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Microstructure and Metal-Insulator Transition in Single Crystalline KMo4O6

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Author(s):
Andrade, Margareth ; Maffei, Mariana Lanzoni ; Salgado Alves, Leandro Marcos ; Moreira dos Santos, Carlos Alberto ; Ferreira, Bento ; Sartori, Antonio Fernando
Total Authors: 6
Document type: Journal article
Source: MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS; v. 15, n. 6, p. 5-pg., 2012-11-01.
Abstract

High quality KMo4O6 single crystals with tetragonal structure (space group P4/mbm) have been prepared by fused salt electrolysis. The crystals were studied by scanning electron microscopy (SEM), X-ray diffractometry, electrical resistivity, and magnetization measurements. X-ray powder diffraction patterns and SEM have given some information on the growth of single crystals. Electrical resistivity as a function of temperature shows that the KMo4O6 compound is a bad metal with resistivity change of approximately 30% in the temperature range from 2 to 300K. A metal-insulator transition (MIT), observed at approximately 110K, has been also confirmed for this material. Magnetization as a function of temperature agrees with previous report, however a magnetic ordering has been observed in M(H) curves in the whole temperature range. (AU)

FAPESP's process: 09/54001-2 - Acquisition of cryogen-free equipment for the characterization of magnetic properties by vibrating sample magnetometry
Grantee:Carlos Alberto Moreira dos Santos
Support Opportunities: Multi-user Equipment Program
FAPESP's process: 09/14524-6 - Re-liquefier for using in a 9 t MagLab Oxford
Grantee:Carlos Alberto Moreira dos Santos
Support Opportunities: Regular Research Grants
FAPESP's process: 10/06637-2 - Crystalline structure and physical properties of the anomalous conductor KxMoO2-d
Grantee:Leandro Marcos Salgado Alves
Support Opportunities: Scholarships in Brazil - Doctorate