Surface Characteristics of TiO₂ Coatings Formed by Micro-Arc Oxidation in Ti-25Ta-xNb Alloys: The Influence of Microstructure and Applied Voltage

Author(s)

Quadros, Fernanda de Freitas ; Correa, Diego Rafael Nespeque ; Fosca, Marco ; Ortenzi, Marco ; Plakhotnaia, Olga N. ; Grandini, Carlos Roberto ; Rau, Julietta V.

• Document type: Journal article
• Source: COATINGS; v. 15, n. 6, p. 19-pg., 2025-06-19.

Abstract

Due to their excellent mechanical properties and good biocompatibility, titanium (Ti) and its alloys are widely used as biomaterials. However, when implanted in the body, metallic materials may cause serious complications such as wear and infection, leading to patient discomfort and, in some cases, the need for revision surgery. Micro-arc oxidation (MAO) is a surface modification technique that offers a promising strategy to overcome these challenges. This study investigated the impact of the microstructure of Ti-25 Ta-xNb alloys (x = 10, 20, and 30 wt%) and the variation in applied voltage during the MAO process on the characteristics of the TiO2 oxide coatings formed. The alloys were treated by MAO at 200, 250, and 300 V using a bioactive electrolyte containing Ca, P, Mg, and Ag. EDS, SEM, XRD, Raman spectroscopy, and adhesion tests performed characterization. Results indicated that Nb addition stabilized the beta phase and anticipated the potentiostatic regime. Increasing the voltage supplied to the system provides greater energy, prolonging the galvanostatic regime and promoting the formation of larger and more uniform pores. The oxide coating thickness ranged from approximately 3 to 10 mu m, with a tendency to decrease at higher voltages. The coatings exhibited low c, with anatase and rutile phases predominating, the applied voltage and Nb concentration influencing their relative proportions. Even in small amounts, all electrolyte elements (P, Mg, and Ag) were successfully incorporated into the coatings under all conditions. Raman and XRD analyses confirmed a decrease in anatase and an increase in rutile phases with increasing voltage and Nb content. Mechanical testing revealed good adhesion of the coatings in all samples, with the best results obtained at 200 V. The findings demonstrate that the developed coatings exhibit promising characteristics for future surface engineering strategies aimed at improving the performance of metallic biomaterials. (AU)

• FAPESP's process: 22/15205-6 - Surface functionalization in alloys of the Ti-25Ta-Nb system for biomedical applications
• Grantee: Fernanda de Freitas Quadros
• Support Opportunities: Scholarships in Brazil - Doctorate
• FAPESP's process: 24/03148-3 - Biofunctionalization of biomedical Ti-based alloys using micro-arc oxidation and the concept of high entropy oxides
• Grantee: Diego Rafael Nespeque Correa
• Support Opportunities: Regular Research Grants
• FAPESP's process: 24/01132-2 - Multidisciplinary Center for the Development of Assistive Technology (MCDAT)
• Grantee: Carlos Roberto Grandini
• Support Opportunities: Research Grants - Science Centers for Development