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Cs-based lead perovskite nanocrystals nucleation and growth studies via in situ SAXS and WAXS.

Grant number: 17/11019-5
Support Opportunities:Scholarships abroad - Research Internship - Master's degree
Effective date (Start): September 01, 2017
Effective date (End): February 28, 2018
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
Principal Investigator:Ana Flávia Nogueira
Grantee:Raphael Fernando Moral
Supervisor: Michael Toney
Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Research place: SLAC National Accelerator Laboratory, United States  
Associated to the scholarship:16/02268-9 - Hybrid nanocomposites composed of cesium lead-halide perovskite quantum dots and semiconducting polymers for third generation solar cells, BP.MS

Abstract

Cs-based lead perovskites nanocrystals (CsPbX3) will be synthesized in situ in a x-ray beam line from synchrotron source to evaluate their growth from the precursors. The precursors will be dissolved in a vessel and heated. The growth of the nanocrystals will be probed via SAXS and WAXS. The purpose is to elucidate the growth mechanism of these nanocrystals, a pioneer work in the literature.

News published in Agência FAPESP Newsletter about the scholarship:
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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MORAL, RAPHAEL F.; BONATO, LUIZ GUSTAVO; GERMINO, JOSE CARLOS; COELHO OLIVEIRA, WILLIAN XERXES; KAMAT, RUPINI; XU, JUNWEI; TASSONE, CHRISTOPHER J.; STRANKS, SAMUEL D.; TONEY, MICHAEL F.; NOGUEIRA, ANA FLAVIA. Synthesis of Polycrystalline Ruddlesden-Popper Organic Lead Halides and Their Growth Dynamics. CHEMISTRY OF MATERIALS, v. 31, n. 22, p. 9472-9479, . (16/02268-9, 17/11986-5, 17/11019-5)

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