Structural similarity of the humic substances from hydrochar obtained from vinasse and sugarcane bagasse with the Black Earth (TPI)

• Grant number: 17/05575-2
• Support Opportunities: Scholarships in Brazil - Master
• Effective date (Start): August 01, 2017
• Effective date (End): June 30, 2019
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Acordo de Cooperação: Coordination of Improvement of Higher Education Personnel (CAPES)
• Principal Investigator: Márcia Cristina Bisinoti
• Grantee: Lucas Raimundo Bento
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil
• Associated scholarship(s): 17/17991-0 - Molecular characterization of the humic substances from "Terra Preta de Indio" soils and hydrochar from sugarcane wastes" by Humeomics, BE.EP.MS

Abstract

The agro-industry is responsible for producing large amounts of waste in the world, and the Brazilian sugarcane industries are responsible for the generation of 149 million tons of sugarcane bagasse and 10 billion liters of vinasse. The "Terra Preta de Indio" (TPI) or Amazonian Dark Earth are soils known for their high fertility, this soil has a large amount of organic matter formed by a binary mixture of pyrogenic carbon and polycondensed and functionalized structures, formed by the burning of animal and plants wastes the indigenous population. Studies have shown that hydrothermal carbonization (HTC) of biomass produces a recalcitrant carbon rich material, called hydrochar. The process employs temperatures around 300 oC, humid biomass and self-generated pressures. The objective this study will be to characterize structurally the humic substances (HS) extracted from the hydrochars produced from HTC with wastes from the sugarcane industry in different conditions with the HS of the TPI soils. The HS will be extracted from four hydrochars produced from the HTC, TPI soil profile and adjacent area profile, a total of 14 samples. HS will be characterized using UV-VIS, Molecular Fluorescence, NMR, FTIR, TGA and CHNS techniques. Soil and hydrochars samples will be characterized by 13C NMR, FTIR, TGA, DRX and CHNS. Calcium, magnesium, iron and potassium will be quantified by Atomic Absorption Spectrophotometry with Flame Atomization and also total phosphorus by UV-VIS. A granulometric analysis and pH measurement will be performed. The recalcitrance of hydrochar and TPI soils in terms of pyrogenic carbon will be evaluated. It is expected with the structural characterization of SH from TPI and hydrochars to infer whats the condition of hydrochar production that provides structural characteristics similar to TPI soils. (AU)

Scientific publications

(4)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

BENTO, LUCAS RAIMUNDO; SPACCINI, RICCARDO; CANGEMI, SILVANA; MAZZEI, PIERLUIGI; DE FREITAS, BIANCA BORGE; OLIVEIRA DE SOUZA, ANDRESSA EVA; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; PICCOLO, ALESSANDRO; BISINOTI, MARCIA CRISTINA. Hydrochar obtained with by-products from the sugarcane industry: Molecular features and effects of extracts on maize seed germination. Journal of Environmental Management, v. 281, MAR 1 2021. (18/15733-7, 17/17991-0, 17/05575-2)

DA SILVA, LEILA SOARES; CONSTANTINO, ISABELA CARREIRA; BENTO, LUCAS RAIMUNDO; TADINI, AMANDA MARIA; BISINOTI, MARCIA CRISTINA; BOSCOLO, MAURICIO; FERREIRA, ODAIR PASTOR; MOUNIER, STEPHANE; PICCOLO, ALESSANDRO; SPACCINI, RICCARDO; et al. Humic extracts from hydrochar and Amazonian Anthrosol: Molecular features and metal binding properties using EEM-PARAFAC and 2D FTIR correlation analyses. Chemosphere, v. 256, OCT 2020. (15/22954-1, 17/26718-6, 17/05575-2)

BENTO, LUCAS R.; CONSTANTINO, ISABELA C.; TADINI, AMANDA M.; MELO, CAMILA A.; FERREIRA, ODAIR P.; MOREIRA, ALTAIR B.; BISINOTI, MARCIA C.. Chemical and Spectroscopic Characteristics of Anthrosol (Amazonian Dark Earth) and Surrounding Soil from the Brazilian Amazon Forest: Evaluation of Mineral and Organic Matter Content by Depth. Journal of the Brazilian Chemical Society, v. 31, n. 8, p. 1623-1634, AUG 2020. (15/22954-1, 18/15733-7, 17/05575-2)

BENTO, LUCAS RAIMUNDO; MELO, CAMILA ALMEIDA; FERREIRA, ODAIR PASTOR; MOREIRA, ALTAIR BENEDITO; MOUNIER, STEPHANE; PICCOLO, ALESSANDRO; SPACCINI, RICCARDO; BISINOTI, MARCIA CRISTINA. Humic extracts of hydrochar and Amazonian Dark Earth: Molecular characteristics and effects on maize seed germination. Science of The Total Environment, v. 708, MAR 15 2020. (15/22954-1, 18/15733-7, 17/05575-2, 17/17991-0)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

BENTO, Lucas Raimundo. Structural similarity of humic substances from hydrochar obtained from vinasse and sugarcane bagasse with those of the Amazonian dark earth. 2019. Master's Dissertation - Universidade Estadual Paulista (Unesp). Instituto de Biociências Letras e Ciências Exatas. São José do Rio Preto São José do Rio Preto.