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Synthesis and catalytic activity of enantioenriched complexes bearing bisfunctional ligands

Grant number: 19/15883-1
Support type:Scholarships in Brazil - Doctorate (Direct)
Effective date (Start): October 01, 2019
Effective date (End): April 30, 2022
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal researcher:Caio Costa Oliveira
Grantee:Lucas dos Santos Cunha
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Associated research grant:18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis, AP.JP

Abstract

Ligands able to form complexes with two metals or a metal and a Lewis acid are known as bifunctional ligands. In this project, these ligands will be synthesized two types of complexes: (1) complexes containing a chiral Lewis acid and an achiral bifunctional ligand and (2) chiral bifunctional binders containing two different metals. In both cases, these complexes will be used for the development of sequential enantioselective reactions. (AU)

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