Nonlinear optic and magneto-optic in glass and glass-ceramics containing niobium and tantalum

• Grant number: 20/01786-1
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• Start date: October 01, 2020
• End date: March 31, 2024
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Principal Investigator: Marcelo Nalin
• Grantee: Lia Mara Silva Marcondes
• Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
• Associated research grant: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass, AP.CEPID
• Associated scholarship(s): 21/11494-0 - Manufacture of photonic microdevices in glasses containing niobium and tantalum, BE.EP.PD

Abstract

The development of materials for the construction of fully optical communication networks requires the improvement of integrated optical and photonic devices. Oxide glasses containing niobium and tantalum are promising for passive and active devices due to their linear and non-linear optical properties. In this work, glass and glass-ceramics based on germanates and phosphates containing niobium (a national resource) and tantalum will be studied because they have a wide transmission window, high refractive indices and optical properties superior to conventional silicate glasses. The nonlinear properties resulting from optical microstructuring, after glass irradiation with femtosecond laser in the infrared region will be investigated. This study is promising, since the analysis of nonlinear optical properties will be performed in matrices already optimized and provided by Prof. Dr. Gael Poirier of the Federal University of Alfenas. In addition, the synthesis and characterization of rare-earth-doped matrices for the formation of paramagnetic terbium gallate crystals is also proposed, aiming to study the luminescent and magneto-optical properties. The synthesis and characterization of the new matrices aiming at the formation of terbium gallate crystals will be carried out at IQ-UNESP and the investigation of non-linear properties and femtosecond laser micromachining in collaboration with Professor Dr. Cleber Renato Mendonça at the Federal University of São Paulo/Campus de São Carlos and later, in France, with Professor Dr. Thierry Cardinal from Université de Bordeaux (BEPE). (AU)

Scientific publications

(5)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MARCONDES, LIA MARA; DA CUNHA, CRISTIANO RAMOS; DE PIETRO, GABRIELE MATINATTI; MANZANI, DANILO; GONCALVES, ROGERIA ROCHA; BATISTA, GISLENE; CASSANJES, FABIA CASTRO; POIRIER, GAEL. Multicolor tunable and NIR broadband emission from rare-earth-codoped tantalum germanate glasses and nanostructured glass-ceramics. Journal of Luminescence, v. 239, NOV 2021. (20/01786-1, 17/11301-2, 18/16126-7, 13/07793-6, 20/05319-9)

MARCONDES, LIA MARA; BRADTMUELLER, HENRIK; DOS SANTOS, SABRINA NICOLETI CARVALHO; NOLASCO, LUCAS KONAKA; MENDONCA, CLEBER RENATO; SANTAGNELI, SILVIA HELENA; POIRIER, GAEL YVES; NALIN, MARCELO. Structural and luminescence characterization of europium-doped niobium germanate glasses and glass-ceramics: Novel insights from 93Nb solid-state NMR spectroscopy. CERAMICS INTERNATIONAL, v. 48, n. 14, p. 8-pg., 2022-07-15. (13/07793-6, 19/26399-3, 20/01786-1)

MARCONDES, L. M.; SANTAGNELI, S. H.; RIBEIRO, S. J. L.; CAIUT, J. M. A.; MISOGUTI, L.; NALIN, M.. Structural and optical characterization of tungsten phosphate glasses containing silver and erbium. Optical Materials, v. 132, p. 7-pg., 2022-08-04. (20/01786-1, 13/07793-6)

DA CUNHA, CRISTIANO RAMOS; MARCONDES, LIA MARA; BATISTA, GISLENE; GONCALVES, ROGERIA ROCHA; CASSANJES, FABIA CASTRO; POIRIER, GAEL YVES. rystallization of bronze-like perovskite in potassium tantalum germanate glasses: Glass ceramic preparation and its optical propertie. Optical Materials, v. 122, n. B, DEC 2021. (20/01786-1, 17/11301-2, 20/05319-9)

MARCONDES, LIA MARA; SILVA, MARIANA CAROLINA DE CASTRO; FRANCO, DOUGLAS FAZA; MANZANI, DANILO; POIRIER, GAEL YVES; NALIN, MARCELO. Monitoring Ag nanoparticles growth in undoped and Er3+-doped glasses by in-situ UV-Vis spectroscopy and its luminescent properties. Journal of Non-Crystalline Solids, v. 609, p. 8-pg., 2023-03-20. (20/01786-1, 13/07793-6)