| Full text | |
| Author(s): Show less - |
Lyonnet, Julien R.
;
Velasco-Rubio, Alvaro
;
Abrams, Roman
;
Phan, Ha
;
Muhlfenzl, Kim
;
Chen, Xuemeng
;
Cerveri, Alessandro
;
Correia, Jose TiagoM.
;
Paixao, Marcio W.
;
Elmore, Charles S.
;
Martin, Ruben
Total Authors: 11
|
| Document type: | Journal article |
| Source: | ACS CATALYSIS; v. 14, n. 24, p. 6-pg., 2024-12-06. |
| Abstract | |
Herein, we describe a photoinduced multicomponent catalytic carboxylation protocol that streamlines the access to 13C-labeled carboxylic acids from simple olefin precursors, sulfinate salts and 13CO2. Site selectivity is dictated by the radical philicity of the starting precursors and reaction intermediates, resulting in either a four-component or a five-component endeavor. The method is characterized by its simplicity and flexibility across a wide number of coupling counterparts (AU) | |
| FAPESP's process: | 19/01560-6 - Nickel-catalyzed intermolecular dicarbofunctionalization of unactivated alkenes, employing CO2 and radical precursors |
| Grantee: | José Tiago Menezes Correia |
| Support Opportunities: | Scholarships abroad - Research Internship - Post-doctor |