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Investigation ofsurface-pegylatednanocellulose as reinforcing agent onPBATbiodegradable nanocomposites

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Author(s):
de Souza, Alana Gabrieli ; de Lima, Giovanni Floriano ; Rangari, Vijaya Kumar ; dos Santos Rosa, Derval
Total Authors: 4
Document type: Journal article
Source: Polymer Composites; v. 41, n. 10, p. 13-pg., 2020-08-06.
Abstract

In the present work, nanocellulose (NC) has been surface-pegylated and further employed as reinforcement in poly(butylene adipate-co-terephthalate) (PBAT) through the melting process. The nanocomposites showed a significant stiffness increase, especially the 2% pegylated-NC, due to the good interaction between the modified NC and the matrix. Also the pegylation improved the filler-PBAT adhesion, which resulted in higher thermal stability and low crystallinity. Raman spectroscopy confirmed the strong interaction between the 2% pegylated-NC, morphological analysis confirmed the filler adhesion. The water absorption indicated that the pegylated-NC has a low tendency to absorb water, which improves its applicability, for example, as a packaging material. This unique study is of great value for the future design of pegylated-NC biodegradable nanocomposites with tailored properties. (AU)

FAPESP's process: 18/25239-0 - Evaluation of dispersion of modified cellulose nanostructures in bionanocomposites
Grantee:Derval dos Santos Rosa
Support Opportunities: Scholarships abroad - Research
FAPESP's process: 18/11277-7 - PBAT films with cellulose nanostructures treated with essential oils encapsulated for active packaging
Grantee:Derval dos Santos Rosa
Support Opportunities: Regular Research Grants