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Development of supercapacitors devices from graphene, carbon nanotubes and diamonds

Grant number: 14/02163-7
Support type:Research Grants - Young Investigators Grants
Duration: November 01, 2014 - October 31, 2019
Field of knowledge:Engineering - Electrical Engineering - Electrical Materials
Principal Investigator:Hudson Giovani Zanin
Grantee:Hudson Giovani Zanin
Home Institution: Faculdade de Engenharia Elétrica e de Computação (FEEC). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Assoc. researchers:Alfredo Carlos Peterlevitz ; Anderson de Oliveira Lobo ; Fernanda Roberta Marciano ; Helder Jose Ceragioli
Associated grant(s):15/50093-0 - Brazil and UK collaboration for energy storage and supply, AP.R SPRINT
Associated scholarship(s):18/20756-6 - Pseudocapacitors from metal oxides and activated carbon composites, BP.DR
16/21941-6 - Development of remote soil moisture sensor on Unmanned Aerial Vehicle for irrigated agriculture, BP.DR
17/19222-4 - Development of storage and supplier device of electric power and methodology of dynamic analysis in operation mode, BP.DD
+ associated scholarships 17/03640-1 - Development of prototype of powerful energy storer and supplier, BP.MS
17/03371-0 - Elastic bracelet for energy storage and supply on wearable technology, BP.MS
17/02634-8 - Prototype development of electric bicycle, BP.MS
16/25082-8 - Development of prototype of energy storer and supplier, BP.MS
15/17829-3 - Design and implementation of a HFCVD reactor, BP.IC
15/17764-9 - Synthesis and characterization of graphene by chemical deposition, BP.IC
14/21587-2 - Development of supercapacitors devices from graphene, carbon nanotubes and diamonds, BP.JP - associated scholarships

Abstract

This project aims to create a research group focused on storage and supply of electric energy by developing and applying supercapacitor devices. The interest in this study is due to the fact that such devices can be charged in seconds with energy in order of kWh/kg, providing electrical power in the magnitude of kW/kg, if requested.1,2 This innovation is considered strategic by developed countries, because their advantages are important for various equipment such as hospital, electric vehicles, phones and laptops. 3 Considering this scenario, this project will focus on developing national supercapacitors, however, using graphene, carbon nanotubes and porous diamonds, since cutting-edge research has highlighted them as advantageous for these applications due to their properties. As regards the method, it is known that such materials can be prepared in CVD reactors from the vapour phase, so initially this work proposes the construction of a reactor, which will be used to prepare the desirable materials. The evaluation of supercapacitor, on the other hand, will examine the storage and delivery of electric power through electrochemical processes involving the intercalation and diffusion of lithium ions. 4,5 Finally, the goal will be to develop a national prototype of high performance electrochemical double layer capacitor. Many previous results 5, 6 of this researcher applicant and its collaborative network have opened the door for this election, which if be granted is going to allow the formation of a new Brazilian research group in this area (AU)

Scientific publications (30)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DA SILVA, LEONARDO M.; CESAR, REINALDO; MOREIRA, CASSIO M. R.; SANTOS, JEFERSON H. M.; DE SOUZA, LINDOMAR G.; PIRES, BRUNO MORANDI; VICENTINI, RAFAEL; NUNES, WILLIAN; ZANIN, HUDSON. Reviewing the fundamentals of supercapacitors and the difficulties involving the analysis of the electrochemical findings obtained for porous electrode materials. ENERGY STORAGE MATERIALS, v. 27, p. 555-590, MAY 2020. Web of Science Citations: 0.
NUNES, WILLIAN G.; PIRES, BRUNO M.; DE OLIVEIRA, FRANCISCA E. R.; DE MARQUE, ALINE M. P.; CREMASCO, LETICIA F.; VICENTINI, RAFAEL; DOUBEK, GUSTAVO; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Study of the aging process of nanostructured porous carbon-based electrodes in electrochemical capacitors filled with aqueous or organic electrolytes. JOURNAL OF ENERGY STORAGE, v. 28, APR 2020. Web of Science Citations: 1.
SILVA SOARES, LUIS EDUARDO; NAHORNY, SIDNEI; BRAGA, VIVIAN DE FARIA; MARCIANO, FERNANDA ROBERTA; BHATTACHARJEE, TANMOY T.; LOBO, ANDERSON OLIVEIRA. Raman spectroscopy-multivariate analysis related to morphological surface features on nanomaterials applied for dentin coverage. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v. 228, MAR 5 2020. Web of Science Citations: 0.
