Development of antistatic and biodegradable packages based on hybrid polyester composites with the addition of glassy carbon and graphene nanoplates

• Grant number: 20/12501-8
• Support Opportunities: Regular Research Grants
• Duration: July 01, 2021 - June 30, 2023
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Fabio Roberto Passador
• Grantee: Fabio Roberto Passador
• Host Institution: Instituto de Ciência e Tecnologia (ICT). Universidade Federal de São Paulo (UNIFESP). Campus São José dos Campos. São José dos Campos , SP, Brazil
• Associated researchers: Gilmar Patrocínio Thim ; Larissa Stieven Montagna ; Mirabel Cerqueira Rezende

Abstract

Antistatic packaging is used to protect electronic components from damage caused by electrostatic discharges, and must have a sufficiently low electrical resistivity. With the increasing demand for these components, there is an increase in polymeric waste that is often inappropriately disposed of in the environment. In order to reduce these residues, biopolymers and biodegradable polymers can be an eco-friendly solution. Among the different biopolymers, poly (lactic acid) (PLA) and poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) are good choices because they are renewable and have a biodegradable origin. However, these polymers have high electrical resistivity, a property that prevents their use for the production of antistatic packaging, requiring the addition of antistatic agents. One way is through the addition of carbon materials that are electrically conductive, such as carbon nanotubes (CNT), carbon black (CB), glassy carbon (GC), and graphene nanoplates (GNP). In this context, hybrid composites of biodegradable polyester matrices (PLA, PHBV, and PLA/PHBV blends) with the addition of different contents of GC and GNP will be prepared in a double-screw extruder followed by the preparation of standard specimens using injection molding and production of films, in order to assess biodegradability, mechanical, thermal, and electrical properties, aiming to obtain antistatic and biodegradable packaging. (AU)

Scientific publications

(12)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DE MOURA, NAYARA KOBA; DE MELO MORGADO, GUILHERME FERREIRA; MARTINS, EDUARDO FERREIRA; ESCANIO, CAMILA ALVES; ESPOSITO, ELISA; MARINI, JULIANO; PASSADOR, FABIO ROBERTO. Evaluation of Shape Memory in Poly(lactic acid)/ thermoplastic Polyurethane Filaments with Carbon Nanotubes and Graphene Nanoplatelets. MACROMOLECULAR SYMPOSIA, v. 406, n. 1, p. 8-pg., 2022-12-01. (20/12501-8)

DA SILVA, THAIS FERREIRA; DE MELO MORGADO, GUILHERME FERREIRA; FONSECA ALBERS, ANA PAULA; QUINTEIRO, EDUARDO; PASSADOR, FABIO ROBERTO. High-density polyethylene/attapulgite (ATP) nanocomposites: Effect of the organophilization of ATP on the structural, mechanical, and thermal properties. Journal of Applied Polymer Science, v. 139, n. 27, p. 14-pg., 2022-05-05. (20/12501-8)

DA SILVA, THAIS FERREIRA; MONTEIRO DE SOUZA, GABRIEL PORTILHO; DE MELO MORGADO, GUILHERME FERREIRA; ALBERS, ANA PAULA FONSECA; QUINTEIRO, EDUARDO; PASSADOR, FABIO ROBERTO. nfluence of surface modification of attapulgite (ATP) with aminosilane (3-aminopropyl) triethoxysilane for the preparation of LLDPE/ATP nanocomposite. JOURNAL OF POLYMER RESEARCH, v. 29, n. 3, MAR 2022. (16/19978-9, 20/12501-8)

OYAMA, ISABELA MONTEIRO CESAR; DOS ANJOS, ERICK GABRIEL RIBEIRO; MORGADO, GUILHERME FERREIRA DE MELO; MARTINS, EDUARDO FERREIRA; PASSADOR, FABIO ROBERTO. Antistatic and antimicrobial packaging of PLA/PHBV blend-based graphene nanoplatelets nanocomposites. Journal of Applied Polymer Science, v. N/A, p. 17-pg., 2023-07-26. (20/12501-8)

MONTAGNA, LARISSA STIEVEN; DE ALMEIDA, FABIO AUGUSTO PASSOS; DOS SANTOS BATISTA, LARISSA ANNE PEREIRA; DOS ANJOS, ERICK GABRIEL RIBEIRO; BRAZIL, TAYRA RODRIGUES; DE MELO MORGADO, GUILHERME FERREIRA; BALDAN, MAURICIO RIBEIRO; PASSADOR, FABIO ROBERTO. A viable strategy to recycle post-used carbon fiber thermoset composites as a multi-functional filler for PP composites. JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, v. N/A, p. 21-pg., 2023-05-20. (20/12501-8)

