Calibration in Laser-Induced Breakdown Spectroscopy (LIBS): alternatives, challenges, proposals comparison and proposition of a universal procedure

• Grant number: 19/24223-5
• Support Opportunities: Regular Research Grants
• Start date: July 01, 2020
• End date: December 31, 2022
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Edenir Rodrigues Pereira Filho
• Grantee: Edenir Rodrigues Pereira Filho
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil

Abstract

In this project a universal calibration strategy will be proposed focusing solid samples analysis by laser-induced breakdown spectroscopy (LIBS). Several univariate and multivariate calibration proposals will be tested for food, electronic waste and sugarcane samples direct analysis. The elements that will be determined are toxic and essentials. A research team composed of chemistries, mathematician and physics, as well as, master and PhD students will work together in order to apply artificial neural network, calibration free and data fusion. Parallel factor analysis (PARAFAC) will be used for data processing and removal of possible spectral interference. (AU)

Scientific publications

(14)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

COSTA, VINICIUS CAMARA; DE MELLO, MATHEUS LIMA; BABOS, DIEGO VICTOR; CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES. Calibration strategies for determination of Pb content in recycled polypropylene from car batteries using laser-induced breakdown spectroscopy (LIBS). Microchemical Journal, v. 159, DEC 2020. (19/24223-5)

VINICIUS C. COSTA; DIEGO V. BABOS; JEYNE P. CASTRO; DANIEL F. ANDRADE; RAIMUNDO R. GAMELA; RAQUEL C. MACHADO; MARCO A. SPERANÇA; ALISSON S. ARAÚJO; JOSÉ A. GARCIA; EDENIR R. PEREIRA-FILHO. Calibration Strategies Applied to Laser-Induced Breakdown Spectroscopy: A Critical Review of Advances and Challenges. Journal of the Brazilian Chemical Society, v. 31, n. 12, p. 2439-2451, 2020-12-14. (16/17221-8, 18/17753-5, 19/24223-5, 16/01513-0, 18/24569-6, 16/17304-0)

MACHADO, RAQUEL C.; BABOS, DIEGO VICTOR; ANDRADE, DANIEL F.; PEREIRA-FILHO, EDENIR RODRIGUES. A novel strategy for direct elemental determination using laser-induced breakdown spectroscopy: fluence calibration. Journal of Analytical Atomic Spectrometry, v. 36, n. 10, JUL 2021. (16/17304-0, 19/24223-5, 16/01513-0)

NASCIMENTO, PALOMA ANDRADE MARTINS; SPERANCA, MARCO AURELIO; ROMANO BELETTI, DOUGLAS; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. White Crystal Cane Sugar Analysis Using a Noninvasive Method for Detection of Tampering with Sand. FOOD ANALYTICAL METHODS, v. 14, n. 7, p. 1438-1442, JUL 2021. (19/01102-8, 14/50945-4, 18/18212-8, 19/24223-5)

ANDRADE, DANIEL FERNANDES; DE ALMEIDA, EDUARDO; PEREIRA DE CARVALHO, HUDSON WALLACE; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Chemical inspection and elemental analysis of electronic waste using data fusion - Application of complementary spectroanalytical techniques. Talanta, v. 225, APR 1 2021. (16/01513-0, 15/05942-0, 16/17304-0, 18/24569-6, 19/24223-5)

GAMELA, RAIMUNDO R.; FONTOURA, BEATRIZ M.; COSTA, VINICIUS C.; BABOS, DIEGO, V; PEREIRA-FILHO, EDENIR R.. Matrix-Matching Calibration Using Solid Standards: A Comparison between Univariate and Multivariate Strategies for the Determination of Calcium and Magnesium in Bean Seed Samples Employing Laser-Induced Breakdown Spectroscopy (LIBS). Analytical Letters, v. N/A, p. 14-pg., 2022-08-09. (19/24223-5)

