Petroleomics by FT-MS: New Strategies for Characterization by Pre-fractionation of contaminated and emulsified oils

• Grant number: 13/19161-4
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date: December 01, 2013
• End date: February 28, 2017
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Marcos Nogueira Eberlin
• Grantee: Jandyson Machado Santos
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated scholarship(s): 15/05818-7 - Petroleomics by FT-MS: comprehensive analysis of crude oils using SARA fractionation with emphasis in asphaltenes and resins characterization, BE.EP.DR

Abstract

Known as one of the most complex matrices of chemical characterization, crude oil is considered one of the most important mixtures used on modern society. In the effort of meeting the need for more comprehensive characterization of crude oils and derivatives, the recent field called Petroleomics has resolved and characterized through advanced techniques on mass spectrometry (MS) the composition of thousands of CcHhNnOoSs type compounds in these matrices. Due to the small number of studies in the literature, in special regarding to studies of crude oils of Brazilian sedimentary basins, this project proposes in its first stage, a novel work in the application of SARA fractionation (Saturates, Aromatics, Resins and Asphaltenes) in onshore and offshore crude oils with different API degrees, and studies of these fractions through ultra-high resolution and accuracy MS technique of Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) using electrospray (ESI) as the ionization source . As scientific and technological innovation is proposed in a second step the characterization of emulsified crude oils by ESI FT-ICR MS, seeking an investigation of the chemical composition that influences the formation and stabilization of emulsions in crude oils, revealing again the study's originality, as there are no reports in the literature of that kind of study with Brazilian crude oils at the moment. Therefore, this project aims by its two steps, to scientific and technological innovations in all upstream steps of the oil industry, mainly involving the exploration, drilling, production and transportation, with the development of procedures at the forefront of knowledge aimed at national petrochemical matrices.

Scientific publications

(15)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

FERREIRA, JORDANA ALVES; SANTOS, JANDYSON MACHADO; BREITKREITZ, MARCIA CRISTINA; SANTOS FERREIRA, JOANA MARIA; PONTES LINS, PAULO MANOEL; FARIAS, SAMUEL COHEN; DE MORAIS, DAMILA RODRIGUES; EBERLIN, MARCOS NOGUEIRA; GRESPAN BOTTOLI, CARLA BEATRIZ. Characterization of the lipid profile from coconut (Cocos nucifera L.) oil of different varieties by electrospray ionization mass spectrometry associated with principal component analysis and independent component analysis. Food Research International, v. 123, p. 189-197, SEP 2019. (13/19161-4, 16/23157-0, 12/18318-4)

PUDENZI, MARCOS ALBIERI; SANTOS, JANDYSON MACHADO; WISNIEWSKI, JR., ALBERTO; EBERLIN, MARCOS NOGUEIRA. Comprehensive Characterization of Asphaltenes by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Precipitated under Different n-Alkanes Solvents. ENERGY & FUELS, v. 32, n. 2, p. 1038-1046, FEB 2018. (13/19161-4)

CORREA, DELEON N.; SANTOS, JANDYSON M.; EBERLIN, LIVIA S.; EBERLIN, MARCOS N.; TEUNISSEN, SEBASTIAAN F.. Forensic Chemistry and Ambient Mass Spectrometry: A Perfect Couple Destined for a Happy Marriage?. Analytical Chemistry, v. 88, n. 5, p. 2515-2526, MAR 1 2016. (13/19161-4)

KATAOKA, ERICA M.; MURER, RUI C.; SANTOS, JANDYSON M.; CARVALHO, ROGERIO M.; EBERLIN, MARCOS N.; AUGUSTO, FABIO; POPPI, RONEI J.; GOBBI, ANGELO L.; HANTAO, LEANDRO W.. Simple, Expendable, 3D-Printed Microfluidic Systems for Sample Preparation of Petroleum. Analytical Chemistry, v. 89, n. 6, p. 3460-3467, MAR 21 2017. (13/19161-4, 15/05059-9, 14/00228-4)

SANTOS, JANDYSON M.; PUDENZI, MARCOS A.; WISNIEWSKI, JR., ALBERTO; BREITKREITZ, MARCIA C.; EBERLIN, MARCOS N.. Optimization of Atmospheric Pressure Photoionization for the Crude Oil Analysis Using Ultra-High Resolution Mass Spectrometry. Journal of the Brazilian Chemical Society, v. 30, n. 4, p. 819-829, APR 2019. (13/19161-4)

SANTOS, JANDYSON M.; VETERE, ALESSANDRO; WISNIEWSKI, ALBERTO; EBERLIN, MARCOS N.; SCHRADER, WOLFGANG. Modified SARA Method to Unravel the Complexity of Resin Fraction(es) in Crude Oil. ENERGY & FUELS, v. 34, n. 12, p. 16006-16013, DEC 17 2020. (13/19161-4, 15/05818-7)

ZANQUI, ANA B.; DA SILVA, CLAUDIA; RESSUTTE, JESSICA; DE MORAIS, DAMILA; SANTOS, JANDYSON M.; EBERLIN, MARCOS; CARDOZO-FILHO, LUCIO; VISENTAINER, JESUI V.; GOMES, SANDRA T. M.; MATSUSHITA, MAKOTO. Brazil Nut Oil Extraction Using Subcritical n-Propane: Advantages and Chemical Composition. Journal of the Brazilian Chemical Society, v. 31, n. 3, p. 603-612, MAR 2020. (13/19161-4)

