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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Harvestman Phenols and Benzoquinones: Characterisation and Biosynthetic Pathway

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Author(s):
Rocha, Daniele F. O. [1] ; Wouters, Felipe C. [1] ; Zampieri, Davila S. [1] ; Brocksom, Timothy J. [2] ; Machado, Glauco [3] ; Marsaioli, Anita J. [1]
Total Authors: 6
Affiliation:
[1] Univ Estadual Campinas, Inst Quim, BR-13083970 Campinas, SP - Brazil
[2] Univ Fed Sao Carlos, Dept Quim, Lab Quim Bioorgan, BR-13565905 Sao Carlos, SP - Brazil
[3] Univ Sao Paulo, Inst Biociencias, Dept Ecol, BR-05508090 Sao Paulo - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Molecules; v. 18, n. 9, p. 11429-11451, SEP 2013.
Web of Science Citations: 15
Abstract

Benzoquinones are usually present in arthropod defence exudates. Here, we describe the chemical profiles of 12 harvestman species belonging to the neotropical family Gonyleptidae. Nine of the studied species produced benzoquinones, while three produced alkyl phenols. Two benzoquinones and one phenol exhibited biological activity against bacteria and fungi. We also studied the biosynthesis of 2-ethyl-1,4-benzoquinone by feeding Magnispina neptunus individuals with C-13-labelled precursors; the benzoquinones were biosynthesised through a polyketide pathway using acetate and propionate building blocks. (AU)

FAPESP's process: 08/06604-7 - Cladistics of the harvestmen of the family Gonyleptidae (Arachnida: Opiliones) based on morphological, behavioral and molecular characters
Grantee:Ricardo Pinto da Rocha
Support Opportunities: Regular Research Grants