Synthesis of lithium doped magnesium ferrites and their vibrational and magnetic properties: Correlation of experimental and density functional theory

Author(s):Show less -

Manjunatha, K. ; Angadi, V. Jagadeesha ; Hardi, Sammed Shantinath ; Chiu, Hsin-Hao ; Hsu, Tsu-En ; Wu, Sheng Yun ; Oliveira, Marisa C. ; Longo, Elson ; Ribeiro, Renan A. P. ; Ubaidullah, Mohd ; Al-Kahtani, Abdullah A. ; Sharma, Kuldeep ; Gupta, Manish ; Basavegowda, Nagaraj ; Wang, Shifa ; Sathish, T. ; Manjunatha, S. O. ; Kubrin, S. P.

• Document type: Journal article
• Source: CERAMICS INTERNATIONAL; v. 50, n. 12, p. 11-pg., 2024-05-01.

Abstract

Recently, there has been an increased focus on investigating the possible use of ferrite nanoparticles as magnetic memory devices. In this study, we report on the structural, microstructural, Raman, density functional theory and magnetic characteristics of Mg1-xLixFe2O4 (x = 0, 0.15, 0.3, 0.45, 0.5 and 0.75). Samples were synthesized by solution combustion synthesis method. Samples were subjected to characterize X-ray diffraction (XRD), Scanning electron microscopy (SEM) and Raman Spectra. XRD reveals that all synthesized samples show a single phase formation and unit cell volume, crystallite size varied with an increase in Lithium-ion concentration. SEM micrographs confirmed the porous nature increases with the rise of Li concentration. Particles are agglomeration and spherical type of nature was confirmed by TEM images. Further, Raman Spectra confirms the spinel cubic structure of MgFe2O4 nanoparticles belongs to the Fd3m space group. Despite the fact that the full unit cell has 56 atoms (Z = 8), the smallest Bravais cell consists of only 14 atoms (Z = 2). Consequently, in order to understand this effect, the electronic structure of pure and doped models was investigated through the Band Structure and Density of States (D.O.S.) profiles. First the crystalline structure of pure and Li-doped MgFe2O4 was analyzed based on the optimized lattice parameters and M - O (M = Mg, Li and Fe) bond distances. The band-gap was computed to be 2.54 eV being a direct transition between two points, in an excellent agreement with the experimental measurements. To investigate the temperature dependent magnetic properties, the M - H loops of Li doped MgFe2O4 nanoparticles traced at below and above room temperature over the applied magnetic field +/- 60 kOe. The M - H loops recorded at above and below room temperature demonstrated that the ferromagnetic nature of the sample. Further, the magnetic properties was investigated using temperature dependent FC and ZFC magnetization measurements. Above room temperature, the ZFC and FC curves show irreversibility and split at certain temperatures, as well as a broad maximum in ZFC curves at blocking temperature (T B ). Saturation magnetization (M s ) values are higher at 15 K compared to 300 K, attributed to reduced thermal fluctuation. Our results suggest that synthesized materials are useful for room temperature magnetic memory device application. (AU)

• FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
• Grantee: Elson Longo da Silva
• Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC
• FAPESP's process: 21/01651-1 - CDMF - Functional Materials Development Center: theoretical study of multifunctional materials with potential antiviral application
• Grantee: Marisa Carvalho de Oliveira
• Support Opportunities: Scholarships in Brazil - Post-Doctoral