Calibration in Laser-Induced Breakdown Spectroscopy (LIBS): alternatives, challenges, proposals comparison and proposition of a universal procedure

• Grant number: 19/24223-5
• Support Opportunities: Regular Research Grants
• Start date: July 01, 2020
• End date: December 31, 2022
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Edenir Rodrigues Pereira Filho
• Grantee: Edenir Rodrigues Pereira Filho
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
• City of the host institution: São Carlos

Abstract

In this project a universal calibration strategy will be proposed focusing solid samples analysis by laser-induced breakdown spectroscopy (LIBS). Several univariate and multivariate calibration proposals will be tested for food, electronic waste and sugarcane samples direct analysis. The elements that will be determined are toxic and essentials. A research team composed of chemistries, mathematician and physics, as well as, master and PhD students will work together in order to apply artificial neural network, calibration free and data fusion. Parallel factor analysis (PARAFAC) will be used for data processing and removal of possible spectral interference. (AU)

Scientific publications

(22)

(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)

GAMELA, RAIMUNDO RAFAEL; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. Minimal-Invasive Analytical Method and Data Fusion: an Alternative for Determination of Cu, K, Sr, and Zn in Cocoa Beans. FOOD ANALYTICAL METHODS, v. 14, n. 3, p. 545-551, MAR 2021. (14/50945-4, 19/01102-8, 18/18212-8, 19/24223-5)

HILARIO, FELIPE FERRI; LIMA DE MELLO, MATHEUS; PEREIRA-FILHO, EDENIR RODRIGUES. Forensic analysis of hand-written documents using laser-induced breakdown spectroscopy (LIBS) and chemometrics. ANALYTICAL METHODS, v. 13, n. 2, p. 232-241, JAN 14 2021. (19/24223-5)

MACHADO, RAQUEL C.; SILVA, ANA BEATRIZ S.; ANDRADE, DANIEL F.; PINHEIRO, FERNANDA C.; WILLIAMS, CHARLES B.; DONATI, GEORGE L.; NOGUEIRA, ANA RITA A.; PEREIRA-FILHO, EDENIR R.. Alternative Approaches Applied to Inductively Coupled Plasma Techniques: Multi-Flow and Two-Flow Calibration. Journal of the Brazilian Chemical Society, v. 32, n. 4, p. 842-851, APR 2021. (18/26145-9, 19/24223-5, 16/17304-0)

FELIPE FERRI HILÁRIO; JEYNE PRICYLLA CASTRO; TOMAS EDSON BARROS; EDENIR RODRIGUES PEREIRA-FILHO. . Química Nova, v. 44, n. 7, p. 874-881, 2021-09-03. (19/24223-5, 16/17221-8)

RODRIGUES, LETICIA DA SILVA; FERREIRA, DENNIS SILVA; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. Mineral and trace element analysis of non-conventional food plants using ICP OES and chemometric techniques. Food Chemistry, v. 472, p. 7-pg., 2025-01-14. (23/08085-7, 19/24223-5, 19/01102-8, 14/50945-4, 21/10882-7, 22/02232-5)

DENNIS DA SILVA FERREIRA; LETICIA DA SILVA RODRIGUES; FABIOLA MANHAS VERBI PEREIRA; EDENIR RODRIGUES PEREIRA FILHO. . Química Nova, v. 46, n. 7, p. 747-754, 2023-08-28. (22/02232-5, 21/10882-7, 19/24223-5, 16/17221-8)

ANDRADE, DANIEL FERNANDES; CASTRO, JEYNE PRICYLLA; GARCIA, JOSE AUGUSTO; MACHADO, RAQUEL CARDOSO; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Analytical and reclamation technologies for identification and recycling of precious materials from waste computer and mobile phones. Chemosphere, v. 286, n. 2, JAN 2022. (16/17304-0, 16/17221-8, 18/24569-6, 19/24223-5)

ARAUJO, ALISSON SILVA; CASTRO, JEYNE PRICYLLA; SPERANCA, MARCO AURELIO; ANDRADE, DANIEL FERNANDES; DE MELLO, MATHEUS LIMA; PEREIRA-FILHO, EDENIR RODRIGUES. Multiway Calibration Strategies in Laser-Induced Breakdown Spectroscopy: A Proposal. Analytical Chemistry, v. 93, n. 16, p. 10-pg., 2021-04-14. (16/01513-0, 16/17304-0, 16/17221-8, 19/24223-5)

FERREIRA, DENNIS SILVA; PEREIRA-FILHO, EDENIR RODRIGUES. A preliminary study of a sequential leaching process to recover Ag, Au, Cu, and Sn from E-waste. HYDROMETALLURGY, v. 235, p. 10-pg., 2025-08-01. (16/01513-0, 19/24223-5)

FERREIRA, DENNIS SILVA; BUIL-GARCIA, JUAN; ANZANO, JESUS M.; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. Calibration Models for Macronutrient (Ca, K, and Mg) Determination in Food Samples Using Laser-Induced Breakdown Spectroscopy: Instruments Comparison and Error Structure Information for Enhanced Predictive Accuracy. FOOD ANALYTICAL METHODS, v. N/A, p. 8-pg., 2025-07-14. (19/24223-5, 23/08085-7, 19/01102-8)

ANDRADE, DANIEL FERNANDES; DE ALMEIDA, EDUARDO; PEREIRA DE CARVALHO, HUDSON WALLACE; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Chemical inspection and elemental analysis of electronic waste using data fusion - Application of complementary spectroanalytical techniques. Talanta, v. 225, APR 1 2021. (16/01513-0, 15/05942-0, 16/17304-0, 18/24569-6, 19/24223-5)

