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Studies of physicochemical properties variations of Pt-Sn / C catalysts, Pt-Nd / C and Pt-Sn-Nd / C for the electro-oxidation of ethanol

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Author(s):
Nathalia Abe Santos
Total Authors: 1
Document type: Doctoral Thesis
Press: São Carlos.
Institution: Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC/BT)
Defense date:
Examining board members:
Joelma Perez; Adalgisa Rodrigues de Andrade; Margarida Juri Saeki; Edson Antonio Ticianelli
Advisor: Joelma Perez
Abstract

The development of efficient catalyst to ethanol oxidation reaction in fuel cells requires the comprehension of the influence of material proprerties (composition and crystallinity) on the catalytic activity. Herein, PtSn-based catalysts were synthesized and annealed in H2 or Ar atmosphere with and without MgO protective coating. Also, catalysts Pt, Sn and Nd-based were synthesized. The physical characterization of annealed Pt-Sn/C samples shows the formation of nanoparticles with different crystalline phases and alloy amounts with no agglomeration. The MgO coating was an efficient protector since the Pt-Sn particles did not grown during annealing. All the Pt-Sn/C catalysts present similar voltammetric profile in acidic electrolytic and shows better catalytic activity for CO oxidation than commercial Pt, before and after accelerated aging test (AAT). Differences in the linear sweep profile during CO oxidation before AAT indicate changes in the surface structure of catalysts annealed in H2 atmosphere, which can be explained by metal dissolution or particles growth. Studies also show catalysts with lower Sn amount in alloy phase are more stable for ethanol oxidation. The results of Pt-Sn and/or Nd catalysts system show improvement in the ethanol oxidation activity by Nd-based catalysts before AAT. It is possible that the cycling can dissolve Nd, preventing metals particles coalescence. Sn-based catalysts show strong acetic acid infrared absorption bands in FTIRAS analyses. CO bands appear less intense for Nd-based catalysts, which indicates a weak CO adsorption on these materials. In addition, the trimetallic Pt-Sn-Nd/C catalyst presents the best performance in unitary cell tests. (AU)

FAPESP's process: 13/17549-5 - Study of variations of physico-chemical properties of Nd-Pt/C and Pt-Nd-Sn/C for the ethanol electro-oxidation.
Grantee:Nathalia Abe Santos
Support Opportunities: Scholarships in Brazil - Doctorate