Study and application of electrochemical technology for the analysis and degradation of endocrine interferents: materials, sensors, processes and scientific dissemination

• Grant number: 17/10118-0
• Support type: Research Projects - Thematic Grants
• Duration: August 01, 2018 - July 31, 2023
• Field of knowledge: Engineering - Sanitary Engineering
• Principal Investigator: Marcos Roberto de Vasconcelos Lanza
• Grantee: Marcos Roberto de Vasconcelos Lanza
• Home Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil
• Co-Principal Investigators: Artur de Jesus Motheo ; Mauro Coelho dos Santos ; Neidenêi Gomes Ferreira
• Assoc. researchers: Ana Cláudia Kasseboehmer ; Ana Lopes Correia Tavares ; Fernando Cruz de Moraes ; Kathia Maria Honorio ; Luiz Henrique Ferreira ; Renata Colombo ; Robson da Silva Rocha
• Associated grant(s): 19/00599-6 - 25th ISE topical meeting, AR.EXT; 19/06650-3 - EMU granted in the 2017/10118-0 process: potentiostat system with impedance module, AP.EMU; 18/22210-0 - EMU granted in process 2017/10118-0: liquid chromatograph (HPLC), AP.EMU; 18/22211-7 - EMU granted in process 2017/10118-0: total organic carbon analyzer (TOC), AP.EMU; 18/22022-0 - EMU granted in the 2017/10118-0 process: spectroelectrochemistry system, AP.EMU
• Associated scholarship(s): 19/20634-0 - Treatment of wastewater contaminated with endocrine interferences through the application of electrochemical advanced oxidation processes: synergistic effect of different carbon supported cathodes, BP.PD; 18/18675-8 - Nanostructured electrocatalysts based on PT, PD and oxides of low cost for applications in energy and environment, BP.DR; 19/04421-7 - Production and characterization of metal-graphene or graphene oxide nanocomposites for the electrocatalytic production of hydrogen peroxide: application to the degradation of endocrine disrupting chemicals by electrochemical advanced oxidation processes, BP.PD; + associated scholarships 19/12328-7 - Synthesis, activation and electrochemical application of non-commercial carbon, BP.IC; 18/22026-5 - Design and construction of a photoreactor system for the preliminary evaluation of electrodes aiming at their application in the degradation of organic compounds that act as endocrine disruptors, BE.PQ; 19/06768-4 - Use of the residues of the beer production in the thermal synthesis of active carbon and their application in the study of the reduction reaction of oxygen, BP.IC; 19/08701-4 - Hydrogen peroxide electrosynthesis recharging gas thickness electrodes (EDG) modified with combined nanostructured metal oxides, BP.DD; 19/00288-0 - Degradation of antibiotics by electrochemical advanced oxidation processes, BP.PD; 19/04543-5 - Study of the contribution of videos of scientific dissemination to the formation of the scientific spirit, BP.PD; 19/01925-4 - Application of gas diffusion electrodes modified with advanced materials in hydrogen peroxide electrosynthesis applied for the degradation of organic pollutants, BP.DD; 19/00239-0 - "synthesis and characterization of new electrocatalysts for hydrogen peroxide electrogeneration", BP.PD; 19/00592-1 - Degradation of carbamate agrochemicals from Advanced Oxidation Electrochemical Processes (AOEP) using boron doped diamond electrodes, BP.DD; 18/26307-9 - Development of Pd and Nb electrocatalysts for application in fuel cells and degradation of organic pollutants, BP.IC; 18/26475-9 - Evaluation and application of electrodes of oxide mixtures and boron doped diamond for the degradation of organic compounds with activity of endocrine interference, BP.DD; 18/19103-8 - Computational study of electrochemical properties related to the degradation of endocrine disruptors, BP.PD; 18/16308-8 - Production and characterization of hybrid nanomaterials from electrospun nanofibers and evaluation of their efficiency against the electrochemical oxidation of atrazine, BP.DR; 18/19108-0 - Study of the inquiry method contribution to students autonomy perception in high school chemistry classes, BP.IC; 16/19612-4 - Degradation of endocrine disruptors carbofuran, methylparaben and propylparaben via electrogenerated H2O2 and associated processes (electrogenerated H2O2/UV, electro-Fenton e photoelectro-Fenton), BP.DD; 16/08760-2 - Heterojunction of NiO/ZnO and CuO/ZnO applied at the PHOTOELETRODEGRADATION of trimethoprim and levofloxacin, BP.PD; 14/27164-6 - Production and characterization of reticulated vitreous carbon/nanodiamond/silver nanoparticles composites used for nitrate removal, BP.PD - associated scholarships

Abstract

The aim of this research project is the development and application of new materials in electrochemical processes (and associated) for the degradation of compounds with endocrine interference activity (endocrine disruptors), evaluating the efficiency of these processes and the identification of by-products of degradation. In addition, the project provides the development of electrochemical sensors of analysis for this type of compound and the scientific dissemination of the knowledge produced both in the scientific environment and for society in general, with special attention for public school students. (AU)

Scientific publications

(22)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

FAVA, ELSON LUIZ; DO PRADO, THIAGO MARTIMIANO; GARCIA-FILHO, AMAURI; SILVA, TIAGO ALMEIDA; CINCOTTO, FERNANDO HENRIQUE; DE MORAES, FERNANDO CRUZ; FARIA, RONALDO CENSI; FATIBELLO-FILHO, ORLANDO. Non-enzymatic electrochemical determination of creatinine using a novel screen-printed microcell. Talanta, v. 207, JAN 15 2020. Web of Science Citations: 0.

