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Performance of CO adsorption on inorganic SiC-based graphenylene doped with Fe, Co and Mn

Grant number: 22/00349-2
Support Opportunities:Scholarships in Brazil - Master
Start date: May 01, 2022
End date: July 31, 2024
Field of knowledge:Physical Sciences and Mathematics - Chemistry
Principal Investigator:Julio Ricardo Sambrano
Grantee:Nicolas Ferreira Martins
Host Institution: Faculdade de Ciências (FC). Universidade Estadual Paulista (UNESP). Campus de Bauru. Bauru , SP, Brazil
Associated research grant:13/07296-2 - CDMF - Center for the Development of Functional Materials, AP.CEPID
Associated scholarship(s):22/14576-0 - Molecular dynamics simulations of novel two-dimensional materials, BE.EP.MS

Abstract

Due to the high interest in the development of new two-dimensional (2D) materials, computer simulation can be used to obtain and predict nanostructures with unique properties, assisting experimentalists in future synthesis routes and the industry by providing innovative commercial materials. In light of this, this project aims, in unprecedently study, uses the density functional theory (DFT) to investigate the structural and electronic properties of inorganic graphenylene-like silicon carbide (IGP-SiC) doped with transition metals (TM) (Fe, Co, and Mn), in order to study the impact of each atom on the material's properties. Furthermore, N atoms will be inserted and bonded to the TM to evaluate the influence of nitrogen on the stability and electronic modulation of the IGP-SiC systems to improve the behavior of the TM-IGP-SiC systems. In this sense, the current study will investigate TM-IGP-SiC nanostructures with and without N atoms, as well as their adsorption of carbon monoxide (CO) gas, to better comprehend the various interactions that exist between the molecule and the surfaces of the IGP-SiC. These studies will shed light on the ability of IGP-SiC to be modulated and the role of N atoms in the structural and electronic behavior of TM-IGP-SiC systems, as well as provide insights into the performance of these surfaces in CO adsorption for future applications.

