Study of Surface-Mounted Metal-Organic Frameworks (SURMOFs) growth mechanisms to application on electrical devices

• Grant number: 19/01561-2
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• Start date: May 15, 2019
• End date: May 14, 2020
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
• Principal Investigator: Carlos César Bof Bufon
• Grantee: Tatiana Parra Vello
• Supervisor: Christof Woll
• Host Institution: Centro Nacional de Pesquisa em Energia e Materiais (CNPEM). Ministério da Ciência, Tecnologia e Inovação (Brasil). Campinas , SP, Brazil
• Institution abroad: Karlsruhe Institute of Technology (KIT), Germany
• Associated to the scholarship: 16/25346-5 - Capacitive devices for hybrid nanostructures characterization: study of electrical properties of surface metal-organic frameworks -SURMOFs- and metallophthalocyanines, BP.DR

Abstract

Surface Metal-Organic Frameworks (SURMOFs) is a new class of nanostructured materials based on the tridimensional networks of metallic clusters and organic ligands. These structures have important characteristics such as crystalline orientation, high porosity and superficial area. In the recent years, SURMOFs films have been applied in electrical devices as a mainly component. However, there are just a few works in literature about the study of electrical properties of SURMOF thin films (<50 nm), since their incorporation in electrical devices is still a challenge. Here, we propose the study of SURMOF growth conditions and their incorporation in nanomembrane-based device platforms, which allows the electrical measurement of ultra-thin SURMOF films. The study of growth parameters will be focused on the synthesis of homogeneous and low-rough films, presenting high stability in chemical and physical environments related with photolithographic process typically used in device fabrication. Different types of SURMOFs will be assembled such as HKUST-1, SURMOF-2 and ZIF-8, using spray, flow automation and dipping robot growth setups. This project will contribute to the study of SURMOFs thin-films electrical and dielectric properties, allowing a deeper understanding of films characteristics and expanding their applications, mainly in the field of nanotechnology. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALBANO, LUIZ G. S.; DE CAMARGO, DAVI H. S.; SCHLEDER, GABRIEL R.; DEEKE, SAMANTHA G.; VELLO, TATIANA P.; PALERMO, LEIRSON D.; CORREA, CATIA C.; FAZZIO, ADALBERTO; WOELL, CHRISTOF; BUFON, CARLOS C. B.. Room-Temperature Negative Differential Resistance in Surface-Supported Metal-Organic Framework Vertical Heterojunctions. SMALL, v. 17, n. 35, JUL 2021. (17/18139-6, 14/25979-2, 16/25346-5, 14/50906-9, 19/01561-2, 17/02317-2, 17/25553-3)

VELLO, TATIANA PARRA; ALBANO, LUIZ GUSTAVO SIMAO; DOS SANTOS, THAMIRIS CESCON; COLLETTI, JULIA CANTOVITZ; SANTOS BATISTA, CARLOS VINICIUS; LEME, VITORIA FERNANDES CINTRA; DOS SANTOS, THAMIRIS COSTA; MIGUEL, MARIA PAULA DIAS CARNEIRO; DE CAMARGO, DAVI HENRIQUE STARNINI; BOF BUFON, CARLOS CESAR. Electrical Conductivity Boost: In Situ Polypyrrole Polymerization in Monolithically Integrated Surface-Supported Metal-Organic Framework Templates. SMALL, v. N/A, p. 14-pg., 2023-09-26. (17/02317-2, 14/50906-9, 16/25346-5, 19/01561-2, 14/25979-2, 17/25553-3)