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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Effect of strontium addition on ferroelectric phase transition of PZT thin films prepared by chemical route

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Author(s):
Pontes, F. M. [1] ; Galhiane, M. S. [1] ; Santos, L. S. [1] ; Gavino, A. [1] ; Petit, L. A. [1] ; Pontes, D. S. L. [2] ; Longo, E. [2] ; Chiquito, A. J. [3] ; Costa, C. E. F. [4]
Total Authors: 9
Affiliation:
[1] Univ Estadual Paulista, Dept Chem, LAMAC, BR-17033360 Sao Paulo - Brazil
[2] Univ Estadual Paulista, Inst Chem, BR-14801970 Sao Paulo - Brazil
[3] Univ Fed Sao Carlos, Dept Phys, BR-13565905 Sao Carlos, SP - Brazil
[4] Fed Univ Para, Inst Nat Sci, LOC, BR-66059 Belem, Para - Brazil
Total Affiliations: 4
Document type: Journal article
Source: APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING; v. 95, n. 3, p. 693-698, JUN 2009.
Web of Science Citations: 3
Abstract

The dependence of ferroelectric phase transition temperature as a function of strontium substitution in lead titanate zirconate thin films (referred here as PSZT) on platinum-coated silicon substrates was investigated. The dielectric study reveals that the material undergoes a diffuse type ferroelectric phase transition that depends on the substitution of Sr for Pb in PZT. At 100 kHz, the phase transition temperatures were 633, 613 and 516 K for PSZT10, PSZT20 and PSZT30 thin films, respectively. On the other hand, the results showed that the dependence of the dielectric constant upon the frequency does not reveal any relaxor behavior. The diffusivity increases with increasing Sr contents in the studied composition range. The experimental data obtained from measurements of the dielectric constant as a function of temperature and frequencies showed a classical behavior of ferroelectric phase transition in PSZT thin films, rather than a relaxor ferroelectric phase transition. The transition temperature decreases with increasing Sr contents due to the decrease in grain size, lattice decrease and local structural disorder. (AU)