Mechanistic study of the addition reaction of TeCl4 to alkynes: Participation of TeCl3 centered-radical

Keppler, Artur F.; Prado, Fernanda M.; Cerchiaro, Giselle; Di Mascio, Paolo; Comasseto, Joao V.

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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Mechanistic study of the addition reaction of TeCl4 to alkynes: Participation of TeCl3 centered-radical

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Author(s):	Keppler, Artur F. ^[1] ; Prado, Fernanda M. ^[1] ; Cerchiaro, Giselle ^[2] ; Di Mascio, Paolo ^[1] ; Comasseto, Joao V. ^[1] Total Authors: 5
Affiliation:	^[1] Univ Sao Paulo, Inst Quim, BR-05508900 Sao Paulo - Brazil ^[2] Univ Fed ABC, Ctr Ciencias Nat & Humanas, Santo Andre, SP - Brazil Total Affiliations: 2
Document type:	Journal article
Source:	JOURNAL OF ORGANOMETALLIC CHEMISTRY; v. 693, n. 24, p. 3558-3562, NOV 15 2008.
Web of Science Citations:	2
Abstract
The mechanism of the addition reaction of TeCl(4) to alkynes was indirectly established by the detection of TeCl(3) centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization. Crown Copyright (C) 2008 Published by Elsevier B. V. All rights reserved. (AU)

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