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Preparation of solid-stabilized heteroarilzinc salts for application in functionalized heterocyclic compounds synthesis

Grant number: 14/13869-8
Support Opportunities:Scholarships in Brazil - Scientific Initiation
Effective date (Start): August 01, 2014
Effective date (End): July 31, 2015
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Giuliano Cesar Clososki
Grantee:Bárbara Soares da Silva Rossato
Host Institution: Faculdade de Ciências Farmacêuticas de Ribeirão Preto (FCFRP). Universidade de São Paulo (USP). Ribeirão Preto , SP, Brazil


The main objective of this project is to synthesize solid-stabilized heteroarylzinc reagents to be used in Negishi cross-coupling reaction with various heteroaromatic halides under microwave irradiation. Furthermore, the application of these reagents in microwave-assisted carbonyl addition reactions will be also investigated.

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