Laser-Induced Breakdown Spectroscopy (LIBS) application in the analyses of electronic waste (printed circuit boards and polymers), food and difficult preparation liquid samples

• Grant number: 16/01513-0
• Support Opportunities: Regular Research Grants
• Start date: August 01, 2017
• End date: July 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Edenir Rodrigues Pereira Filho
• Grantee: Edenir Rodrigues Pereira Filho
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil

Abstract

This research project aims at combining the results obtained by inductively coupled optical emission spectrometry (ICP OES) and laser-induced breakdown spectroscopy (LIBS) for the analysis of various types of samples, such as electronic waste (batteries, polymers and electronic circuits) food (juices and fortified food), mineral supplements and also liquid samples that are difficult to prepare (oil and honey, for example). These samples have environmental and agro-industrial importance and the results will bring new information about their composition, as well as the generation methods with minimal or no sample preparation. In addition, chemometric tools for better understanding of the results and data processing will be used. (AU)

Scientific publications

(46)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

COSTA, VINICIUS CAMARA; DE BABOS, DIEGO VICTOR; BATISTA DE AQUINO, FRANCISCO WENDEL; VIRGILIO, ALEX; CARQUEIJA AMORIM, FABIO ALAN; PEREIRA-FILHO, EDENIR RODRIGUES. Direct Determination of Ca, K and Mg in Cassava Flour Samples by Laser-Induced Breakdown Spectroscopy (LIBS). FOOD ANALYTICAL METHODS, v. 11, n. 7, SI, p. 1886-1896, JUL 2018. (16/01513-0)

ANDRADE, DANIEL FERNANDES; MACHADO, RAQUEL CARDOSO; BACCHI, MARCIO ARRUDA; PEREIRA-FILHO, EDENIR RODRIGUES. Proposition of electronic waste as a reference material - part 1: sample preparation, characterization and chemometric evaluation. Journal of Analytical Atomic Spectrometry, v. 34, n. 12, p. 2394-2401, DEC 1 2019. (16/01513-0, 16/17304-0)

MACHADO, RAQUEL C.; ANDRADE, DANIEL F.; BABOS, V, DIEGO; CASTRO, JEYNE P.; COSTA, VINICIUS C.; SPERANCA, MARCO AURELIO; GARCIA, JOSE AUGUSTO; GAMELA, RAIMUNDO R.; PEREIRA-FILHO, EDENIR R.. Solid sampling: advantages and challenges for chemical element determination-a critical review. Journal of Analytical Atomic Spectrometry, v. 35, n. 1, p. 54-77, JAN 1 2020. (16/17221-8, 16/01513-0, 16/17304-0)

BABOS, DIEGO VICTOR; VIRGILIO, ALEX; COSTA, VINICIUS CAMARA; DONATI, GEORGE LUIS; PEREIRA-FILHO, EDENIR RODRIGUES. Multi-energy calibration (MEC) applied to laser-induced breakdown spectroscopy (LIBS). Journal of Analytical Atomic Spectrometry, v. 33, n. 10, p. 1753-1762, OCT 1 2018. (14/18393-1, 16/01513-0)

JIMENEZ, VICTORIA C.; MONFERRAN, MATEO D.; SPERANCA, MARCO A.; CASTRO, JEYNE P.; CATELANI, TIAGO A.; PELLERANO, ROBERTO G.; PERINO, ERNESTO; PEREIRA-FILHO, EDENIR R.; CABALERI, NORA G.; GALLEGO, OSCAR F.. Combination of analytic techniques to chemical characterization and preservation of Jurassic clam shrimp carapaces from La Matilde Formation, Patagonia. Journal of South American Earth Sciences, v. 109, AUG 2021. (14/22408-4, 12/01769-3, 16/17221-8, 16/01513-0)

