Porous materials: preparation, properties and applications

• Grant number: 00/11103-5
• Support Opportunities: Research Projects - Thematic Grants
• Start date: March 01, 2003
• End date: June 30, 2008
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Principal Investigator: Yoshitaka Gushikem
• Grantee: Yoshitaka Gushikem
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated research grant(s): 06/51751-2 - Chemometrics based xas characterization of titanium on titanium oxide modified chromatographic silica., AR.EXT

Abstract

The aim of this project is the investigation of the preparation process of porous materials with special interest on: a) dispersed metal oxides and b) microporous and mesopourous crystalline solids, and characterizing them by several analysis techniques as well the application of these materials for the development of recognition devices, like chemical sensors and reactors. The optimization of the preparation process of this material will look for higher adsorption capacity and selectivity. In this sense, the interaction between different researchers with the same objective to reach the consolidation of the knowledge for material preparation and characterization will be prioritizes. The possibility to form experts on basic and applied aspects with a multidisciplinary view in material preparations and applications in sensors and chemical reactors will be emphasized. (AU)

Scientific publications

(19)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

HÉRICA A. MAGOSSO; NATÁLIA FATTORI; YURIY V. KHOLIN; YOSHITAKA GUSHIKEM. Adsorption of metal ions on novel 3-n-propyl (methylpyridinium) silsesquioxane chloride polymers surface: study of heterogeneous equilibrium at the solid-solution interface. Journal of the Brazilian Chemical Society, v. 20, n. 4, p. 744-752, 2009-00-00. (00/11103-5)

PAVAN‚ F.A.; SCHWINGEL RIBEIRO‚ E.; GUSHIKEM‚ Y.. Congo red immobilized on a silica/aniline xerogel: Preparation and application as an amperometric sensor for ascorbic acid. Electroanalysis, v. 17, n. 7, p. 625-629, 2005. (00/11103-5)

CANEVARI‚ T.C.; LUZ‚ R.C.S.; GUSHIKEM‚ Y.. Electrocatalytic Determination of Nitrite on a Rigid Disk Electrode Having Cobalt Phthalocyanine Prepared In Situ. Electroanalysis, v. 20, n. 7, p. 765-770, 2008. (00/11103-5)

ARGUELLO‚ J.; MAGOSSO‚ H.A.; RAMOS‚ R.R.; CANEVARI‚ T.C.; LANDERS‚ R.; PIMENTEL‚ V.L.; GUSHIKEM‚ Y.. Structural and electrochemical characterization of a cobalt phthalocyanine bulk-modified SiO₂/SnO₂ carbon ceramic electrode. Electrochimica Acta, v. 54, n. 7, p. 1948-1953, 2009. (00/11103-5)

PEREIRA‚ F.M.V.; BUENO‚ M.I.M.S.. Image evaluation with chemometric strategies for quality control of paints. Analytica Chimica Acta, v. 588, n. 2, p. 184-191, 2007. (00/11103-5)

CANEVARI, THIAGO C.; VINHAS, RITA C. G.; LANDERS, RICHARD; GUSHIKEM, YOSHITAKA. SiO2/SnO2/Sb2O5 microporous ceramic material for immobilization of Meldola's blue: Application as an electrochemical sensor for NADH. BIOSENSORS & BIOELECTRONICS, v. 26, n. 5, p. 2402-2406, 2011. (00/11103-5)

MARONEZE‚ C.M.; ARENAS‚ L.T.; LUZ‚ R.; BENVENUTTI‚ E.V.; LANDERS‚ R.; GUSHIKEM‚ Y.. Meldola blue immobilized on a new SiO₂/TiO₂/graphite composite for electrocatalytic oxidation of NADH. Electrochimica Acta, v. 53, n. 12, p. 4167-4175, 2008. (00/11103-5)

ARGUELLO, JACQUELINE; LEIDENS, VICTOR L.; MAGOSSO, HERICA A.; RAMOS, RODRIGO R.; GUSHIKEM, YOSHITAKA. Simultaneous voltammetric determination of ascorbic acid, dopamine and uric acid by methylene blue adsorbed on a phosphorylated zirconia-silica composite electrode. Electrochimica Acta, v. 54, n. 2, p. 560-565, DEC 30 2008. (00/11103-5)

ANDRÉ R. RAMOS; JACQUELINE ARGUELLO; HÉRICA A. MAGOSSO; YOSHITAKA GUSHIKEM. Al2O3 coated with 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octane silsesquioxane chloride and its use for immobilization of cobalt(II) tetrasulfonated phthalocyanine in oxalic acid electrooxidation. Journal of the Brazilian Chemical Society, v. 19, n. 4, p. 755-761, 2008-00-00. (00/11103-5)

