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Synthesis and catalytic activity of metal complexes bearing enantioenriched sulphoxides ligands

Grant number: 19/00080-0
Support type:Scholarships in Brazil - Doctorate (Direct)
Effective date (Start): March 01, 2019
Effective date (End): April 30, 2022
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal researcher:Caio Costa Oliveira
Grantee:Eduardo José de Carvalho Junior
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Associated research grant:18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis, AP.JP

Abstract

Chiral sulphoxides are ligands underexplored in the literature, despite the great potential for asymmetric catalytic reactions. In this project, it is proposed the synthesis of chiral sulfoxides with C2 symmetry and its application in the synthesis of chiral bimetallic complexes. In addition, the synthesized complexes will be evaluated as catalysts for enantioselective transformations. (AU)

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