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Green, Biodegradable, and Flexible Resistive Heaters-Based Upon a Novel Laser-Induced Graphene Manufacturing Process

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Author(s):
Morais, Rogerio Miranda ; Vieira, Douglas Henrique ; Ozorio, Maiza da Silva ; Nogueira, Gabriel Leonardo ; Rollo, Andrew ; Kettle, Jeff ; Alves, Neri
Total Authors: 7
Document type: Journal article
Source: ADVANCED SUSTAINABLE SYSTEMS; v. 8, n. 10, p. 10-pg., 2024-05-27.
Abstract

Laser induced graphene (LIG), prepared directly with an in situ synthesis method onto Kraft Paper substrates, is proposed for the manufacture of biodegradable electronic devices. The investigation explores the influence of laser power and scanning speed on the properties of LIG conductive tracks and a sheet resistance of up to 0.25 k Omega sq-1. Raman spectroscopy and microscopy is used to analyse the interfacial properties, in particular the transition of cellulose fibers to carbonized graphene flakes through photothermal pyrolysis, leading to the formation of coral-like structures. To demonstrate the applicability of the approach, flexible resistive heaters have been manufactured and tests show rapid heating with a homogeneous distribution and a maximum temperature of 145.5 degrees C. Additionally, an electro-thermal conversion efficiency (hr+c) of 17.05 mW (degrees C cm2)-1 is achieved. Finally, a comparative Life Cycle Assessment with FR-4 based electronics has been undertaken and the environmental impacts are calculated. The impact assessment shows a two magnitude lower impact on the environment for most categories, which suggests the approach is beneficial for the environment at a global production level. The results show that the photothermal pyrolysis of Kraft paper using a laser diode allows for low-impact devices flexible and green electronics products. Laser Induced Graphene (LIG) is formed through Kraft paper pyrolysis, varying power and speed parameters. Achieving low sheet resistance and favorable morphology, the LIG proved suitable for conductive tracks in resistive heater applications. Results highlighted precise temperature control and rapid responses, demonstrating proof of concept with potential for real-world applications. Additionally, life cycle assessment demonstrated significantly reduced environmental impact. image (AU)

FAPESP's process: 20/12282-4 - Development of vertical electrolyte-gated field effect transistors for UV photodetectors
Grantee:Douglas Henrique Vieira
Support Opportunities: Scholarships in Brazil - Doctorate
FAPESP's process: 22/12332-7 - Printed electronic devices for sustainable electronics
Grantee:Neri Alves
Support Opportunities: Regular Research Grants