Application of gas diffusion electrodes modified with advanced materials in hydrogen peroxide electrosynthesis applied for the degradation of organic pollutants

• Grant number: 19/01925-4
• Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
• Start date: April 01, 2019
• End date: June 30, 2023
• Field of knowledge: Engineering - Sanitary Engineering - Water Supply and Wastewater Treatment
• Principal Investigator: Mauro Coelho dos Santos
• Grantee: Lanna Emilli Barbosa Lucchetti
• Host Institution: Centro de Ciências Naturais e Humanas (CCNH). Universidade Federal do ABC (UFABC). Santo André , SP, Brazil
• Associated research grant: 17/10118-0 - Study and application of electrochemical technology for the analysis and degradation of endocrine interferents: materials, sensors, processes and scientific dissemination, AP.TEM
• Associated scholarship(s): 21/14794-5 - Application of theoretical methods to understand catalytic trends in oxygen reduction reaction for hydrogen peroxide selectivity, BE.EP.DD

Abstract

Synthesis, characterization and application of new nanostructured electrocatalytic materials for electrogeneration of H2O2, involving from the synthesis of the materials by different routes (polymer precursors, hydrothermal synthesis or impregnation method) until its morphological-structural characterization, using techniques such as (SEM), X-ray Photoelectronic Spectroscopy (XPS), X-Ray Diffraction analysis (XRD), X-Ray Fluorescence (FRX) and others and electrochemistry (cyclic and linear scanning voltammetry on rotating ring - disk systems). To study the electrogeneration of H2O2 in electrochemical bench cell and in a flow reactor with gas diffusion electrodes modified or not with nanostructured electrocatalysts. To study the degradation of organic pollutants that are associated to the thematic project using PEOAS and TOC analysis, high performance liquid chromatography, gas chromatography and ion chromatography, in order to trace the degradation routes and the reduction of concentration of the organic pollutants. (AU)

Scientific publications

(6)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ANTONIN, VANESSA S.; LUCCHETTI, LANNA E. B.; SOUZA, FELIPE M.; PINHEIRO, VICTOR S.; MOURA, JOAO C.; TRENCH, ALINE B.; DE ALMEIDA, JAMES M.; AUTRETO, PEDRO A. S.; LANZA, MARCOS R. V.; SANTOS, MAURO C.. Sodium niobate microcubes decorated with ceria nanorods for hydrogen peroxide electrogeneration: An experimental and theoretical study. Journal of Alloys and Compounds, v. 965, p. 11-pg., 2023-11-25. (17/22976-0, 21/14394-7, 21/05364-7, 17/10118-0, 19/01925-4, 20/14100-0)

LUCCHETTI, LANNA E. B.; DE ALMEIDA, JAMES M.; AUTRETO, PEDRO A. S.; SANTOS, MAURO C.. ssessing the oxygen reduction reaction by a 2-electron mechanism on ceria surface. Physical Chemistry Chemical Physics, v. 23, n. 34, AUG 2021. (19/01925-4, 17/10118-0)

LUCCHETTI, LANNA E. B.; AUTRETO, PEDRO A. S.; SANTOS, MAURO C.; DE ALMEIDA, JAMES M.. Cerium doped graphene-based materials towards oxygen reduction reaction catalysis. MATERIALS TODAY COMMUNICATIONS, v. 38, p. 6-pg., 2024-03-01. (19/01925-4, 17/10118-0)

LUCCHETTI, LANNA E. B.; AUTRETO, PEDRO A. S.; DE ALMEIDA, JAMES M. M.; SANTOS, MAURO C. C.; SIAHROSTAMI, SAMIRA. Unravelling catalytic activity trends in ceria surfaces toward the oxygen reduction and water oxidation reactions. REACTION CHEMISTRY & ENGINEERING, v. 8, n. 6, p. 9-pg., 2023-03-03. (17/10118-0, 19/01925-4)

LUCCHETTI, LANNA E. B.; ALMEIDA, MICHELL O.; DE ALMEIDA, JAMES M.; AUTRETO, PEDRO A. S.; HONORIO, KATHIA M.; SANTOS, MAURO C.. Density functional theory studies of oxygen reduction reaction for hydrogen peroxide generation on Graphene-Based catalysts. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 895, AUG 15 2021. (18/19103-8, 17/10118-0, 19/01925-4)

HUEBNER, J. L.; LUCCHETTI, L. E. B.; NONG, H. N.; SHARAPA, D. I.; PAUL, B.; KROSCHEL, M.; KANG, J.; TESCHNER, D.; BEHRENS, S.; STUDT, F.; et al. Cation Effects on the Acidic Oxygen Reduction Reaction at Carbon Surfaces. ACS ENERGY LETTERS, v. 9, n. 4, p. 8-pg., 2024-03-01. (17/10118-0, 19/01925-4, 21/14794-5)