NEIVA, ARIANE MACIEL; SPERANCA, MARCO AURELIO; COSTA, VINICIUS CAMARA; CHAGAS JACINTO, MANUEL ANTONIO; PEREIRA-FILHO, EDENIR RODRIGUES. Determination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium. ENVIRONMENTAL MONITORING AND ASSESSMENT, v. 190, n. 10, OCT 2018. (16/01513-0, 11/51564-6, 15/14488-0)

SPERANCA, MARCO AURELIO; VIRGILIO, ALEX; PEREIRA-FILHO, EDENIR RODRIGUES; BATISTA DE AQUINO, FRANCISCO WENDEL. Determination of Elemental Content in Solder Mask Samples Used in Printed Circuit Boards Using Different Spectroanalytical Techniques. Applied Spectroscopy, v. 72, n. 8, p. 1205-1214, AUG 2018. (14/18393-1, 13/04688-7, 16/01513-0)

CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES. Spectroanalytical method for evaluating the technological elements composition of magnets from computer hard disks. Talanta, v. 189, p. 205-210, NOV 1 2018. (14/22408-4, 16/17221-8, 16/01513-0, 12/01769-3)

VINICIUS C. COSTA; AMANDA S. AUGUSTO; JEYNE P. CASTRO; RAQUEL C. MACHADO; DANIEL F. ANDRADE; DIEGO V. BABOS; MARCO A. SPERANÇA; RAIMUNDO R. GAMELA; EDENIR R. PEREIRA-FILHO. LASER INDUCED-BREAKDOWN SPECTROSCOPY (LIBS): HISTÓRICO, FUNDAMENTOS, APLICAÇÕES E POTENCIALIDADES. Química Nova, v. 42, n. 5, p. 527-545, 2019-07-18. (16/17304-0, 14/11415-0, 16/17221-8, 16/01513-0)

ANDRADE, DANIEL FERNANDES; ROMANELLI, JOAO PAULO; PEREIRA-FILHO, EDENIR RODRIGUES. Past and emerging topics related to electronic waste management: top countries, trends, and perspectives. Environmental Science and Pollution Research, v. 26, n. 17, p. 17135-17151, JUN 2019. (16/17304-0, 16/01513-0)

GAMELA, RAIMUNDO R.; COSTA, VINICIUS C.; SPERANCA, MARCO A.; PEREIRA-FILHO, EDENIR R.. Laser-induced breakdown spectroscopy (LIBS) and wavelength dispersive X-ray fluorescence (WDXRF) data fusion to predict the concentration of K, Mg and P in bean seed samples. Food Research International, v. 132, JUN 2020. (16/01513-0)

COSTA, VINICIUS CAMARA; CASTRO, JEYNE PRICYLLA; ANDRADE, DANIEL FERNANDES; BABOS, DIEGO VICTOR; GARCIA, JOSE AUGUSTO; SPERANCA, MARCO AURELIO; CATELANI, TIAGO AUGUSTO; PEREIRA-FILHO, EDENIR RODRIGUES. Laser-induced breakdown spectroscopy (LIBS) applications in the chemical analysis of waste electrical and electronic equipment (WEEE). TRAC-TRENDS IN ANALYTICAL CHEMISTRY, v. 108, p. 65-73, NOV 2018. (16/17221-8, 16/17304-0, 16/01513-0)

AUGUSTO, AMANDA S.; CASTRO, JEYNE P.; SPERANCA, MARCO A.; PEREIRA-FILHO, EDENIR R.. Combination of Multi-Energy Calibration (MEC) and Laser-Induced Breakdown Spectroscopy (LIBS) for Dietary Supplements Analysis and Determination of Ca, Mg and K. Journal of the Brazilian Chemical Society, v. 30, n. 4, p. 804-812, APR 2019. (16/17221-8, 16/01513-0, 14/11415-0)

