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Thin films obtained by spin and dip-coating using sol-gel methodology

Grant number: 12/11673-3
Support Opportunities:Regular Research Grants
Duration: November 01, 2012 - October 31, 2014
Field of knowledge:Engineering - Chemical Engineering
Principal Investigator:Eduardo José Nassar
Grantee:Eduardo José Nassar
Host Institution: Reitoria. Universidade de Franca (UNIFRAN). Franca , SP, Brazil

Abstract

Surface coating by the sol-gel methodology represents an alternative process that leads to new applications for common substrates. This is possible thank to the multifunctionality that the materials can acquire, which in turn will depend on the sol composition. The sol-gel methodology has been used for the preparation of films and coatings with different applications, such as energy conversion and storage, solar cells, batteries, fuel cells, conducting films, planar waveguides, and bioapplications, among others. These utilizations will depend on the thickness, composition, thermal treatment, and deposition methodology. In this work films will be prepared by the spin- and dip-coating technique, and the sol-gel methodology will be employed for the synthesis of the precursors at several composition, for different applications. The coating will consist of indium tin oxide as the conducting film, titanium as the waveguide, and calcium phosphate, for bioapplications. Additionally, the films will be doped with lanthanide ions, which will serve as structural probe for spectroscopic studies. The characterization will be performed by spectroscopic measurerements such as diffuse reflectance, ultraviolet absorption, Raman, infrared, and photoluminescence, as well as X-ray diffraction and scanning and transmission electron microscopy. (AU)

