| Full text | |
| Author(s): |
Zukerman-Schpector, Julio
;
Caracelli, Ignez
;
Guadagnin, Rafael Carlos
;
Stefani, Helio A.
;
Tiekink, Edward R. T.
Total Authors: 5
|
| Document type: | Journal article |
| Source: | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS; v. 67, p. 12-pg., 2011-07-01. |
| Abstract | |
The Te-IV atom in the title compound, [Te(C4H9)(C8H10Br)Cl-2] or C12H19BrCl2Te, is in a distorted psi-trigonal-bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)degrees]. Close intramolecular [Te center dot center dot center dot Br = 3.3444 (18) angstrom] and intermolecular [Te center dot center dot center dot Cl = 3.675 (3) angstrom] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C-H center dot center dot center dot Cl. (AU) | |