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Scientific publications (19)
(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)
MARTINS, NICOLAS F.; FABRIS, GUILHERME S. L.; MAIA, ARY S.; ALBUQUERQUE, ANDERSON R.; SAMBRANO, JULIO R.. Inorganic graphenylene-like silicon carbide as anode material for Na batteries. FLATCHEM, v. 35, p. 8-pg., . (22/03959-6, 19/08928-9, 13/07296-2, 22/00349-2, 20/10380-9)
DENIS, PABLO A.; LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; SAMBRANO, JULIO R.. Codoped germanene with 3p and 4p elements elements. Journal of Molecular Modeling, v. 30, n. 10, p. 10-pg., . (22/00349-2, 22/03959-6, 22/16509-9)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; AZEVEDO, SERGIO A.; FABRIS, GUILHERME S. L.; SAMBRANO, JULIO R.. Novel octa-graphene-like structures based on GaP and GaAs. Journal of Molecular Modeling, v. 29, n. 7, p. 8-pg., . (22/00349-2, 20/01144-0, 22/03959-6)
LIMA, KLEUTON A. L.; LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; DIAS, ALEXANDRE C.; SAMBRANO, JULIO R.; GALVAO, DOUGLAS S.; RIBEIRO JR, LUIZ A.. Petal-Graphyne: A novel 2D carbon allotrope for high-performance Li and Na ion storage. JOURNAL OF ENERGY STORAGE, v. 130, p. 10-pg., . (13/08293-7, 20/01144-0, 24/05087-1, 22/16509-9, 22/00349-2, 22/03959-6, 22/14576-0)
AZEVEDO, SERGIO A.; LARANJEIRA, JOSE A. S.; SILVA, JERONIMO F.; LONGO, ELSON; SAMBRANO, JULIO R.. Ag-doped SrTiO3: Enhanced water splitting for hydrogen production. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 79, p. 9-pg., . (20/01144-0, 22/03959-6, 22/00349-2, 22/16509-9)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A.; FABRIS, GUILHERME S. L.; DENIS, PABLO A.; SAMBRANO, JULIO R.. Irida-graphene as a high-performance anode for sodium batteries. JOURNAL OF ENERGY STORAGE, v. 104, p. 11-pg., . (20/01144-0, 22/03959-6, 13/07296-2, 24/05087-1, 22/16509-9, 22/00349-2)
MARTINS, NICOLAS; LARANJEIRA, J. A. S.; DE AZEVEDO, SERGIO; SAMBRANO, JULIO. Strain Engineering to Improve the Electronic and Photocatalytic Properties of the Inorganic Graphenylene Based on SiC. ACS APPLIED ELECTRONIC MATERIALS, v. 6, n. 4, p. 9-pg., . (20/01144-0, 22/03959-6, 13/07296-2, 22/16509-9, 22/00349-2)
LARANJEIRA, JOSE A. S.; ELAGGOUNE, WARDA; MARTINS, NICOLAS F.; CHEN, XIHAO; SAMBRANO, JULIO R.. OLi3-decorated irida-graphene for high-capacity hydrogen storage: A first-principles study. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, v. 207, p. 9-pg., . (22/16509-9, 22/00349-2, 22/03959-6, 22/14576-0, 20/01144-0)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS; DENIS, PABLO A.; SAMBRANO, JULIO. High Stability, Piezoelectric Response, and Promising Photocatalytic Activity on the New Pentagonal CGeP4 Monolayer. ACS PHYSICAL CHEMISTRY AU, v. 5, n. 1, p. 10-pg., . (22/16509-9, 22/00349-2, 20/01144-0, 22/14576-0, 22/03959-6)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; LIMA, KLEUTON A. L.; XIAO, LINGTAO; CHEN, XIHAO; RIBEIRO JUNIOR, LUIZ A.; SAMBRANO, JULIO R.. Sodium-decorated P-C3N: A porous 2D framework for high-capacity and reversible hydrogen storage. MATERIALS TODAY COMMUNICATIONS, v. 48, p. 9-pg., . (22/00349-2, 20/01144-0, 22/03959-6, 24/05087-1, 22/16509-9, 13/08293-7, 22/14576-0)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A.; DE AZEVEDO, SERGIO A.; FABRIS, GUILHERME S. L.; SAMBRANO, JULIO R.. Tuning the electronic properties of the SiC graphenylene by transition metal (Fe, Mn and Co) doping. PHYSICA B-CONDENSED MATTER, v. 691, p. 9-pg., . (22/00349-2, 13/07296-2, 22/03959-6, 22/16509-9)
MARTINS, NICOLAS F.; MAIA, ARY S.; LARANJEIRA, JOSE A. S.; FABRIS, GUILHERME S. L.; ALBUQUERQUE, ANDERSON R.; SAMBRANO, JULIO R.. Hydrogen storage on the lithium and sodium-decorated inorganic graphenylene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 51, p. 10-pg., . (20/01144-0, 22/03959-6, 22/14576-0, 13/07296-2, 22/00349-2)
SILVA, JERONIMO F.; FABRIS, GUILHERME S. L.; SAMBRANO, JULIO R.; ALBUQUERQUE, ANDERSON R.; MAIA, ARY S.. TOPISO3D Viewer: Enhancing Topological Analysis through 3D Isosurfaces. JOURNAL OF CHEMICAL INFORMATION AND MODELING, v. 63, n. 7, p. 15-pg., . (19/08928-9, 20/10380-9, 22/03959-6, 13/07296-2, 22/00349-2)
SILVA, JERONIMO F.; FABRIS, GUILHERME S. L.; SAMBRANO, JULIO R.; ALBUQUERQUE, ANDERSON R.; MAIA, ARY S.. TOPISO3D Viewer: Enhancing Topological Analysis through 3D Isosurfaces. JOURNAL OF CHEMICAL INFORMATION AND MODELING, v. N/A, p. 15-pg., . (19/08928-9, 20/10380-9, 22/03959-6, 13/07296-2, 22/00349-2)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A.; DENIS, PABLO A.; SAMBRANO, JULIO R.. High sensitivity of nitrobenzene on the ZnO monolayer and the role of strain engineering. Applied Surface Science, v. 679, p. 10-pg., . (22/03959-6, 13/07296-2, 22/14576-0, 22/16509-9, 22/00349-2)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A.; DENIS, PABLO A.; SAMBRANO, JULIO R.. Ag decoration as a strategy to enhance the methanol and ethanol sensing on the biphenylene sheet. SURFACES AND INTERFACES, v. 51, p. 12-pg., . (20/01144-0, 22/03959-6, 13/07296-2, 22/16509-9, 22/00349-2)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; DENIS, PABLO A.; SAMBRANO, JULIO R.. A novel and promising Penta-Octa-Based silicon carbide semiconductor. FLATCHEM, v. 46, p. 9-pg., . (20/01144-0, 22/03959-6, 22/14576-0, 22/16509-9, 22/00349-2)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; DENIS, PABLO A.; SAMBRANO, JULIO R.. Graphenyldiene: A new sp2-graphene-like nanosheet. CARBON TRENDS, v. 14, p. 9-pg., . (20/01144-0, 22/03959-6, 22/14576-0, 22/16509-9, 22/00349-2)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A. S.; AZEVEDO, SERGIO A.; FABRIS, GUILHERME S. L.; SAMBRANO, JULIO R.. Structural, electronic and mechanical properties of a novel graphenylene-like structure based on GeC. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, v. 181, p. 9-pg., . (20/01144-0, 22/03959-6, 22/14576-0, 13/07296-2, 22/00349-2)