VINICIUS C. COSTA; DIEGO V. BABOS; JEYNE P. CASTRO; DANIEL F. ANDRADE; RAIMUNDO R. GAMELA; RAQUEL C. MACHADO; MARCO A. SPERANÇA; ALISSON S. ARAÚJO; JOSÉ A. GARCIA; EDENIR R. PEREIRA-FILHO. Calibration Strategies Applied to Laser-Induced Breakdown Spectroscopy: A Critical Review of Advances and Challenges. Journal of the Brazilian Chemical Society, v. 31, n. 12, p. 2439-2451, 2020-12-14. (16/17221-8, 19/24223-5, 18/17753-5, 18/24569-6, 16/01513-0, 16/17304-0)

NASCIMENTO, PALOMA ANDRADE MARTINS; SPERANCA, MARCO AURELIO; ROMANO BELETTI, DOUGLAS; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. White Crystal Cane Sugar Analysis Using a Noninvasive Method for Detection of Tampering with Sand. FOOD ANALYTICAL METHODS, v. 14, n. 7, p. 1438-1442, JUL 2021. (19/01102-8, 14/50945-4, 18/18212-8, 19/24223-5)

ARAUJO, ALISSON SILVA; ANDRADE, DANIEL FERNANDES; BABOS, DIEGO VICTOR; CASTRO, JEYNE PRICYLLA; GARCIA, JOSE AUGUSTO; SPERANCA, MARCO AURELIO; GAMELA, RAIMUNDO RAFAEL; MACHADO, RAQUEL CARDOSO; COSTA, VINICIUS CAMARA; GUEDES, WESLEY NASCIMENTO; et al. Key Information Related to Quality by Design (QbD) Applications in Analytical Methods Development. BRAZILIAN JOURNAL OF ANALYTICAL CHEMISTRY, v. 8, n. 30, p. 14-28, JAN-MAR 2021. (14/50945-4, 19/24223-5, 19/01102-8, 18/18212-8)

COSTA, VINICIUS CAMARA; DE MELLO, MATHEUS LIMA; BABOS, DIEGO VICTOR; CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES. Calibration strategies for determination of Pb content in recycled polypropylene from car batteries using laser-induced breakdown spectroscopy (LIBS). Microchemical Journal, v. 159, DEC 2020. (19/24223-5)

MACHADO, RAQUEL C.; BABOS, DIEGO VICTOR; ANDRADE, DANIEL F.; PEREIRA-FILHO, EDENIR RODRIGUES. A novel strategy for direct elemental determination using laser-induced breakdown spectroscopy: fluence calibration. Journal of Analytical Atomic Spectrometry, v. 36, n. 10, JUL 2021. (16/17304-0, 19/24223-5, 16/01513-0)

FERREIRA, DENNIS SILVA; BABOS, DIEGO VICTOR; LIMA-FILHO, MAURO HENRIQUE; CASTELLO, HELOISA FROEHLICK; OLIVIERI, ALEJANDRO C.; PEREIRA, FABIOLA MANHAS VERBI; PEREIRA-FILHO, EDENIR RODRIGUES. Laser-induced breakdown spectroscopy (LIBS): calibration challenges, combination with other techniques, and spectral analysis using data science. Journal of Analytical Atomic Spectrometry, v. 39, n. 12, p. 25-pg., 2024-11-08. (19/24223-5, 19/01102-8, 21/10882-7, 16/17221-8, 22/02232-5)

GAMELA, RAIMUNDO R.; FONTOURA, BEATRIZ M.; COSTA, VINICIUS C.; BABOS, DIEGO, V; PEREIRA-FILHO, EDENIR R.. Matrix-Matching Calibration Using Solid Standards: A Comparison between Univariate and Multivariate Strategies for the Determination of Calcium and Magnesium in Bean Seed Samples Employing Laser-Induced Breakdown Spectroscopy (LIBS). Analytical Letters, v. N/A, p. 14-pg., 2022-08-09. (19/24223-5)

FERREIRA, DENNIS S.; PEREIRA, FABIOLA M. V.; OLIVIERI, ALEJANDRO C.; PEREIRA-FILHO, EDENIR R.. Electronic waste analysis using laser-induced breakdown spectroscopy (LIBS) and X-ray fluorescence (XRF): Critical evaluation of data fusion for the determination of Al, Cu and Fe. Analytica Chimica Acta, v. 1303, p. 9-pg., 2024-03-28. (19/24223-5, 19/01102-8, 21/10882-7, 16/17221-8, 22/02232-5)

ROMERO, ESTEBAN; FERREIRA, DENNIS S.; PEREIRA, FABIOLA M. V.; OLIVIERI, ALEJANDRO C.; PEREIRA-FILHO, EDENIR R.; ARANCIBIA, JUAN A.. Cement classification and characterization using Non-Invasive techniques. Talanta, v. 284, p. 12-pg., 2024-11-20. (19/24223-5, 19/01102-8, 21/10882-7, 16/17221-8, 22/02232-5)

DE ARAUJO, THAILA LORENA; PEREIRA, FABIOLA MANHAS VERBI; PEREIRA-FILHO, EDENIR RODRIGUES. Direct solid sample analysis of low-cost jewelry using spectroanalytical techniques: exploratory chemical data evaluation and metal migration with synthetic sweat. ANALYTICAL METHODS, v. 16, n. 15, p. 6-pg., 2024-03-11. (19/24223-5, 19/01102-8, 21/10882-7, 16/17221-8, 22/02232-5)

FERREIRA, DENNIS S.; PEREIRA-FILHO, EDENIR R.. LIBS and Hyperspectral Imaging as a Real-Time Process Control Tool for Metal Recovery from E-Waste. Journal of the Brazilian Chemical Society, v. 36, n. 12, p. 13-pg., 2025-01-01. (19/24223-5)