ZANQUI, ANA BEATRIZ; DA SILVA, CLAUDIA MARQUES; RESSUTTE, JESSICA BARRIONUEVO; DE MORAIS, DAMILA RODRIGUES; SANTOS, JANDYSON MACHADO; EBERLIN, MARCOS NOGUEIRA; CARDOZO-FILHO, LUCIO; DA SILVA, EDSON ANTONIO; MARQUES GOMES, SANDRA TEREZINHA; MATSUSHITA, MAKOTO. Extraction and assessment of oil and bioactive compounds from cashew nut (Anacardium occidentale) using pressurized n-propane and ethanol as cosolvent. JOURNAL OF SUPERCRITICAL FLUIDS, v. 157, MAR 1 2020. (13/19161-4)

SANTOS, JANDYSON MACHADO; LEMOS SANTOS, FLAVIA MICAELLA; EBERLIN, MARCOS NOGUEIRA; WISNIEWSKI, JR., ALBERTO. Advanced Aspects of Crude Oils Correlating Data of Classical Biomarkers and Mass Spectrometry Petroleomics. ENERGY & FUELS, v. 31, n. 2, p. 1208-1217, FEB 2017. (13/19161-4)

DOS SANTOS, FABIO N.; SANTOS, JANDYSON M.; MESQUITA, PAULO R. R.; OLIVEIRA, KARLA B.; RODRIGUES, FREDERICO M.; LOPES, WILSON A.; EBERLIN, MARCOS N.. Immediate differentiation of unusual seed oils by easy ambient sonic-spray ionization mass spectrometry and chemometric analysis. ANALYTICAL METHODS, v. 8, n. 18, p. 3681-3690, 2016. (13/19161-4)

SANTOS, JANDYSON M.; DOS SANTOS, LUANA O.; SILVA, FERNANDA F.; EBERLIN, MARCOS N.; WISNIEWSKI, JR., ALBERTO. Comprehensive Characterization of Second-Generation Biofuel from Invasive Freshwater Plants by FT-ICR MS. BioEnergy Research, v. 8, n. 4, p. 1938-1945, DEC 2015. (13/19161-4)

ZANQUI, ANA BEATRIZ; DA SILVA, CLAUDIA MARQUES; DE MORAIS, DAMILA RODRIGUES; SANTOS, JANDYSON MACHADO; OENNING RIBEIRO, SUELLEN ANDRESSA; EBERLIN, MARCOS NOGUEIRA; CARDOZO-FILHO, LUCIO; VISENTAINER, JESUI VERGILIO; MARQUES GOMES, SANDRA TEREZINHA; MATSUSHITA, MAKOTO. Sacha inchi (Plukenetia volubilis L.) oil composition varies with changes in temperature and pressure in subcritical extraction with n-propane. INDUSTRIAL CROPS AND PRODUCTS, v. 87, p. 64-70, SEP 2016. (13/19161-4)

SANTOS, JANDYSON M.; VENDRAMINI, PEDRO H.; SCHWAB, NICOLAS V.; EBERLIN, MARCOS N.; DE MORAIS, DAMILA R.. A dopant for improved sensitivity in easy ambient sonic-spray ionization mass spectrometry. Journal of Mass Spectrometry, v. 51, n. 1, p. 53-61, JAN 2016. (13/19161-4)

ZANQUI, ANA B.; DE MORAIS, DAMILA R.; DA SILVA, CLAUDIA M.; SANTOS, JANDYSON M.; CHIAVELLI, LUCAS U. R.; BITTENCOURT, PAULO R. S.; EBERLIN, MARCOS N.; VISENTAINER, JESUI V.; CARDOZO-FILHO, LUCIO; MATSUSHITA, MAKOTO. Subcritical Extraction of Salvia hispanica L. Oil with N-Propane: Composition, Purity and Oxidation Stability as Compared to the Oils Obtained by Conventional Solvent Extraction Methods. Journal of the Brazilian Chemical Society, v. 26, n. 2, p. 282-289, FEB 2015. (13/19161-4)

SANTOS, JANDYSON MACHADO; GALAVERNA, RENAN DE S.; PUDENZI, MARCOS A.; SCHMIDT, EDUARDO M.; SANDERS, NATHANIEL L.; KURULUGAMA, RUWAN T.; MORDEHAI, ALEX; STAFFORD, GEORGE C.; WISNIEWSKI, JR., ALBERTO; EBERLIN, MARCOS N.. Petroleomics by ion mobility mass spectrometry: resolution and characterization of contaminants and additives in crude oils and petrofuels. ANALYTICAL METHODS, v. 7, n. 11, p. 4450-4463, 2015. (13/19161-4)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

SANTOS, Jandyson Machado. New approaches in petroleomics by FT-MS employed in crude oils with different physicochemical characteristics. 2017. Doctoral Thesis - Universidade Estadual de Campinas (UNICAMP). Instituto de Química Campinas, SP.