BABOS, DIEGO VICTOR; BARROS, ARIANE ISIS; NOBREGA, JOAQUIM ARAUJO; PEREIRA-FILHO, EDENIR RODRIGUES. Calibration strategies to overcome matrix effects in laser-induced breakdown spectroscopy: Direct calcium and phosphorus determination in solid mineral supplements. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, v. 155, p. 90-98, MAY 2019. (16/01513-0)

FABÍOLA MANHAS VERBI PEREIRA; EDENIR RODRIGUES PEREIRA-FILHO. APLICAÇÃO DE PROGRAMA COMPUTACIONAL LIVRE EM PLANEJAMENTO DE EXPERIMENTOS: UM TUTORIAL. Química Nova, v. 41, n. 9, p. 1061-1071, 2018-09-00. (16/00779-6, 16/01513-0, 17/05550-0)

COSTA, V. C.; FERREIRA, S. DOS SANTOS; SANTOS, L. N.; SPERANCA, M. A.; DA SILVA, C. SANTOS; SODRE, G. A.; PEREIRA-FILHO, E. R.. Qualitative and Quantitative Analysis of Soils Using Laser-Induced Breakdown Spectroscopy and Chemometrics Tools. Journal of Applied Spectroscopy, v. 87, n. 2, p. 378-386, MAY 2020. (16/01513-0)

RIBEIRO, MATHEUS C. S.; SENESI, GIORGIO S.; CABRAL, JADER S.; CENA, CICERO; MARANGONI, BRUNO S.; KIEFER, CHARLES; NICOLODELLI, GUSTAVO. Evaluation of rice varieties using LIBS and FTIR techniques associated with PCA and machine learning algorithms. APPLIED OPTICS, v. 59, n. 32, p. 10043-10048, NOV 10 2020. (16/01513-0)

CASTRO, JEYNE PRICYLLA; SPERANCA, MARCO AURELIO; BABOS, DIEGO VICTOR; ANDRADE, DANIEL FERNANDES; PEREIRA-FILHO, EDENIR RODRIGUES. Neodymium determination in hard drive disks magnets using different calibration approaches for wavelength dispersive X-ray fluorescence. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, v. 164, FEB 2020. (16/01513-0, 16/17304-0, 16/17221-8, 18/17753-5, 14/22408-4, 12/01769-3)

CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES. CHEMICAL EXPLORATORY ANALYSIS OF PRINTED CIRCUIT BOARD (PCB) USING INDUCTIVELY COUPLED PLASMA OPTICAL EMISSION SPECTROMETRY (ICP OES): DATA TREATMENT AND ELEMENTS CORRELATION. DETRITUS, v. 13, p. 131-139, DEC 2020. (16/17221-8, 12/01769-3, 14/22408-4, 18/17753-5, 16/01513-0)

COSTA, VINICIUS CAMARA; PEREIRA, FABIOLA MANHAS VERBI. Laser-induced breakdown spectroscopy applied to the rapid identification of different types of polyethylene used for toy manufacturing. JOURNAL OF CHEMOMETRICS, v. 34, n. 12, p. 8-pg., 2020-04-27. (16/01513-0, 19/01102-8, 18/18212-8)

COSTA, VINICIUS CAMARA; CARQUEIJA AMORIM, FABIO ALAN; DE BABOS, DIEGO VICTOR; PEREIRA-FILHO, EDENIR RODRIGUES. Direct determination of Ca, K, Mg, Na, P, S, Fe and Zn in bivalve mollusks by wavelength dispersive X-ray fluorescence (WDXRF) and laser-induced breakdown spectroscopy (LIBS). Food Chemistry, v. 273, p. 8-pg., 2019-02-01. (16/01513-0)

ARAUJO, ALISSON SILVA; CASTRO, JEYNE PRICYLLA; SPERANCA, MARCO AURELIO; ANDRADE, DANIEL FERNANDES; DE MELLO, MATHEUS LIMA; PEREIRA-FILHO, EDENIR RODRIGUES. Multiway Calibration Strategies in Laser-Induced Breakdown Spectroscopy: A Proposal. Analytical Chemistry, v. 93, n. 16, p. 10-pg., 2021-04-14. (16/01513-0, 16/17304-0, 16/17221-8, 19/24223-5)

