Study and control of the crystalline orientations in MoS2/TiO2 and MoS2/TiO2:H heterojunctions and their effects on its physicochemical properties

• Grant number: 19/00757-0
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• Start date: July 01, 2019
• End date: August 31, 2022
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Fernando Alvarez
• Grantee: Fernando Graniero Echeverrigaray
• Host Institution: Instituto de Física Gleb Wataghin (IFGW). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated research grant: 12/10127-5 - Research and development of nanostructured materials for electronic and surface physics applications, AP.TEM

Abstract

The performance of electronic and mechanical devices that work continuously or intermittent is impaired by inherent process of energy losses associated with the system. This energy dissipation can be minimized by mastering the atomic-molecular interactions (due to chemical bonds and van der Waals forces) that form the crystalline structure in devices such as nanostructured heterojunctions. These dissipative processes basically depend on the crystalline structure of the materials and mastering its atomic bonding forming is a fundamental step for developing nanostructures heterojunctions for several applications.The project proposes to study the nanoscopic aspects intervening in the formation of atomic interfacial interactions in heterojunctions constituted by MoS2/TiO2 and MoS2/TiO2 nano-layers obtained by Ion Beam Deposition (IBAD) and sputtering techniques. The aims of the project focus on the control of the morphology of heterojunctions (stacking structure), nanofriction and absorption optical gap optical transmission in the ultraviolet-visible UV-VIS ranges for different crystallographic orientations of the multilayer systems. The project contemplates incorporating of the study of the friction properties due to the fact that the electronic structure of the material surface influences the properties related to dissipative forces at the nanoscopic level. As an innovative exploration and based on the importance of the electronic optical gap of TiO2 and passivation surface properties of the material, the project contemplates studies of hydrogen doping. The effect of hydrogen is the modification of the absorption coefficient (optical gap), influencing the Nano friction and photocatalytic properties of these materials. Combining the doping with H of the TiO2 and the control of the interface properties of the crystalline orientation and atomic bonds, the research focus to obtain a family of new materials with potential applications in optoelectronics devices (e.g., solar energy and catalysis) and mechanical devices (e.g., nanoscopic gadgets where low friction is fundamental). (AU)

Scientific publications

(9)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ZANATTA, A. R.; ECHEVERRIGARAY, F. G.; CEMIN, F.; ALVAREZ, F.. radual and selective achievement of Rutile-TiO2 by thermal annealing amorphous TixOyNz film. Journal of Non-Crystalline Solids, v. 579, MAR 1 2022. (18/24461-0, 19/00757-0, 19/18460-4)

ANTUNES, VINICIUS G.; FIGUEROA, CARLOS A.; ALVAREZ, FERNANDO. Chemisorption Competition between H2O and H-2 for Sites on the Si Surface under Xe+ Ion Bombardment: An XPS Study. Langmuir, v. 38, n. 6, p. 8-pg., 2022-02-15. (12/10127-5, 19/00757-0, 19/18460-4, 18/24461-0)

ECHEVERRIGARAY, FERNANDO GRANIERO; FIGUEROA, CARLOS ALEJANDRO; ZANATTA, ANTONIO RICARDO; ALVAREZ, FERNANDO. Heterophase Interface and Surface Functionalization of TiOx/TiSix Metastable Nanofilms. ADVANCED MATERIALS INTERFACES, v. 9, n. 24, p. 14-pg., 2022-07-20. (19/00757-0, 19/18460-4)

ECHEVERRIGARAY, F. G.; ZANATTA, A. R.; ALVAREZ, F.. Reducible oxide and allotropic transition induced by hydrogen annealing: synthesis routes of TiO2 thin films to tailor optical response. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 12, p. 1623-1637, MAY-JUN 2021. (19/18460-4, 19/00757-0)

PEROTTI, BRUNA L.; CAMMARATA, ANTONIO; CEMIN, FELIPE; SALES DE MELLO, SARON R.; LEIDENS, LEONARDO M.; ECHEVERRIGARAY, FERNANDO G.; MINEA, TIBERIU; ALVAREZ, FERNANDO; MICHELS, ALEXANDRE F.; POLCAR, TOMAS; et al. Phototribology: Control of Friction by Light. ACS APPLIED MATERIALS & INTERFACES, v. 13, n. 36, p. 43746-43754, SEP 15 2021. (19/00757-0, 18/24461-0)

ZANATTA, A. R.; CEMIN, F.; ECHEVERRIGARAY, F. G.; ALVAREZ, F.. On the relationship between the Raman scattering features and the Ti-related chemical states of TixOyNz films. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 14, p. 864-870, SEP-OCT 2021. (19/18460-4, 18/24461-0, 19/00757-0)

VAGNER F. G. SOARES; DANIEL A. RAMIREZ; IGOR Z. DAMASCENO; FERNANDO G. ECHEVIRRIGARAY; CARLOS A. FIGUEROA; BRUNA L. PEROTTI; FRANCISCO L. SERAFINI; GIVANILSON B. OLIVEIRA; ANDRÉ R. TERTO; EDUARDO K. TENTARDINI. Structure, mechanical properties and oxidation resistance of iso and non-iso architected TiN/Cr multilayers coatings deposited by magnetron sputtering. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 24, n. 1, 2021-01-15. (19/00757-0)

LITORIA, ADITYA K.; JOSHI, MANOJ D.; ANTUNES, V.; SINGH, DIGVIJAY; FIGUEROA, CARLOS A.; ALVAREZ, F.; HOSMANI, SANTOSH S.. The response of boronized 34CrAlMo5-10 (EN41B) steel to nanoindentation, oxidation, and wear. PHILOSOPHICAL MAGAZINE, v. 101, n. 7, p. 777-818, APR 3 2021. (12/10127-5, 18/24461-0, 19/00757-0)

ECHEVERRIGARAY, FERNANDO G.; ALVAREZ, FERNANDO. Searching guidelines for scalable and controllable design of multifunctional materials and hybrid interfaces: Status and perspective. FRONTIERS IN CHEMICAL ENGINEERING, v. 4, p. 10-pg., 2022-08-31. (19/00757-0)