ARAUJO, ALISSON SILVA; ANDRADE, DANIEL FERNANDES; BABOS, DIEGO VICTOR; CASTRO, JEYNE PRICYLLA; GARCIA, JOSE AUGUSTO; SPERANCA, MARCO AURELIO; GAMELA, RAIMUNDO RAFAEL; MACHADO, RAQUEL CARDOSO; COSTA, VINICIUS CAMARA; GUEDES, WESLEY NASCIMENTO; et al. Key Information Related to Quality by Design (QbD) Applications in Analytical Methods Development. BRAZILIAN JOURNAL OF ANALYTICAL CHEMISTRY, v. 8, n. 30, p. 14-28, JAN-MAR 2021. (14/50945-4, 19/24223-5, 19/01102-8, 18/18212-8)

GAMELA, RAIMUNDO RAFAEL; PEREIRA-FILHO, EDENIR RODRIGUES; PEREIRA, FABIOLA MANHAS VERBI. Minimal-Invasive Analytical Method and Data Fusion: an Alternative for Determination of Cu, K, Sr, and Zn in Cocoa Beans. FOOD ANALYTICAL METHODS, v. 14, n. 3, p. 545-551, MAR 2021. (14/50945-4, 19/01102-8, 18/18212-8, 19/24223-5)

FELIPE FERRI HILÁRIO; JEYNE PRICYLLA CASTRO; TOMAS EDSON BARROS; EDENIR RODRIGUES PEREIRA-FILHO. PLANEJAMENTO DE MISTURAS E VISUALIZAÇÃO DA REGIÃO ÓTIMA COM PLANILHAS NO EXCEL: UM TUTORIAL. Química Nova, v. 44, n. 7, p. 874-881, 2021-09-03. (19/24223-5, 16/17221-8)

ANDRADE, DANIEL FERNANDES; CASTRO, JEYNE PRICYLLA; GARCIA, JOSE AUGUSTO; MACHADO, RAQUEL CARDOSO; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Analytical and reclamation technologies for identification and recycling of precious materials from waste computer and mobile phones. Chemosphere, v. 286, n. 2, JAN 2022. (16/17304-0, 16/17221-8, 18/24569-6, 19/24223-5)

MACHADO, RAQUEL C.; SILVA, ANA BEATRIZ S.; ANDRADE, DANIEL F.; PINHEIRO, FERNANDA C.; WILLIAMS, CHARLES B.; DONATI, GEORGE L.; NOGUEIRA, ANA RITA A.; PEREIRA-FILHO, EDENIR R.. Alternative Approaches Applied to Inductively Coupled Plasma Techniques: Multi-Flow and Two-Flow Calibration. Journal of the Brazilian Chemical Society, v. 32, n. 4, p. 842-851, APR 2021. (18/26145-9, 19/24223-5, 16/17304-0)

HILARIO, FELIPE FERRI; LIMA DE MELLO, MATHEUS; PEREIRA-FILHO, EDENIR RODRIGUES. Forensic analysis of hand-written documents using laser-induced breakdown spectroscopy (LIBS) and chemometrics. ANALYTICAL METHODS, v. 13, n. 2, p. 232-241, JAN 14 2021. (19/24223-5)

ARAUJO, ALISSON SILVA; CASTRO, JEYNE PRICYLLA; SPERANCA, MARCO AURELIO; ANDRADE, DANIEL FERNANDES; DE MELLO, MATHEUS LIMA; PEREIRA-FILHO, EDENIR RODRIGUES. Multiway Calibration Strategies in Laser-Induced Breakdown Spectroscopy: A Proposal. Analytical Chemistry, v. 93, n. 16, p. 10-pg., 2021-04-14. (16/01513-0, 16/17304-0, 16/17221-8, 19/24223-5)

DENNIS DA SILVA FERREIRA; LETICIA DA SILVA RODRIGUES; FABIOLA MANHAS VERBI PEREIRA; EDENIR RODRIGUES PEREIRA FILHO. PRINCIPAL COMPONENT ANALYSIS (PCA) PARA A AVALIAÇÃO DE DADOS QUÍMICOS E GERAÇÃO DE HEAT MAPS: UM TUTORIAL. Química Nova, v. 46, n. 7, p. 747-754, 2023-08-28. (16/17221-8, 19/24223-5, 22/02232-5, 21/10882-7)