COSTA, VINICIUS CAMARA; DE BABOS, DIEGO VICTOR; BATISTA DE AQUINO, FRANCISCO WENDEL; VIRGILIO, ALEX; CARQUEIJA AMORIM, FABIO ALAN; PEREIRA-FILHO, EDENIR RODRIGUES. Direct Determination of Ca, K and Mg in Cassava Flour Samples by Laser-Induced Breakdown Spectroscopy (LIBS). FOOD ANALYTICAL METHODS, v. 11, n. 7, p. 11-pg., 2018-07-01. (16/01513-0)

COSTA, VINICIUS CAMARA; CARQUEIJA AMORIM, FABIO ALAN; DE BABOS, DIEGO VICTOR; PEREIRA-FILHO, EDENIR RODRIGUES. Direct determination of Ca, K, Mg, Na, P, S, Fe and Zn in bivalve mollusks by wavelength dispersive X-ray fluorescence (WDXRF) and laser-induced breakdown spectroscopy (LIBS). Food Chemistry, v. 273, n. SI, p. 91-98, FEB 1 2019. (16/01513-0)

COSTA, VINICIUS CAMARA; PEREIRA, FABIOLA MANHAS VERBI. Laser-induced breakdown spectroscopy applied to the rapid identification of different types of polyethylene used for toy manufacturing. JOURNAL OF CHEMOMETRICS, v. 34, n. 12, SI, APR 2020. (19/01102-8, 16/01513-0, 18/18212-8)

MACHADO, RAQUEL C.; BABOS, DIEGO VICTOR; ANDRADE, DANIEL F.; PEREIRA-FILHO, EDENIR RODRIGUES. A novel strategy for direct elemental determination using laser-induced breakdown spectroscopy: fluence calibration. Journal of Analytical Atomic Spectrometry, v. 36, n. 10, JUL 2021. (16/17304-0, 19/24223-5, 16/01513-0)

ALEXANDRINA, EDUARDO CARLOS; BABOS, DIEGO VICTOR; ANDRADE, DANIEL FERNANDES; COSTA, VINICIUS CAMARA; LUI, ELAINE SCHORNOBAY; CORREA, NIVALDO APARECIDO; AGUIAR, MONICA LOPES; PEREIRA-FILHO, EDENIR RODRIGUES. Particulate matter (PM10) from Sao Carlos-SP (Brazil): spectroanalytical techniques to evaluate and determine chemical elements. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, v. 99, n. 7, MAY 2019. (16/01513-0, 12/14928-2, 16/17304-0)

BABOS, DIEGO VICTOR; COSTA, VINICIUS CAMARA; PEREIRA-FILHO, EDENIR RODRIGUES. Wavelength dispersive X-ray fluorescence (WD-XRF) applied to speciation of sulphur in mineral supplement for cattle: Evaluation of the chemical and matrix effects. Microchemical Journal, v. 147, p. 628-634, JUN 2019. (16/01513-0)

RAIMUNDO R. GAMELA; VINICIUS C. COSTA; MATHEUS L. DE MELLO; JULIA C. ROMERO; FÁBIO A. C. AMORIM; EDENIR R. PEREIRA-FILHO. Multivariate Analysis: Use of Doehlert Design (DD) for Optimization of a Simple Sample Preparation Procedure for the Determination of Inorganic Constituents in Cocoa Beans Employing Microwave Acid Digestion and ICP OES. Journal of the Brazilian Chemical Society, v. 31, n. 10, p. 2082-2090, 2020-10-09. (16/01513-0)