CESAR, R.; BRAVO-CASTILLERO, J.; RAMOS, R. R.; PEREIRA, C. A. M.; ZANIN, H.; ROLLO, J. M. D. A. Relating mechanical properties of vertebral trabecular bones to osteoporosis. COMPUTER METHODS IN BIOMECHANICS AND BIOMEDICAL ENGINEERING, DEC 2019. Web of Science Citations: 0.
SOARES, DAVI M.; VICENTINI, RAFAEL; PETERLEVITZ, ALFREDO C.; RODELLA, CRISTIANE B.; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Tungsten oxide and carbide composite synthesized by hot filament chemical deposition as electrodes in aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 26, DEC 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; NUNES, WILLIAN; FREITAS, BRUNO G. A.; DA SILVA, LEONARDO M.; SOARES, DAVI MARCELO; CESAR, REINALDO; RODELLA, CRISTIANE B.; ZANIN, HUDSON. Niobium pentoxide nanoparticles @ multi-walled carbon nanotubes and activated carbon composite material as electrodes for electrochemical capacitors. ENERGY STORAGE MATERIALS, v. 22, p. 311-322, NOV 2019. Web of Science Citations: 0.
ZAMBIANCO, NAIARA ALANA; SILVA, TIAGO ALMEIDA; ZANIN, HUDSON; FATIBELLO-FILHO, ORLANDO; JANEGITZ, BRUNO CAMPOS. Novel electrochemical sensor based on nanodiamonds and manioc starch for detection of diquat in environmental samples. DIAMOND AND RELATED MATERIALS, v. 98, OCT 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; SOARES, DAVI MARCELO; NUNES, WILLIAN; FREITAS, BRUNO; COSTA, LENON; DA SILVA, LEONARDO M.; ZANIN, HUDSON. Core-niobium pentoxide carbon-shell nanoparticles decorating multiwalled carbon nanotubes as electrode for electrochemical capacitors. Journal of Power Sources, v. 434, SEP 15 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; NUNES, WILLIAN G.; COSTA, LENON H.; DA SILVA, LEONARDO M.; PASCON, ALINE; JACKSON, PALOMA; DOUBEK, GUSTAVO; ZANIN, HUDSON. Highly stable nickel-aluminum alloy current collectors and highly defective multi-walled carbon nanotubes active material for neutral aqueous-based electrochemical capacitors. JOURNAL OF ENERGY STORAGE, v. 23, p. 116-127, JUN 2019. Web of Science Citations: 2.
VICENTINI, RAFAEL; DA SILVA, LEONARDO MORAIS; CECILIO JUNIOR, EDSON PEDRO; ALVES, THAYANE ALMEIDA; NUNES, WILLIAN GONCALVES; ZANIN, HUDSON. How to Measure and Calculate Equivalent Series Resistance of Electric Double-Layer Capacitors. Molecules, v. 24, n. 8 APR 2 2019. Web of Science Citations: 1.
NUNES, WILLIAN G.; DA SILVA, LEONARDO M.; VICENTINI, RAFAEL; FREITAS, BRUNO G. A.; COSTA, LENON H.; PASCON, ALINE M.; ZANIN, HUDSON. Nickel oxide nanoparticles supported onto oriented multi-walled carbon nanotube as electrodes for electrochemical capacitors. Electrochimica Acta, v. 298, p. 468-483, MAR 1 2019. Web of Science Citations: 3.
TELES, JOSE J. S.; FARIA, EMANUEL R.; SANTOS, JEFERSON H. M.; DE SOUSA, LINDOMAR G.; FRANCO, DEBORA V.; NUNES, WILLIAN G.; ZANIN, HUDSON; DA SILVA, LEONARDO M. Supercapacitive properties, anomalous diffusion, and porous behavior of nanostructured mixed metal oxides containing Sn, Ru, and Ir. Electrochimica Acta, v. 295, p. 302-315, FEB 1 2019. Web of Science Citations: 0.
