Physical and chemical characteristics of plasma-activated water generated by hybrid dielectric barrier discharge and gliding arc discharge

Author(s)

Neto, Nilton F. Azevedo ; Miranda, Felipe S. ; Moreira Jr, Pedro W. P. ; Gomes, Marcelo P. ; Alves Jr, Clodomiro ; Koga-Ito, Cristiane Y. ; Pessoa, Rodrigo S.

• Document type: Journal article
• Source: JOURNAL OF PHYSICS D-APPLIED PHYSICS; v. 57, n. 41, p. 15-pg., 2024-10-18.

Abstract

This research explores the synergistic application of Dielectric Barrier Discharge (DBD) and Gliding Arc Plasma Jet (GAPJ) in a Hybrid Plasma Discharge (HPD) setup for enhanced water activation. The HPD system demonstrated balanced and sustained generation of reactive oxygen and nitrogen species (RONS), maintaining efficiency at higher specific input energy (SIE) values. Comparative analyses with DBD and GAPJ systems highlighted the superior performance of the HPD system in generating RONS and modifying water's molecular structure. Key observations included a decrease in water's pH and an increase in oxidation-reduction potential, total dissolved solids, and conductivity, stabilizing beyond 5 l min-1 airflow and 10 min of treatment. UV-Vis spectroscopy identified nitrites, nitrates, hydrogen peroxide, and nitrous acid, while Raman spectroscopy captured shifts in vibrational modes, particularly in librational and O-H stretching bands. These changes correlated with alterations in reactive species concentrations and pH levels. Overall, the HPD system emerged as a versatile and efficient approach for generating plasma-activated water, suitable for applications in microbial deactivation, surface sterilization, and electrocatalytic process optimization, offering stable and continuous production of reactive species across a range of SIE values. (AU)

• FAPESP's process: 19/05856-7 - Use of low temperature atmospheric pressure plasma in dentistry: from laboratory bench to clinics
• Grantee: Cristiane Yumi Koga Ito
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 21/14181-3 - Development and study of a plasma system generated by dielectric barrier discharge (DBD) for continuous activation of liquids applied in dental treatments
• Grantee: Felipe de Souza Miranda
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• FAPESP's process: 23/02268-2 - Generation and characterization of different liquids activated with plasma for use in endodontic treatment
• Grantee: Nilton Francelosi Azevedo Neto
• Support Opportunities: Scholarships in Brazil - Post-Doctoral