DA SILVA, THAIS FERREIRA; ALBERS, ANA PAULA FONSECA; QUINTEIRO, EDUARDO; SUNDARARAJ, UTTANDARAMAN; PASSADOR, FABIO ROBERTO. Mechanical, thermal, rheological, and morphological characterization of polyolefin/activated attapulgite nanocomposites. Journal of Applied Polymer Science, v. 140, n. 39, p. 17-pg., 2023-07-21. (20/12501-8, 16/19978-9)

DOS ANJOS, ERICK GR; MOURA, NAYARA K.; ANTONELLI, EDUARDO; BALDAN, MAURICIO R.; GOMES, NEWTON AS; BRAGA, NATALIA F.; SANTOS, ADELINA P.; REZENDE, MIRABEL C.; PESSAN, LUIZ A.; PASSADOR, FABIO R.. Role of adding carbon nanotubes in the electric and electromagnetic shielding behaviors of three different types of graphene in hybrid nanocomposites. JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, v. N/A, p. 27-pg., 2022-09-06. (20/12501-8)

DOS ANJOS, ERICK GABRIEL RIBEIRO; BRAZIL, TAYRA RODRIGUES; MORGADO, GUILHERME FERREIRA DE MELO; MONTAGNA, LARISSA STIEVEN; BRAGA, NATALIA FERREIRA; ANTONELLI, EDUARDO; MARINI, JULIANO; REZENDE, MIRABEL CERQUEIRA; PASSADOR, FABIO ROBERTO. Influence of MWCNT aspect ratio on the rheological, electrical, electromagnetic shielding, and mechanical properties of polycarbonate melt mixed nanocomposites. JOURNAL OF POLYMER RESEARCH, v. 30, n. 2, p. 16-pg., 2023-02-01. (21/10136-3, 20/12501-8)

DE MELO MORGADO, GUILHERME FERREIRA; DE MOURA, NAYARA KOBA; MARTINS, EDUARDO FERREIRA; ESCANIO, CAMILA ALVES; BACKES, EDUARDO HENRIQUE; MARINI, JULIANO; PASSADOR, FABIO ROBERTO. Effect of blend ratio on thermal, mechanical, and shape memory properties of poly (lactic acid)/thermoplastic polyurethane bio-blends. JOURNAL OF POLYMER RESEARCH, v. 29, n. 12, p. 12-pg., 2022-12-01. (20/12501-8)

DA SILVA, THAIS FERREIRA; DE SOUZA, GABRIEL PORTILHO MONTEIRO; MORGADO, GUILHERME FERREIRA DE MELO; QUINTEIRO, EDUARDO; ALBERS, ANA PAULA FONSECA; PASSADOR, FABIO ROBERTO. Effect of Different Surface Modifications of Brazilian Attapulgite (ATP) on the Mechanical and Thermal Properties of LLDPE/ATP Nanocomposites. MACROMOLECULAR SYMPOSIA, v. 406, n. 1, p. 11-pg., 2022-12-01. (20/12501-8, 16/19978-9)

ZAGGO, HENRIQUE M. M.; BRAGA, NATALIA F.; DOS ANJOS, ERICK G. R.; MONTAGNA, LARISSA S. S.; ANTONELLI, EDUARDO; PASSADOR, FABIO R. R.. Effect of Recycled Graphite as an Antistatic Agent on the Mechanical, Thermal, and Electrical Properties of Poly(Trimethylene Terephthalate). MACROMOLECULAR SYMPOSIA, v. 406, n. 1, p. 11-pg., 2022-12-01. (19/22339-6, 20/12501-8)

SARTURATO, ANA CAROLINA PRATAVIERA; DOS ANJOS, ERICK GABRIEL RIBEIRO; MARINI, JULIANO; MORGADO, GUILHERME FERREIRA DE MELO; BALDAN, MAURICIO RIBEIRO; PASSADOR, FABIO ROBERTO. Polypropylene/talc/graphene nanoplates (GNP) hybrid composites: Effect of GNP content on the thermal, rheological, mechanical, and electrical properties. Journal of Applied Polymer Science, v. N/A, p. 13-pg., 2023-01-24. (20/12501-8)