BABOS, DIEGO VICTOR; CASTRO, JEYNE PRICYLLA; ANDRADE, DANIEL FERNANDES; COSTA, VINICIUS CAMARA; PEREIRA-FILHO, EDENIR RODRIGUES. Determination and speciation of phosphorus in fertilizers and mineral supplements for cattle by X-ray absorption near-edge structure spectroscopy: a simple nondestructive method. ANALYTICAL METHODS, v. 11, n. 11, p. 1508-1515, MAR 21 2019. (16/17221-8, 16/01513-0, 16/17304-0)

ANDRADE, DANIEL FERNANDES; FORTUNATO, FELIPE MANFROI; PEREIRA-FILHO, EDENIR RODRIGUES. Calibration strategies for determination of the In content in discarded liquid crystal displays (LCD) from mobile phones using laser-induced breakdown spectroscopy (LIBS). Analytica Chimica Acta, v. 1061, p. 42-49, JUL 11 2019. (16/01513-0, 16/17304-0)

COSTA, VINICIUS CAMARA; BATISTA AQUINO, FRANCISCO WENDEL; PARANHOS, CAIO MARCIO; PEREIRA-FILHO, EDENIR RODRIGUES. Use of laser-induced breakdown spectroscopy for the determination of polycarbonate (PC) and acrylonitrile-butadiene-styrene (ABS) concentrations in PC/ABS plastics from e-waste. WASTE MANAGEMENT, v. 70, p. 212-221, DEC 2017. (13/04688-7, 16/01513-0)

FIGUEIREDO, CAIO M.; CASTRO, JEYNE P.; SPERANCA, MARCO A.; FIALHO, LUCIMAR L.; NOBREGA, JOAQUIM A.; PEREIRA-FILHO, EDENIR R.. Qualitative and Quantitative Chemical Investigation of Orthopedic Alloys by Combining Wet Digestion, Spectroanalytical Methods and Direct Solid Analysis. Journal of the Brazilian Chemical Society, v. 29, n. 4, p. 680-688, APR 2018. (14/22408-4, 16/17221-8, 16/01513-0)

BABOS, DIEGO VICTOR; COSTA, VINICIUS CAMARA; SPERANCA, MARCO AURELIO; PEREIRA-FILHO, EDENIR RODRIGUES. Direct determination of calcium and phosphorus in mineral supplements for cattle by wavelength dispersive X-ray fluorescence (WD-XRF). Microchemical Journal, v. 137, p. 272-276, MAR 2018. (16/01513-0)

SPERANCA, MARCO AURELIO; ANDRADE, DANIEL FERNANDES; CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES. Univariate and multivariate calibration strategies in combination with laser-induced breakdown spectroscopy (LIBS) to determine Ti on sunscreen: A different sample preparation procedure. OPTICS AND LASER TECHNOLOGY, v. 109, p. 648-653, JAN 2019. (16/01513-0, 16/17304-0, 16/17221-8)

VINICIUS C. COSTA; DIEGO V. BABOS; JEYNE P. CASTRO; DANIEL F. ANDRADE; RAIMUNDO R. GAMELA; RAQUEL C. MACHADO; MARCO A. SPERANÇA; ALISSON S. ARAÚJO; JOSÉ A. GARCIA; EDENIR R. PEREIRA-FILHO. Calibration Strategies Applied to Laser-Induced Breakdown Spectroscopy: A Critical Review of Advances and Challenges. Journal of the Brazilian Chemical Society, v. 31, n. 12, p. 2439-2451, 2020-12-14. (16/17221-8, 18/17753-5, 19/24223-5, 16/01513-0, 18/24569-6, 16/17304-0)

ANDRADE, DANIEL FERNANDES; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Current trends in laser-induced breakdown spectroscopy: a tutorial review. APPLIED SPECTROSCOPY REVIEWS, v. 56, n. 2, MAR 2020. (18/24569-6, 16/17304-0, 16/01513-0)

