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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electrical Resistivity in Non-stoichiometric MoO2

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Author(s):
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Alves, L. M. S. [1] ; Benaion, S. S. [1] ; Romanelli, C. M. [1] ; dos Santos, C. A. M. [1] ; da Luz, M. S. [1, 2] ; de Lima, B. S. [1] ; Oliveira, F. S. [1] ; Machado, A. J. S. [1] ; Guedes, E. B. [3] ; Abbate, M. [3] ; Mossanek, R. J. O. [3]
Total Authors: 11
Affiliation:
[1] Univ Sao Paulo, Escola Engn Lorena, BR-12600970 Lorena, SP - Brazil
[2] Univ Fed Triangulo Mineiro, Inst Ciencias Tecnol & Exatas, BR-38064200 Uberaba, MG - Brazil
[3] Univ Fed Parana, Dept Fis, BR-81531990 Curitiba, PR - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Brazilian Journal of Physics; v. 45, n. 2, p. 234-237, APR 2015.
Web of Science Citations: 4
Abstract

MoO (y) with 1.85 a parts per thousand currency signaEuro parts per thousand y a parts per thousand currency signaEuro parts per thousand 2.20 has been studied by X-ray diffractometry and photoemission spectroscopy at room temperature and by electrical resistance as a function of temperature from 2 to 300 K. Although X-ray diffractograms are very similar to the stoichiometric MoO2 with monoclinic structure of the space group P2(1)/c (14), the electrical properties are strongly dependent on the oxygen composition. Samples with y = 1.85 and 1.90 show anomalous behavior in electrical conductivity. Photoemission and X-ray absorption spectroscopy measurements suggest that this anomalous behavior is related to the presence of Mo3+ ions such as in KxMoO2 compound. (AU)

FAPESP's process: 09/54001-2 - Acquisition of cryogen-free equipment for the characterization of magnetic properties by vibrating sample magnetometry
Grantee:Carlos Alberto Moreira dos Santos
Support Opportunities: Multi-user Equipment Program
FAPESP's process: 10/06637-2 - Crystalline structure and physical properties of the anomalous conductor KxMoO2-d
Grantee:Leandro Marcos Salgado Alves
Support Opportunities: Scholarships in Brazil - Doctorate
FAPESP's process: 09/14524-6 - Re-liquefier for using in a 9 t MagLab Oxford
Grantee:Carlos Alberto Moreira dos Santos
Support Opportunities: Regular Research Grants