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Translucent persistent luminescence glass matrix composite obtained by pressureless viscous sintering

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Author(s):
Fernandes, Roger Gomes ; Mattos, Elaine de Andrade ; da Silva, Victor Murilo Poltronieri ; van der Heggen, David ; Smet, Philippe F. ; Manzani, Danilo ; Teixeira, Veronica de Carvalho ; Rodrigues, Lucas Carvalho Veloso
Total Authors: 8
Document type: Journal article
Source: MATERIALIA; v. 38, p. 6-pg., 2024-09-12.
Abstract

Translucent persistent luminescence glass matrix composites (PeL-GMCs) were successfully obtained for the first time using a pressureless viscous sintering method with silicate glass as the host material. Initially, persistent luminescence microparticles (PeL-MPs) of SrAl2O4: Eu2+; Dy3+ were prepared by microwave-assisted synthesis under a reducing atmosphere. To obtain persistent luminescent glass matrix composites, 1 wt. % of these particles were mixed with soda-lime-silicate glass beads and pressed into pellets. Subsequently, the disk-shaped samples were heat-treated through pressureless viscous sintering. Despite some material porosity, the PeL-GMCs exhibited translucency and prolonged persistent luminescence (similar to 12 min). Additionally, we noted excellent compatibility between the PeL-MPs and the glass host, since no chemical interaction was found, as verified by optical microscopy, energy dispersive X-ray (EDX) mapping analysis and cathodoluminescence (CL) in SEM. Furthermore, the afterglow intensity of the particles was maintained after the preparation of materials. (AU)

FAPESP's process: 22/13267-4 - X-ray damage control and Synchrotron advanced characterization of persistent luminescence transparent glass ceramics
Grantee:Roger Gomes Fernandes
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 21/05603-1 - Follow the charge: using advanced optical and X-ray spectroscopy to master charge transfer processes in phosphors
Grantee:Lucas Carvalho Veloso Rodrigues
Support Opportunities: Regular Research Grants
FAPESP's process: 21/08111-2 - Development of rare earth based light converters: luminescent markers, optical sensors, and amplifiers
Grantee:Hermi Felinto de Brito
Support Opportunities: Research Projects - Thematic Grants