| Full text | |
| Author(s): |
Cariello, Guilherme
;
Gallo, Rafael D. C.
;
Deflon, Victor M.
;
Cormanich, Rodrigo A.
;
Jurberg, Igor D.
Total Authors: 5
|
| Document type: | Journal article |
| Source: | CHEMICAL COMMUNICATIONS; v. 61, n. 10, p. 5-pg., 2024-12-03. |
| Abstract | |
A reaction sequence of visible light-mediated cyclopropanation/acid-promoted ring-opening is described for the formal alkylation of silyl enol ethers with aryldiazoacetates. Under the same conditions, the Danishefsky's diene can react with aryldiazoacetates to afford [4+1]-cycloaddition adducts. Key mechanistic aspects are proposed based on experimental evidence and DFT calculations. (AU) | |
| FAPESP's process: | 22/01104-3 - Photochemistry with visible light aiming at the mild formation of carbenes and nitrenes as versatile intermediates for the functionalization of organic molecules |
| Grantee: | Igor Dias Jurberg |
| Support Opportunities: | Regular Research Grants |
| FAPESP's process: | 22/16188-8 - Computational and experimental studies of hydrogen bonding involving organic F atoms as acceptors |
| Grantee: | Guilherme Cariello Silva |
| Support Opportunities: | Scholarships in Brazil - Doctorate |
| FAPESP's process: | 20/00144-6 - Structural proteomics: design, synthesis and application of new generation crosslinking agents |
| Grantee: | Rafael Douglas Clemente Gallo |
| Support Opportunities: | Scholarships in Brazil - Post-Doctoral |
| FAPESP's process: | 18/03910-1 - Physicochemical studies of fluorinated organic compounds: experimental and theoretical approaches |
| Grantee: | Rodrigo Antonio Cormanich |
| Support Opportunities: | Research Grants - Young Investigators Grants |