ANDRADE, DANIEL FERNANDES; MACHADO, RAQUEL CARDOSO; PEREIRA-FILHO, EDENIR RODRIGUES. Proposition of electronic waste as a reference material - part 2: homogeneity, stability, characterization, and uncertainties. Journal of Analytical Atomic Spectrometry, v. 34, n. 12, p. 2402-2410, DEC 1 2019. (16/01513-0, 16/17304-0)

CASTRO, JEYNE PRICYLLA; BABOS, DIEGO VICTOR; PEREIRA-FILHO, EDENIR RODRIGUES. Calibration strategies for the direct determination of rare earth elements in hard disk magnets using laser-induced breakdown spectroscopy. Talanta, v. 208, FEB 1 2020. (16/17221-8, 14/22408-4, 16/01513-0, 12/01769-3)

CASTRO, JEYNE PRICYLLA; PEREIRA-FILHO, EDENIR RODRIGUES; BRO, RASMUS. Laser-induced breakdown spectroscopy (LIBS) spectra interpretation and characterization using parallel factor analysis (PARAFAC): a new procedure for data and spectral interference processing fostering the waste electrical and electronic equipment (WEEE) recycling process. Journal of Analytical Atomic Spectrometry, v. 35, n. 6, p. 1115-1124, JUN 1 2020. (16/01513-0, 16/17221-8, 18/17753-5, 14/22408-4, 12/01769-3)

GAMELA, RAIMUNDO R.; SPERANCA, MARCO A.; ANDRADE, DANIEL F.; PEREIRA FILHO, EDENIR R.. Hyperspectral images: a qualitative approach to evaluate the chemical profile distribution of Ca, K, Mg, Na and P in edible seeds employing laser-induced breakdown spectroscopy. ANALYTICAL METHODS, v. 11, n. 43, p. 5543-5552, NOV 21 2019. (16/17304-0, 16/01513-0)

COSTA, VINICIUS C.; PINHEIRO, FERNANDA C.; AMORIM, FABIO ALAN C.; PARANHOS DA SILVA, ERIK G.; PEREIRA-FILHO, EDENIR R.. Multivariate optimization for the development of a sample preparation procedure and evaluation of calibration strategies for nutrient elements determination in handmade chocolate. Microchemical Journal, v. 150, NOV 2019. (16/01513-0)

ZANETTI, T. C.; CATELANI, T. A.; PEREIRA-FILHO, E. R.; CABRAL, J. S.. Laser-induced breakdown spectroscopy as a tool for homogeneity measurements in medicine tablets. Laser Physics, v. 30, n. 3, MAR 2020. (16/01513-0)

NEIVA, ARIANE MACIEL; PEREIRA-FILHO, EDENIR RODRIGUES. Evaluation of the Chemical Composition of Synthetic Leather Using Spectroscopy Techniques. Applied Spectroscopy, v. 72, n. 6, p. 921-932, JUN 2018. (11/51564-6, 15/14488-0, 16/01513-0)

ANDRADE, DANIEL FERNANDES; DE ALMEIDA, EDUARDO; PEREIRA DE CARVALHO, HUDSON WALLACE; PEREIRA-FILHO, EDENIR RODRIGUES; AMARASIRIWARDENA, DULASIRI. Chemical inspection and elemental analysis of electronic waste using data fusion - Application of complementary spectroanalytical techniques. Talanta, v. 225, APR 1 2021. (16/01513-0, 15/05942-0, 16/17304-0, 18/24569-6, 19/24223-5)

VICTOR BABOS, DIEGO; CRUZ-CONESA, ANDRES; PEREIRA-FILHO, EDENIR RODRIGUES; ANZANO, JESUS M.. Direct determination of Al and Pb in waste printed circuit boards (PCB) by laser-induced breakdown spectroscopy (LIBS): Evaluation of calibration strategies and economic - environmental questions. JOURNAL OF HAZARDOUS MATERIALS, v. 399, NOV 15 2020. (16/01513-0)