WONG, ADEMAR; SANTOS, ANDERSON M.; CINCOTTO, FERNANDO H.; MORAES, FERNANDO C.; FATIBELLO-FILHO, ORLANDO; SOTOMAYOR, MARIA D. P. T. A new electrochemical platform based on low cost nanomaterials for sensitive detection of the amoxicillin antibiotic in different matrices. Talanta, v. 206, JAN 1 2020. Web of Science Citations: 0.

SOUZA, F. L.; ROCHA, R. S.; FERREIRA, N. G.; RODRIGO, M. A.; LANZA, M. R. V. Effects of coupling hybrid processes on the treatment of wastewater containing a commercial mixture of diuron and hexazinone herbicides. Electrochimica Acta, v. 328, DEC 20 2019. Web of Science Citations: 0.

PARREIRA, LUANNA S.; ANTONIASSI, RODOLFO M.; FREITAS, ISABEL C.; DE OLIVEIRA, DANIELA C.; SPINACE, ESTEVAM V.; CAMARGO, PEDRO H. C.; DOS SANTOS, MAURO C. MWCNT-COOH supported PtSnNi electrocatalysts for direct ethanol fuel cells: Low Pt content, selectivity and chemical stability. RENEWABLE ENERGY, v. 143, p. 1397-1405, DEC 2019. Web of Science Citations: 0.

SOUZA, FELIPE M.; BOHNSTEDT, PAULA; PINHEIRO, VICTOR S.; PAZ, EDSON C.; PARREIRA, LUANNA S.; BATISTA, BRUNO L.; SANTOS, MAURO C. Niobium Enhances Electrocatalytic Pd Activity in Alkaline Direct Glycerol Fuel Cells. CHEMELECTROCHEM, v. 6, n. 21, p. 5396-5406, OCT 31 2019. Web of Science Citations: 0.

FAVA, ELSON LUIZ; SILVA, TIAGO ALMEIDA; DO PRADO, THIAGO MARTIMIANO; DE MORAES, FERNANDO CRUZ; FARIA, RONALDO CENSI; FATIBELLO-FILHO, ORLANDO. Electrochemical paper-based microfluidic device for high throughput multiplexed analysis. Talanta, v. 203, p. 280-286, OCT 1 2019. Web of Science Citations: 0.

PAZ, EDSON C.; PINHEIRO, VICTOR S.; AVEIRO, LUCI R.; SOUZA, FERNANDA L.; LANZA, V, MARCOS R.; SANTOS, MAURO G. Hydrogen Peroxide Electrogeneration by Gas Diffusion Electrode Modified with Tungsten Oxide Nanoparticles for Degradation of Orange II and Sunset Yellow FCF Azo Dyes. Journal of the Brazilian Chemical Society, v. 30, n. 9, p. 1964-1975, SEP 2019. Web of Science Citations: 0.

GENTIL, TUANI C.; PINHEIRO, VICTOR S.; PAZ, EDSON C.; SOUZA, FELIPE M.; PARREIRA, LUANNA S.; SANTOS, MAURO C. Addition of CeO2 Nanorods in PtSn-Based Electrocatalysts for Ethanol Electrochemical Oxidation in Acid Medium. Journal of the Brazilian Chemical Society, v. 30, n. 8, p. 1634-1646, AUG 2019. Web of Science Citations: 0.

MOREIRA, JULIANA; LIMA, VERNICA BOCALON; GOULART, LORENA ATHIE; LANZA, MARCOS R. V. Electrosynthesis of hydrogen peroxide using modified gas diffusion electrodes (MGDE) for environmental applications: Quinones and azo compounds employed as redox modifiers. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 248, p. 95-107, JUL 5 2019. Web of Science Citations: 3.

OISHI, SILVIA SIZUKA; COUTO, ANDREA BOLDARINI; BOTELHO, EDSON COCCHIERI; FERREIRA, NEIDENEI GOMES. Silver deposition optimization process on ultrananocrystalline diamond applied to nitrate reduction. ENVIRONMENTAL TECHNOLOGY, JULY 2019. Web of Science Citations: 0.

