Sharpless Asymmetric Dihydroxylation on ,-Unsaturated Diazoketones: A New Entry for the Synthesis of Disubstituted Furanones

Talero, Alexander G.; Burtoloso, Antonio C. B.

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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Sharpless Asymmetric Dihydroxylation on ,-Unsaturated Diazoketones: A New Entry for the Synthesis of Disubstituted Furanones

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Author(s):	Talero, Alexander G. ; Burtoloso, Antonio C. B. Total Authors: 2
Document type:	Journal article
Source:	Synlett; v. 28, n. 14, p. 1748-1752, SEP 2017.
Web of Science Citations:	5
Abstract
The synthesis of enantiomerically pure 4,5-disubstituted 2-furanones is accomplished in three steps from aldehydes. The steps involve a highly enantioselective Sharpless asymmetric dihydroxylation of ,-unsaturated diazoketones, followed by a photochemical Wolff rearrangement. (AU)

FAPESP's process:	13/18009-4 - Molecular design, synthesis and trypanocidal activity of cruzain reversible covalent inhibitors
Grantee:	Carlos Alberto Montanari
Support Opportunities:	Research Projects - Thematic Grants


FAPESP's process:	13/25504-1 - Development of new methodologies for the asymmetric a-functionalization of carbonyl compounds using chiral catalysts
Grantee:	Antonio Carlos Bender Burtoloso
Support Opportunities:	Regular Research Grants

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