| Full text | |
| Author(s): |
Ferraz de Paiva, Raphael Enoque
;
Nakahata, Douglas Hideki
;
de Carvalho, Marcos Alberto
;
Goulart Bergamini, Fernando Rodrigues
;
Corbi, Pedro Paulo
Total Authors: 5
|
| Document type: | Journal article |
| Source: | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS; v. 73, p. 14-pg., 2017-10-01. |
| Abstract | |
It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N, N ', N ''-donating imine ligand led to a mononuclear compound, namely dichlorido[N, N-dimethyl-N '-(pyridin-2-ylmethylidene) ethane-1,2-diamine]copper(II) monohydrate, [CuCl2(C10H15N3)]center dot H2O,1, while the N, N ', O-donating imine ligand produced a binuclear metal complex, namely mu(2)-chloridodichlorido(mu(2)-2-{[2-(dimethylamino) ethyl] iminomethyl} phenolato)(N, N-dimethylethylenediamine) dicopper(II) 0.11-hydrate, [Cu-2(C11H15N2O) Cl-3(C4H12N2)] 0.11H(2)O, 2. The structure of 2 is a remarkable example of a binuclear copper(II) complex containing a single substituted 2-iminomethylphenolate ligand that has two copper(II) sites in square-pyramidal coordination. (AU) | |
| FAPESP's process: | 15/20882-3 - Metal complexes of sulfamethoxydiazine and sulfadimethoxine: synthesis, characterization and applications as antimicrobial agents for topical use |
| Grantee: | Douglas Hideki Nakahata |
| Support Opportunities: | Scholarships in Brazil - Doctorate |
| FAPESP's process: | 15/25114-4 - Synthesis of New Ag(I), Cu(II), Pd(II) and Pt(II) complexes based on sulfonamides and derivatives: antibacterial activities and application prospects on skin critically colonized wounds. |
| Grantee: | Pedro Paulo Corbi |
| Support Opportunities: | Regular Research Grants |