VICENTINI, RAFAEL; NUNES, WILLIAN GONCALVES; COSTA, LENON HENRIQUE; PASCON, ALINE; DA SILVA, LEONARDO MORAIS; BALDAN, MAURICIO; ZANIN, HUDSON. Environmentally Friendly Functionalization of Porous Carbon Electrodes for Aqueous-Based Electrochemical Capacitors. IEEE TRANSACTIONS ON NANOTECHNOLOGY, v. 18, p. 73-82, 2019. Web of Science Citations: 1.
NUNES, WILLIAN G.; VICENTINI, RAFAEL; DA SILVA, LEONARDO M.; COSTA, LENON H.; TADEU, THAIS; ZANIN, HUDSON. Surface and Electrochemical Properties of Radially Oriented Multiwalled Carbon Nanotubes Grown on Stainless Steel Mesh. Journal of the Electrochemical Society, v. 165, n. 16, p. A3684-A3696, DEC 1 2018. Web of Science Citations: 2.
VICENTINI, RAFAEL; COSTA, LENON HENRIQUE; NUNES, WILLIAN; BOAS, OTAVIO VILAS; SOARES, DAVI MARCELO; ALVES, THAYANE ALMEIDA; REAL, CARLA; BUENO, CAROLINE; PETERLEVITZ, ALFREDO CARLOS; ZANIN, HUDSON. Direct growth of mesoporous Carbon on aluminum foil for supercapacitors devices. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 29, n. 12, p. 10573-10582, JUN 2018. Web of Science Citations: 6.
DOS SANTOS NETO, ANTNIO GOMES; DE SOUSA, CAMILA SILVA; FREIRES, ANDRE DA SILVA; SILVA, SAIMON MORAES; ZANIN, HUDSON; DAMOS, FLAVIO SANTOS; SILVA LUZ, RITA DE CASSIA. Electrochemical sensor for detection of imipramine antidepressant at low potential based on oxidized carbon nanotubes, ferrocenecarboxylic acid, and cyclodextrin: application in psychotropic drugs and urine samples. Journal of Solid State Electrochemistry, v. 22, n. 5, SI, p. 1385-1394, MAY 2018. Web of Science Citations: 1.
NAHORNY, SIDNEI; ZANIN, HUDSON; CHRISTINO, VINIE ABREU; MARCIANO, FERNANDA ROBERTA; OLIVEIRA LOBO, ANDERSON; SILVA SOARES, LUIS EDUARDO. Multi-walled carbon nanotubes/graphene oxide hybrid and nanohydroxyapatite composite: A novel coating to prevent dentin erosion. Materials Science & Engineering C-Materials for Biological Applications, v. 79, p. 199-208, OCT 1 2017. Web of Science Citations: 10.
FARIAS, JULIANNA SANTOS; ZANIN, HUDSON; CALDAS, ADRIANA SILVA; DOS SANTOS, CLENILTON COSTA; DAMOS, FLAVIO SANTOS; SILVA LUZ, RITA DE CASSIA. Functionalized Multiwalled Carbon Nanotube Electrochemical Sensor for Determination of Anticancer Drug Flutamide. JOURNAL OF ELECTRONIC MATERIALS, v. 46, n. 10, p. 5619-5628, OCT 2017. Web of Science Citations: 9.
SPINDOLA, ROLFF FERREIRA; ZANIN, HUDSON; MACENA, CLEIDIVAN SILVA; CONTIN, ANDRE; SILVA LUZ, RITA DE CASSIA; DAMOS, FLAVIO SANTOS. Evaluation of a novel composite based on functionalized multi-walled carbon nanotube and iron phthalocyanine for electroanalytical determination of isoniazid. Journal of Solid State Electrochemistry, v. 21, n. 4, p. 1089-1099, APR 2017. Web of Science Citations: 8.
SILVA, TIAGO ALMEIDA; ZANIN, HUDSON; CORAT, EVALDO JOSE; FATIBELLO-FILHO, ORLANDO. Simultaneous Voltammetric Determination of Paracetamol, Codeine and Caffeine on Diamond-like Carbon Porous Electrodes. Electroanalysis, v. 29, n. 3, p. 907-916, MAR 2017. Web of Science Citations: 8.
SILVA MOREIRA, JOAO VITOR; MAY, PAUL WILLIAM; CORAT, EVALDO JOSE; PETERLEVITZ, ALFREDO CARLOS; PINHEIRO, ROMARIO ARAUJO; ZANIN, HUDSON. Diamond and Carbon Nanotube Composites for Supercapacitor Devices. Journal of Electronic Materials, v. 46, n. 2, p. 929-935, FEB 2017. Web of Science Citations: 6.