PRADO, THIAGO M.; CARRICO, AMANDA; CINCOTTO, FERNANDO H.; FATIBELLO-FILHO, ORLANDO; MORAES, FERNANDO C. Bismuth vanadate/graphene quantum dot: A new nanocomposite for photoelectrochemical determination of dopamine. SENSORS AND ACTUATORS B-CHEMICAL, v. 285, p. 248-253, APR 15 2019. Web of Science Citations: 3.

CINCOTTO, FERNANDO H.; FAVA, ELSON L.; MORAES, FERNANDO C.; FATIBELLO-FILHO, ORLANDO; FARIA, RONALDO C. A new disposable microfluidic electrochemical paper-based device for the simultaneous determination of clinical biomarkers. Talanta, v. 195, p. 62-68, APR 1 2019. Web of Science Citations: 5.

GUARALDO, THAIS T.; GOULART, LORENA A.; MORAES, FERNANDO C.; LANZA, V, MARCOS R. Carbon black nanospheres modified with Cu (II)-phthalocyanine for electrochemical determination of Trimethoprim antibiotic. Applied Surface Science, v. 470, p. 555-564, MAR 15 2019. Web of Science Citations: 6.

SILVA, F. L.; LANZA, V, M. R.; SAEZ, C.; RODRIGO, M. A. Electrochemical dewatering for the removal of hazardous species from sludge. Journal of Environmental Management, v. 233, p. 768-773, MAR 1 2019. Web of Science Citations: 1.

SANTOS, ANDERSON MARTIN; WONG, ADEMAR; CINCOTTO, FERNANDO HENRIQUE; MORAES, FERNANDO CRUZ; FATIBELLO-FILHO, ORLANDO. Square-wave adsorptive anodic stripping voltammetric determination of norfloxacin using a glassy carbon electrode modified with carbon black and CdTe quantum dots in a chitosan film. Microchimica Acta, v. 186, n. 3 MAR 2019. Web of Science Citations: 2.

SOUZA, FELIPE DE MOURA; PANIZ, FERNANDA POLLO; PEDRON, TATIANA; DOS SANTOS, MAURO COELHO; BATISTA, BRUNO LEMOS. A high-throughput analytical tool for quantification of 15 metallic nanoparticles supported on carbon black. HELIYON, v. 5, n. 3 MAR 2019. Web of Science Citations: 1.

PINHEIRO, VICTOR S.; PAZ, EDSON C.; AVEIRO, LUCI R.; PARREIRA, LUANNA S.; SOUZA, FELIPE M.; CAMARGO, PEDRO H. C.; SANTOS, MAURO C. Mineralization of paracetamol using a gas diffusion electrode modified with ceria high aspect ratio nanostructures. Electrochimica Acta, v. 295, p. 39-49, FEB 1 2019. Web of Science Citations: 3.

MARTINS, ALYSSON STEFAN; MARQUES CORDEIRO-JUNIOR, PAULO JORGE; BESSEGATO, GUILHERME GARCIA; CARNEIRO, JUSSARA FERNANDES; BOLDRIN ZANONI, MARIA VALNICE; DE VASCONCELOS LANZA, MARCOS ROBERTO. Electrodeposition of WO3 on Ti substrate and the influence of interfacial oxide layer generated in situ: A photoelectrocatalytic degradation of propyl paraben. Applied Surface Science, v. 464, p. 664-672, JAN 15 2019. Web of Science Citations: 4.

SILVA, FERNANDO L.; SAEZ, CRISTINA; LANZA, V, MARCOS R.; CANIZARES, PABLO; RODRIGO, MANUEL A. The Role of Mediated Oxidation on the Electro-irradiated Treatment of Amoxicillin and Ampicillin Polluted Wastewater. CATALYSTS, v. 9, n. 1 JAN 2019. Web of Science Citations: 1.

RAFAEL CAVA MORI; ANA CLÁUDIA KASSEBOEHMER. ESTRATÉGIAS PARA A INSERÇÃO DE MUSEUS DE CIÊNCIAS NO ESTÁGIO SUPERVISIONADO EM ENSINO DE QUÍMICA. Química Nova, v. 42, n. 7, p. 803-811, Ago. 2019.

GOULART, LORENA A.; GUARALDO, THAIS T.; LANZA, MARCOS R. V. A Novel Electrochemical Sensor Based on Printex L6 Carbon Black Carrying CuO/Cu2O Nanoparticles for Propylparaben Determination. Electroanalysis, v. 30, n. 12, p. 2967-2976, DEC 2018. Web of Science Citations: 2.

CARNEIRO, JUSSARA F.; SILVA, FERNANDO L.; MARTINS, ALYSSON S.; DIAS, RAFAEL M. P.; TITATO, GUILHERME M.; SANTOS-NETO, ALVARO J.; BERTAZZOLI, RODNEI; LANZA, MARCOS R. V. Simultaneous degradation of hexazinone and diuron using ZrO2-nanostructured gas diffusion electrode. CHEMICAL ENGINEERING JOURNAL, v. 351, p. 650-659, NOV 1 2018. Web of Science Citations: 0.