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Scientific publications (25)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MARCELA G. MATOS; EMERSON H. DE FARIA; KATIA J. CIUFFI; LUCAS A. ROCHA; EDUARDO J. NASSAR; MARC VERELST. EFEITO DA CONCENTRAÇÃO DOS ÍONS Eu3+ E Bi3+ NAS PROPRIEDADES FOTOLUMINESCENTE DA MATRIZ DE YVO4. Química Nova, v. 41, n. 8, p. 849-856, . (11/20313-8, 11/09823-4, 12/11673-3)
AZEVEDO, CAROLINE B.; BATISTA, TULIO M.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Nanospherical Silica as Luminescent Markers Obtained by Sol-Gel. Journal of Fluorescence, v. 25, n. 2, p. 433-440, . (12/11673-3, 11/15199-1, 11/09823-4)
DE CAMPOS, BEATRIZ M.; FREIRIA, GABRIELA S.; CIUFFI, KATIA J.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.; DE LIMA, MILTON S. F.. ITO Obtained by Spray Pyrolysis and Coating on Glass Substrate. Journal of the Brazilian Chemical Society, v. 28, n. 12, p. 2412-2420, . (12/11673-3, 12/22927-6, 11/15757-4, 13/22606-8)
MATOS, MARCELA G.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.; VERELST, MARC. Influence of Bi3+ ions on the excitation wavelength of the YVO4:Eu3+ matrix. Optical Materials, v. 62, p. 12-18, . (12/11673-3, 11/09823-4, 11/20313-8)
DE CAMPOS, BEATRIZ M.; CALEFI, PAULO S.; CIUFFI, KATIA J.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.; SILVA, JORGE V. L.; OLIVEIRA, MARCELO F.; MAIA, IZAQUE A.. Coating of polyamide 12 by sol-gel methodology. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 115, n. 2, p. 1029-1035, . (08/09695-3, 12/11673-3)
BALDAN, JR., HUGO; DA SILVA, EVANE; SALTARELLI, MICHELLE; CRISPIM, DENISE; NASSAR, EDUARDO J.; TRUJILLANO, RAQUEL; RIVES, VICENTE; VICENTE, MIGUEL A.; GIL, ANTONIO; KORILI, SOPHIA A.; et al. Inorganic-organic hybrids based on sepiolite as efficient adsorbents of caffeine and glyphosate pollutants. APPLIED SURFACE SCIENCE ADVANCES, v. 1, n. SI, . (16/01501-1, 05/00720-7, 12/11673-3, 13/19523-3, 11/03335-8, 18/26569-3, 17/15482-1)
DE ARAUJO, D. T.; DE PADUA, G. S.; PEIXOTO, V. G.; CIUFFI, K. J.; NASSAR, E. J.; VICENTE, M. A.; TRUJILLANO, R.; RIVES, V; PEREZ-BERNAL, M. E.; DE FARIA, E. H.. Luminescent properties of biohybrid (kaolinite-proline) materials synthesized by a new boric acid catalyzed route and complexed to Eu3+. APPLIED CLAY SCIENCE, v. 192, . (16/50322-2, 18/26569-3, 13/19523-3, 05/00720-7, 12/11673-3, 17/15482-1, 16/01501-1, 11/03335-8)
CLEMENTINO, F. C.; PEIXOTO, V. G.; DE ARAUJO, D. T.; CIUFFI, K. J.; NASSAR, E. J.; VICENTE, M. A.; RIVES, V.; DE FARIA, E. H.. Detection of Cr(III), prometryn, and ibuprofen by hybrid Eu(III)- dipicolinate kaolinite luminescent sensor. APPLIED CLAY SCIENCE, v. 227, p. 14-pg., . (17/15482-1, 17/01719-0, 18/26569-3, 12/11673-3, 16/01501-1, 11/03335-8, 13/19523-3)
DE LIMA, OMAR JOSE; DE ARAUJO, DENIS TALARICO; MARCAL, LIZIANE; MILLER CROTTI, ANTONIO EDUARDO; MACHADO, GUILHERME SIPPEL; NAKAGAKI, SHIRLEY; DE FARIA, EMERSON HENRIQUE; CIUFFI, KATIA JORGE. Photodegradation of Fipronil by Zn-AlPO4 Materials Synthesized by Non-Hydrolytic Sol-Gel Method. CHEMENGINEERING, v. 6, n. 4, p. 22-pg., . (20/06712-6, 12/11673-3, 17/15482-1, 05/00720-7, 13/19523-3, 11/03335-8, 16/01501-1)
PINOS, JESSICA YASMIN DE MORAIS; DE MELO, LETICIA BARBOSA; DE SOUZA, SUELEN DELFINO; MARCAL, LIZIANE; DE FARIA, EMERSON HENRIQUE. Bentonite functionalized with amine groups by the sol-gel route as efficient adsorbent of rhodamine-B and nickel (II). APPLIED CLAY SCIENCE, v. 223, p. 12-pg., . (17/15482-1, 12/11673-3, 16/01501-1, 11/03335-8, 13/19523-3, 05/00720-7)
DO PRADO, MARCUS VINICIUS; GONZALEZ, BEATRIZ; VICENTE, MIGUEL A.; TRUJILLANO, RAQUEL; NASSAR, EDUARDO JOSE; GIL, ANTONIO; SANTAMARIA, L.; KORILI, SOPHIA A.; MARCAL, LIZIANE; DE FARIA, EMERSON H.; et al. Multifunctional heterogeneous catalysts: Tetrakis(pentafluorophenyl) porphinato]iron(III) immobilized on amine-functionalized Diatomaceous Earth for catalytic and adsorption applications. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 11, n. 3, p. 11-pg., . (05/00720-7, 11/03335-8, 12/11673-3, 16/01501-1, 20/06712-6)
FERREIRA, CAMILA M. A.; FREIRIA, GABRIELA S.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Yttrium aluminum garnet coating on glass substrate. Journal of Luminescence, v. 170, n. 2, SI, p. 686-691, . (12/20908-4, 12/11673-3, 13/22606-8)
MATOS, MARCELA G.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CALEFI, PAULO S.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; VITORINO SARMENTO, VICTOR HUGO. Synthesis and photoluminescent properties of yttrium vanadate phosphor prepared by the non-hydrolytic sol-gel process. Journal of Luminescence, v. 147, p. 190-195, . (12/11673-3, 11/09823-4, 11/20313-8)
