Materials with advanced technological and environmental applications

• Grant number: 16/50322-2
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2017
• End date: January 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Agreement: Universidad de Salamanca
• Mobility Program: SPRINT - Projetos de pesquisa - Mobilidade
• Principal Investigator: Katia Jorge Ciuffi Pires
• Grantee: Katia Jorge Ciuffi Pires
• Principal researcher abroad: Rafael Rives Arnau
• Institution abroad: Universidad de Salamanca (USAL), Spain
• Host Institution: Coordenadoria Adjunta de Graduação. Universidade de Franca (UNIFRAN). Franca , SP, Brazil
• Associated research grant: 16/01501-1 - Multifunctional catalysts for advanced oxidation processes employing biogenic matrices or clays, AP.R

Abstract

The main objective of this project, which will feature the collaboration of researchers from the University of Salamanca, Spain, is to synthesize and characterize multifunctional solid materials based on titanium and ironporphyrins with technological and environmental properties. The materials will be prepared from environmentally available arrays with low toxicity or no toxicity such as natural clays (from Brazil or Spain) and frustule silicate matrix of diatomaceous earth, affording materials that should act as effective catalysts in advanced oxidation reactions. Initially, clays and diatomaceous earth will be functionalized with organic groups by the sol-gel process. Then, second-generation ironporphyrins will be incorporated into these matrixes, to obtain a multifunctional catalyst for application in different reactions. The innovative nature of this project will be the use of diatoms (or diatomaceous earth) as Silicon source. After functionalization of the free silanol groups of the matrixes with organic groups by the sol-gel process and immobilization of second-generation ironporphyrins or titanium alkoxides on the solids, the materials will be directly used to treat wastewaters contaminated with emerging organic pollutants, especially ibuprofen and acetyl salicylic acid, and to catalyze the oxidation of cyclohexane and ketone (Baeyer Villiger reaction). It is intended, through this Sprint 2016, have great advances on these goals. (AU)

Scientific publications

(9)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

CINTRA, THAIS E.; SALTARELLI, MICHELLE; SALMAZO, ROSANGELA M. DE F.; DA SILVA, TIAGO HONORATO; NASSAR, EDUARDO J.; TRUJILLANO, RAQUEL; RIVES, VICENTE; VICENTE, MIGUEL A.; DE FARIA, EMERSON H.; CIUFFI, KATIA J.. Catalytic activity of porphyrin-catalyts immobilized on kaolinite. APPLIED CLAY SCIENCE, v. 168, p. 469-477, FEB 2019. (16/01501-1, 16/50322-2, 17/15482-1)

SALTARELLI, MICHELLE; DE FARIA, EMERSON H.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; TRUJILLANO, RAQUEL; RIVES, VICENTE; VICENTE, MIGUEL A.. Aminoiron(III)-porphyrin-alumina catalyst obtained by non-hydrolytic sol-gel process for heterogeneous oxidation of hydrocarbons. MOLECULAR CATALYSIS, v. 462, p. 114-125, JAN 2019. (16/50322-2, 16/01501-1, 13/19523-3, 12/08618-0)

VIEIRA, CARLOS ALEXANDRE; FERREIRA, BRENO F.; DA SILVA, ALEXANDRE FERNANDO; VICENTE, MIGUEL ANGEL; TRUJILLANO, RAQUEL; RIVES, VICENTE; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; DE FARIA, EMERSON H.. Adsorption-Based Synthesis of Environmentally Friendly Heterogeneous Chromium(III) Catalysts for Oxidation Reactions into Kaolinite, Saponite, and Their Amine-Modified Derivatives. ACS APPLIED NANO MATERIALS, v. 1, n. 8, p. 3867-3877, AUG 2018. (16/50322-2, 16/01501-1, 12/08618-0, 13/19523-3)

DA SILVA, TIAGO H.; RIBEIRO, ANDERSON O.; NASSAR, EDUARDO J.; TRUJILLANO, RAQUEL; RIVES, VICENTE; VICENTE, MIGUEL A.; DE FARIA, EMERSON H.; CIUFFI, KATIA J.. Kaolinite/TiO2/cobalt(II) Tetracarboxymetallophthalocyanine Nanocomposites as Heterogeneous Photocatalysts for Decomposition of Organic Pollutants Trimethoprim, Caffeine and Prometryn. Journal of the Brazilian Chemical Society, v. 30, n. 12, SI, p. 2610-2623, DEC 2019. (16/50322-2, 16/01501-1, 17/15482-1)

DE ARAUJO, D. T.; DE PADUA, G. S.; PEIXOTO, V. G.; CIUFFI, K. J.; NASSAR, E. J.; VICENTE, M. A.; TRUJILLANO, R.; RIVES, V; PEREZ-BERNAL, M. E.; DE FARIA, E. H.. Luminescent properties of biohybrid (kaolinite-proline) materials synthesized by a new boric acid catalyzed route and complexed to Eu3+. APPLIED CLAY SCIENCE, v. 192, JUL 2020. (16/50322-2, 18/26569-3, 13/19523-3, 05/00720-7, 12/11673-3, 17/15482-1, 16/01501-1, 11/03335-8)

FERREIRA, BRENO F.; CIUFFI, KATIA J.; NASSAR, EDUARDO J.; VICENTE, MIGUEL A.; TRUJILLANO, RAQUEL; RIVES, VICENTE; DE FARIA, EMERSON H.. Kaolinite-polymer compounds by grafting of 2-hydroxyethyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate. APPLIED CLAY SCIENCE, v. 146, p. 526-534, SEP 15 2017. (16/50322-2, 16/01501-1, 13/19523-3)

GONZALEZ, BEATRIZ; DA SILVA, TIAGO H.; CIUFFI, KATIA J.; VICENTE, MIGUEL A.; TRUJILLANO, RAQUEL; RIVES, VICENTE; DE FARIA, EMERSON H.; KORILI, SOPHIA A.; GIL, ANTONIO. Laponite functionalized with biuret and melamine - Application to adsorption of antibiotic trimethoprim. Microporous and Mesoporous Materials, v. 253, p. 112-122, NOV 15 2017. (16/50322-2, 16/01501-1, 13/19523-3)

GIL, A.; SANTAMARIA, L.; KORILI, S. A.; VICENTE, M. A.; BARBOSA, L. V.; DE SOUZA, S. D.; MARCAL, L.; DE FARIA, E. H.; CIUFFI, K. J.. A review of organic-inorganic hybrid clay based adsorbents for contaminants removal: Synthesis, perspectives and applications. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 5, OCT 2021. (13/19523-3, 16/50322-2, 17/15482-1)

RICCI, GUSTAVO PIMENTA; GARCIA, LARISSA OLIVEIRA; NASSAR, EDUARDO JOSE; NAKAGAKI, SHIRLEY; STIVAL, JOAO FELIPE; DA ROCHA, ZENIS NOVAES; VICENTE, MIGUEL ANGEL; TRUJILLANO, RAQUEL; JIMENEZ, ALEJANDRO; RIVES, VICENTE; et al. Non-hydrolytic sol-gel synthesis of mesoporous iron-aluminum oxide and their properties in the oxidation of hydrocarbons by hydrogen peroxide. Microporous and Mesoporous Materials, v. 325, OCT 2021. (13/19523-3, 05/00720-7, 17/15482-1, 12/11673-3, 16/01501-1, 11/03335-8, 16/50322-2)