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Characterization of Lithium-Ion Batteries from Recycling Perspective towards Circular Economy

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Author(s):
Guimaraes, Lucas Fonseca ; Tenorio, Jorge Alberto Soares ; Vaccari, Mentore ; Espinosa, Denise Crocce Romano ; Botelho Junior, Amilton Barbosa
Total Authors: 5
Document type: Journal article
Source: MINERALS; v. 14, n. 9, p. 21-pg., 2024-09-01.
Abstract

Recycling processes of lithium-ion batteries used in electric and hybrid vehicles are widely studied today. To perform such recycling routes, it is necessary to know the composition of these batteries and their components. In this work, three pouch and three cylindrical LIBs were discharged, dismantled, and characterized, having their compositions known and quantified. The dismantling was performed using scissors, pliers, and a precision cutter equipment. The organic liquid electrolyte was quantified via mass loss after it evaporated at 60 degrees C for 24 h. The separators were analyzed using Fourier-transform infrared spectroscopy (FTIR), and the cathode and anode active materials were analyzed using a scanning electronic microscope coupled to an energy-dispersive spectroscope (SEM-EDS), X-ray diffraction (XDR), and energy-dispersive X-ray fluorescence spectrometry (EDXRF). All LIBs were identified by type (NCA, NMC 442, NMC 811, LCO, and two LFP batteries), and a preliminary economic evaluation was conducted to understand their potential economic value (in USD/t). Both results (characterization and preliminary economic evaluation) were considered to discuss the perspective of recycling towards a circular economy for end-of-life LIBs. (AU)

FAPESP's process: 21/14842-0 - Elucidation of the organometallic complexation mechanism between organic extractants and rare earth elements
Grantee:Amilton Barbosa Botelho Junior
Support Opportunities: Scholarships in Brazil - Post-Doctoral
FAPESP's process: 20/00493-0 - Sustainable mining: recovery of critical raw materials from batteries using environmentally friendly technologies
Grantee:Jorge Alberto Soares Tenório
Support Opportunities: Regular Research Grants
FAPESP's process: 19/11866-5 - Development of innovative processes for the recovery of critical metals
Grantee:Denise Crocce Romano Espinosa
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 23/01032-5 - Separation of critical metals through supported liquid membrane: evaluation of synergistic interaction between organophosphorus and membranes
Grantee:Amilton Barbosa Botelho Junior
Support Opportunities: Scholarships abroad - Research Internship - Post-doctor