PEREIRA, PAULA F. S.; MATOS, MARCELA G.; FERREIRA, CAMILA M. A.; DE FARIA, EMERSON H.; CALEFI, PAULO S.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Aluminate matrix doped with Tm3+/Tb3+/Eu3+ obtained by non-hydrolytic sol-gel route: White light emission. Journal of Luminescence, v. 146, p. 394-397, . (12/11673-3, 12/20908-4, 11/09823-4, 11/20313-8)
MORA, LUCAS D.; BONFIM, LARISSA F.; BARBOSA, LORRANA V.; DA SILVA, TIAGO H.; NASSAR, EDUARDO J.; CIUFFI, KATIA J.; GONZALEZ, BEATRIZ; VICENTE, MIGUEL A.; TRUJILLANO, RAQUEL; RIVES, VICENTE; et al. White and Red Brazilian Sao Simao's Kaolinite-TiO2 Nanocomposites as Catalysts for Toluene Photodegradation from Aqueous Solutions. MATERIALS, v. 12, n. 23, . (12/11673-3, 13/19523-3, 17/15482-1)
RICCI, GUSTAVO PIMENTA; GARCIA, LARISSA OLIVEIRA; NASSAR, EDUARDO JOSE; NAKAGAKI, SHIRLEY; STIVAL, JOAO FELIPE; DA ROCHA, ZENIS NOVAES; VICENTE, MIGUEL ANGEL; TRUJILLANO, RAQUEL; JIMENEZ, ALEJANDRO; RIVES, VICENTE; et al. Non-hydrolytic sol-gel synthesis of mesoporous iron-aluminum oxide and their properties in the oxidation of hydrocarbons by hydrogen peroxide. Microporous and Mesoporous Materials, v. 325, . (13/19523-3, 05/00720-7, 17/15482-1, 12/11673-3, 16/01501-1, 11/03335-8, 16/50322-2)
DE ARAUJO, DENIS T.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; VICENTE, MIGUEL A.; TRUJILLANO, RAQUEL; RIVES, VICENTE; BERNAL, ELENA P.; DE FARIA, EMERSON H.. Grafting of L-proline and L-phenylalanine amino acids on kaolinite through synthesis catalyzed by boric acid. APPLIED SURFACE SCIENCE ADVANCES, v. 4, . (13/19523-3, 16/01501-1, 17/01719-0, 05/00720-7, 11/03335-8, 12/11673-3, 18/26569-3, 17/15482-1)
DA SILVA, ALEXANDRE FERNANDO; DE PADUA, GABRIEL SILVA; DE ARAUJO, DENIS TALARICO; VIEIRA, CARLOS ALEXANDRE; DE FARIA, EMERSON H.. Immobilization of L-alanine into natural kaolinite via amidation catalyzed by boric acid for the development of biohybrid materials. Journal of Solid State Chemistry, v. 287, . (13/19523-3, 05/00720-7, 12/11673-3, 17/15482-1, 16/01501-1, 11/03335-8)
PIZA FIGUEIREDO FERREIRA, ANA VERA DE TOLEDO; VIETRO BARBOSA, LORRANA; DELFINO DE SOUZA, SUELEN; JORGE CIUFFI, KATIA; ANGEL VICENTE, MIGUEL; TRUJILLANO, RAQUEL; KORILI, SOPHIA A.; GIL, ANTONIO; HENRIQUE DE FARIA, EMERSON. Titania-triethanolamine-kaolinite nanocomposites as adsorbents and photocatalysts of herbicides. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v. 419, . (12/11673-3, 13/19523-3, 17/15482-1)
DE SOUSA, EDUARDO P.; DE ARAUJO, DENIS T.; PEIXOTO, VINILSON G.; FERREIRA, BRENO F.; DE FARIA, EMERSON H.; MOLINA, EDUARDO F.. Effect of sodium bentonite content on structural-properties of ureasil poly (ethylene oxide)-PEO hybrid: A perspective for water treatment. APPLIED CLAY SCIENCE, v. 191, . (11/03335-8, 17/15482-1, 13/20455-2, 12/11673-3)
MIURA, BARBARA A.; FERREIRA, NATALIA H.; OLIVEIRA, POLLYANNA F.; DE FARIA, EMERSON H.; TAVARES, DENISE C.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Functionalization of luminescent YVO4:Eu3+ nanoparticles by sol-gel. Journal of Luminescence, v. 159, p. 93-99, . (12/24427-0, 11/21310-2, 12/11673-3, 11/09823-4, 11/15757-4)
SALTARELLI, MICHELLE; MATOS, MARCELA G.; DE FARIA, EMERSON H.; CIUFFI, KATIA J.; ROCHA, LUCAS A.; NASSAR, EDUARDO J.. Preparation of YVO4:Eu3+ at low temperature by the hydrolytic sol-gel methodology. Journal of Sol-Gel Science and Technology, v. 73, n. 2, p. 283-292, . (12/11673-3, 11/09823-4, 11/20313-8)
MATIAS, CARLOS R.; NASSAR, EDUARDO J.; VERELST, MARC; ROCHA, LUCAS A.. Synthesis and Characterization of Nb2O5:La3+,Eu3+ Phosphors Obtained by the Non-Hydrolytic Sol-Gel Process. Journal of the Brazilian Chemical Society, v. 26, n. 12, p. 2558-2570, . (11/15757-4, 11/09823-4, 12/11673-3)
FERREIRA, BRENO F.; DO PRADO, MARCUS V.; MARCAL, LIZIANE; CIUFFI, KATIA J.; VICENTE, MIGUEL A.; GIL, ANTONIO; DE FARIA, EMERSON H.. Manganese-sulfonato porphyrin adsorbed on amino kaolinite as heterogeneous catalyst for oxidation and polymerization reactions. APPLIED CLAY SCIENCE, v. 235, p. 10-pg., . (17/15482-1, 13/19523-3, 11/03335-8, 05/00720-7, 20/06712-6, 12/11673-3, 16/01501-1)
FERREIRA, CAMILA M. A.; FREIRIA, GABRIELA S.; DE FARIA, EMERSON H.; ROCHA, LUCAS A.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.. Yttrium aluminum garnet coating on glass substrate. Journal of Luminescence, v. 170, p. 6-pg., . (12/11673-3, 13/22606-8, 12/20908-4)

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