Synthesis, characterization and application of new adsorbents obtained from mesoporous silica

• Grant number: 09/12189-5
• Support Opportunities: Scholarships in Brazil - Master
• Effective date (Start): March 01, 2010
• Effective date (End): July 31, 2011
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Yoshitaka Gushikem
• Grantee: Natália Fattori
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated research grant: 08/53868-0 - Synthesis and chacterization of novel materials strategically structured and organized to be applied in analytical and photonic devices, AP.TEM

Abstract

The aim of this research project is the development of adsorbent materials based on mesoporous silica supports, organofuncionalized with different structural characteristics. Two substrates will be synthesized in order to obtain the silica with a disordered pore structure, randomly distributed throughout the inorganic network, and a second material consisting of highly ordered pores in the form of cylindrical channels, packed into hexagonal arrangement (SBA-15). The substrate surfaces will be functionalized by immobilization reactions of 4,4'bipyridine linked to an array of silsesquioxane, both monosubstituted, Si(CH2)3X+Cl-, and disubstituted forms[Si(CH2)3]2X2+(Cl-)2, (X = 4,4' bipiridina). The resulting material will be evaluated as ions adsorbents in ethanol, and it will be the basis for the interactions study of these systems. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

FATTORI, NATALIA; MARONEZE, CAMILA M.; MAGOSSO, HERICA A.; KHOLIN, YURIY V.; GUSHIKEM, YOSHITAKA. Highly-controlled grafting of mono and dicationic 4,4 `-bipyridine derivatives on SBA-15 for potential application as adsorbent of CuCl2 from ethanol solution. Journal of Colloid and Interface Science, v. 384, p. 137-142, OCT 15 2012. (09/12189-5)

FATTORI, NATALIA; MARONEZE, CAMILA M.; MAGOSSO, HERICA A.; KHOLIN, YURIY V.; GUSHIKEM, YOSHITAKA. Highly-controlled grafting of mono and dicationic 4,4 '-bipyridine derivatives on SBA-15 for potential application as adsorbent of CuCl2 from ethanol solution. Journal of Colloid and Interface Science, v. 384, p. 6-pg., 2012-10-15. (09/12189-5)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

FATTORI, Natália. Synthesis, characterization and application of new adsorbents materials obtained from chemically modified mesoporous silicas. 2011. Master's Dissertation - Universidade Estadual de Campinas (UNICAMP). Instituto de Química Campinas, SP.