). The device will be studied considering: (i) the thickness of carbon-based materials deposited on the electrode; (ii) the type of mesoporous membrane; (iii) the type of electrolyte; (iv) and the type of pseudocapacient component to be used. In the latter case, it will be studied how to marry the times between the faradáicos and non-faradáicos processes and the viability of a hybrid device. The device will be consolidated by encapsulating electrodes in different coin cell and pocket (pounch) electrochemical cell formats. For each type of cell there will be a comparative study of different types of electrolytes and the effect of temperature on them. In addition, an electrochemical cell will be developed to be studied under dynamic operating conditions (in situ) by Raman spectroscopy. These studies aim at a better understanding of the process of formation of the double electric layer of supercapacitors and to identify changes of physical-chemical nature in their interfaces during their operation. At the end is expected a very in-depth view on the operation of these devices as well as the consolidation of some types of prototypes for different applications. (AU)

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Scientific publications (6)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
VICENTINI, RAFAEL; NUNES, WILLIAN GONCALVES; COSTA, LENON HENRIQUE; PASCON, ALINE; DA SILVA, LEONARDO MORAIS; BALDAN, MAURICIO; ZANIN, HUDSON. Environmentally Friendly Functionalization of Porous Carbon Electrodes for Aqueous-Based Electrochemical Capacitors. IEEE TRANSACTIONS ON NANOTECHNOLOGY, v. 18, p. 73-82, . (17/19222-4, 14/02163-7, 16/25082-8)
SOARES, DAVI M.; VICENTINI, RAFAEL; PETERLEVITZ, ALFREDO C.; RODELLA, CRISTIANE B.; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Tungsten oxide and carbide composite synthesized by hot filament chemical deposition as electrodes in aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 26, . (17/11958-1, 17/19222-4, 16/25082-8, 14/02163-7, 17/03640-1)
VICENTINI, RAFAEL; NUNES, WILLIAN G.; COSTA, LENON H.; DA SILVA, LEONARDO M.; PASCON, ALINE; JACKSON, PALOMA; DOUBEK, GUSTAVO; ZANIN, HUDSON. Highly stable nickel-aluminum alloy current collectors and highly defective multi-walled carbon nanotubes active material for neutral aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 23, p. 116-127, . (16/25082-8, 14/02163-7, 17/11958-1, 17/19222-4)
NUNES, WILLIAN G.; VICENTINI, RAFAEL; DA SILVA, LEONARDO M.; COSTA, LENON H.; TADEU, THAIS; ZANIN, HUDSON. Surface and Electrochemical Properties of Radially Oriented Multiwalled Carbon Nanotubes Grown on Stainless Steel Mesh. Journal of the Electrochemical Society, v. 165, n. 16, p. A3684-A3696, . (16/25082-8, 14/02163-7, 17/19222-4)
NUNES, WILLIAN G.; DA SILVA, LEONARDO M.; VICENTINI, RAFAEL; FREITAS, BRUNO G. A.; COSTA, LENON H.; PASCON, ALINE M.; ZANIN, HUDSON. Nickel oxide nanoparticles supported onto oriented multi-walled carbon nanotube as electrodes for electrochemical capacitors. Electrochimica Acta, v. 298, p. 468-483, . (17/19222-4, 14/02163-7, 16/25082-8)
COSTA, LENON H.; VICENTINI, RAFAEL; SILVA, TIAGO ALMEIDA; DA SILVA, LEONARDO MORAIS; ZANIN, HUDSON. Identification and quantification of the distributed capacitance and ionic resistance in carbon-based supercapacitors using electrochemical techniques and the analysis of the charge-storage dynamics. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 929, p. 15-pg., . (17/19222-4, 14/02163-7)
Academic Publications
(References retrieved automatically from State of São Paulo Research Institutions)
COSTA, Lenon Henrique da. Desenvolvimento de dispositivo pseudocapacitor a base de carbono e óxidos metálicos e análises em operação utilizando espectroscopia Raman. 2022. Doctoral Thesis - Universidade Estadual de Campinas (UNICAMP). Faculdade de Engenharia Elétrica e de Computação Campinas, SP.

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