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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electron spin resonance (ESR) of Eu2+ in type-I clathrate Eu8Ga16Ge30

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Author(s):
Holanda, L. M. [1] ; Vargas, J. M. [1] ; Rettori, C. [1] ; Pagliuso, P. G. [1] ; Bittar, E. M. [1] ; Avila, M. A. [2] ; Takabatake, T. [2]
Total Authors: 7
Affiliation:
[1] Univ Estadual Campinas, Dept Eletron Quant, Inst Fis Gleb Wataghin, Campinas, SP - Brazil
[2] Hiroshima Univ, AdSM, Dept Quantum Matter, Higashihiroshima 7398530 - Japan
Total Affiliations: 2
Document type: Journal article
Source: PHYSICA B-CONDENSED MATTER; v. 404, n. 19, p. 3300-3303, OCT 15 2009.
Web of Science Citations: 6
Abstract

We report temperature dependent X-band (nu similar to 9.5 GHz) electron spin resonance (ESR) experiments in type-I clathrate Eu(8)Ga(16)Ge(30). This system presents interesting thermoelectric properties in its paramagnetic state and orders ferromagnetically below T(C) = 35 K Although the Eu(2+) ions sits on two inequivalent sites in the type-I clathrate structure, we found in the paramagnetic state a single Dysonian Eu(2+) ESR line with a nearly temperature independent g similar to 2 is observed, and its linewidth follows a Korringa-like behavior as a function of temperature. The microscopic details of the exchange coupling between the Eu(2+) local moments and the conduction-electrons (c-e) in this compound are investigated through the obtained Korringa rate (Delta H/Delta T similar to 1 (1) Oe/K) and g-shift (Delta g similar to 0.01(1)) from ESR experiments combined with the magnetic susceptibility and specific heat data. (c) 2009 Elsevier B.V. All rights reserved. (AU)