GISLENE SPLENDORE; EDILSON V. BENVENUTTI; YURIY V. KHOLIN; YOSHITAKA GUSHIKEM. Cellulose acetate-Al2O3 hybrid material coated with N-Propyl-1,4-diazabicyclo [2.2.2] octane chloride: preparation, characterization and study of some metal halides adsorption from ethanol solution. Journal of the Brazilian Chemical Society, v. 16, n. 2, p. 147-152, 2005-04-00. (00/11103-5)

MARONEZE, CAMILA M.; LUZ, RITA C. S.; LANDERS, RICHARD; GUSHIKEM, YOSHITAKA. SiO2/TiO2/Sb2O5/graphite carbon ceramic conducting material: preparation, characterization, and its use as an electrochemical sensor. Journal of Solid State Electrochemistry, v. 14, n. 1, p. 115-121, JAN 2010. (00/11103-5)

LUZ, RITA C. S.; DAMOS, FLAVIO S.; TANAKA, AURO A.; KUBOTA, LAURO T.; GUSHIKEM, YOSHITAKA. Electrocatalysis of reduced L-glutathione oxidation by iron(III) tetra-(N-methyl-4-pyridyl)-porphyrin (FeT4MPyP) adsorbed on multi-walled carbon nanotubes. Talanta, v. 76, n. 5, p. 1097-1104, SEP 15 2008. (00/11103-5)

CANEVARI, THIAGO C.; ARENAS, LELIZ T.; LANDERS, RICHARD; CUSTODIO, ROGERIO; GUSHIKEM, YOSHITAKA. Simultaneous electroanalytical determination of hydroquinone and catechol in the presence of resorcinol at an SiO2/C electrode spin-coated with a thin film of Nb2O5. ANALYST, v. 138, n. 1, p. 315-324, 2013. (00/11103-5)

MARAFON, EDUARDO; KUBOTA, LAURO T.; GUSHIKEM, YOSHITAKA. FAD-modified SiO2/ZrO2/C ceramic electrode for electrocatalytic reduction of bromate and iodate. Journal of Solid State Electrochemistry, v. 13, n. 3, p. 377-383, MAR 2009. (00/11103-5)

EDUARDO MARAFON; ALZIRA M.S. LUCHO; MARIA S.P. FRANCISCO; RICHARD LANDERS; YOSHITAKA GUSHIKEM. Thin film of copper hexacyanoferrate dispersed on the surface of a conducting carbon ceramic material, SiO2/ZrO2/C-graphite: characteristics and electrochemical studies. Journal of the Brazilian Chemical Society, v. 17, n. 8, p. 1605-1611, 2006-12-00. (00/11103-5)

DE CÁSSIA SILVA LUZ‚ R.; DAMOS‚ F.S.; TANAKA‚ A.A.; KUBOTA‚ L.T.; GUSHIKEM‚ Y.. Electrocatalytic activity of 2‚ 3‚ 5‚ 6-tetrachloro-1‚ 4-benzoquinone/multi-walled carbon nanotubes immobilized on edge plane pyrolytic graphite electrode for NADH oxidation. Electrochimica Acta, v. 53, n. 14, p. 4706-4714, 2008. (00/11103-5)

SUSSULINI‚ A.; LIMA‚ AG; FIGUEIREDO‚ EC; FERNANDES‚ HL; PINHEIRO‚ SCL; BUENO‚ M.; PEREIRA‚ FMV. X-ray scattering information of ED-XRF technique for powdered fruit juice mixes. X-RAY SPECTROMETRY, v. 38, n. 3, p. 254-257, 2009. (00/11103-5)

PISSETTI, F. L.; GUSHIKEM, Y.; LUCHO, A. M. S.. Al2O3-coated 3-n-propylpyridinium chloride silsesquioxane polymer film: preparation and electrochemical property study of adsorbed cobalt tetrasulfophthalocyanine. Journal of Colloid and Interface Science, v. 275, n. 1, p. 251-256, Jul. 2004. (00/11103-5)

LUCHO, ALZIRA M. S.; OLIVEIRA, ÉRICA C.; PASTORE, HELOISE O.; GUSHIKEM, YOSHITAKA. 3-n-Propylpyridinium chloride silsesquioxane polymer film-coated aluminumphosphate and adsorption of cobalt(II)tetrasulphophthalocyanine: an electrocatalytic oxidation study of oxalic acid . Journal of Electroanalytical Chemistry, v. 573, n. 1, p. 55-60, Nov. 2004. (00/11103-5)

Filed patent(s) as a result of this research project