SILVA MOREIRA, JOAO VITOR; CORAT, EVALDO JOSE; MAY, PAUL WILLIAM; RIBEIRO CARDOSO, LAYS DIAS; LELIS, PEDRO ALMEIDA; ZANIN, HUDSON. Freestanding Aligned Multi-walled Carbon Nanotubes for Supercapacitor Devices. Journal of Electronic Materials, v. 45, n. 11, p. 5781-5788, NOV 2016. Web of Science Citations: 13.
PETERLEVITZ, A. C.; MAY, P. W.; HARNIMAN, R. L.; JONES, J. A.; CERAGIOLI, H. J.; ZANIN, H. Fast electron transfer kinetics on novel interconnected nanospheres of graphene layers electrodes. Thin Solid Films, v. 616, p. 698-702, OCT 1 2016. Web of Science Citations: 5.
ZANIN, HUDSON; MANZOLLI RODRIGUES, BRUNO VINICIUS; RIBEIRO NETO, WILSON ALVES; SUMAN BRETAS, ROSARIO ELIDA; DA-SILVA, NEWTON SOARES; MARCIANO, FERNANDA ROBERTA; LOBO, ANDERSON OLIVEIRA. High loading of graphene oxide/multi-walled carbon nanotubes into PDLLA: A route towards the design of osteoconductive, bactericidal and non-immunogenic 3D porous scaffolds. Materials Chemistry and Physics, v. 177, p. 56-66, JUL 1 2016. Web of Science Citations: 4.
SILVA, TIAGO ALMEIDA; ZANIN, HUDSON; VICENTINI, FERNANDO CAMPANHA; CORAT, EVALDO JOSE; FATIBELLO-FILHO, ORLANDO. Electrochemical determination of rosuvastatin calcium in pharmaceutical and human body fluid samples using a composite of vertically aligned carbon nanotubes and graphene oxide as the electrode material. SENSORS AND ACTUATORS B-CHEMICAL, v. 218, p. 51-59, OCT 31 2015. Web of Science Citations: 19.
OLIVEIRA, C. A. G. S.; STEIN, M. F.; SAITO, E.; ZANIN, H.; VIEIRA, L. S.; RANIERO, L.; TRAVA-AIROLDI, V. J.; LOBO, A. O.; MARCIANO, F. R. Effect of gold oxide incorporation on electrochemical corrosion resistance of diamond-like carbon. DIAMOND AND RELATED MATERIALS, v. 53, p. 40-44, MAR 2015. Web of Science Citations: 9.
SIQUEIRA, IDALIA A. W. B.; OLIVEIRA, CILIANA A. G. S.; ZANIN, HUDSON; GRINET, MARCO A. V. M.; GRANATO, ALESSANDRO E. C.; PORCIONATTO, MARIMELIA A.; MARCIANO, FERNANDA R.; LOBO, ANDERSON O. Bioactivity behaviour of nano-hydroxyapatite/freestanding aligned carbon nanotube oxide composite. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, v. 26, n. 2 FEB 2015. Web of Science Citations: 5.
ZANIN, H.; MAY, P. W.; HARNIMAN, R. L.; RISBRIDGER, T.; CORAT, E. J.; FERMIN, D. J. High surface area diamond-like carbon electrodes grown on vertically aligned carbon nanotubes. Carbon, v. 82, p. 288-296, FEB 2015. Web of Science Citations: 13.
ZANIN, H.; CERAGIOLI, H. J.; PETERLEVITZ, A. C.; BARANAUSKAS, VITOR; MARCIANO, F. R.; LOBO, A. O. Field emission properties of the graphenated carbon nanotube electrode. Applied Surface Science, v. 324, p. 174-178, JAN 1 2015. Web of Science Citations: 6.
ZANIN, H.; ROSA, C. M. R.; ELIAZ, N.; MAY, P. W.; MARCIANO, F. R.; LOBO, A. O. Assisted deposition of nano-hydroxyapatite onto exfoliated carbon nanotube oxide scaffolds. NANOSCALE, v. 7, n. 22, p. 10218-10232, 2015. Web of Science Citations: 34.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.