Solvent- and Metal-Free Chalcogenation of Bicyclic Arenes Using I-2/DMSO as Non-Metallic Catalytic System

Silva, Lais T.; Azeredo, Juliano B.; Saba, Sumbal; Rafique, Jamal; Bortoluzzi, Adailton J.; Braga, Antonio L.

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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Solvent- and Metal-Free Chalcogenation of Bicyclic Arenes Using I-2/DMSO as Non-Metallic Catalytic System

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Author(s):	Silva, Lais T. ; Azeredo, Juliano B. ; Saba, Sumbal ; Rafique, Jamal ; Bortoluzzi, Adailton J. ; Braga, Antonio L. Total Authors: 6
Document type:	Journal article
Source:	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; v. 2017, n. 32, p. 4740-4748, SEP 1 2017.
Web of Science Citations:	29
Abstract
We have developed a green and efficient protocol for the chalcogenation of bicyclic arenes by using I-2/DMSO as catalytic system under solvent- and metal-free conditions. This protocol allows access to several chalcogenated bicyclic arenes through C(sp(2))-H bond functionalization, in good to excellent yields by using microwave irradiation or conventional heating. (AU)

FAPESP's process:	14/50249-8 - Green chemistry: sustainable synthetic methods employing benign solvents, safer reagents, and bio-renewable feedstock
Grantee:	Arlene Gonçalves Corrêa
Support Opportunities:	Research Grants - Research Centers in Engineering Program

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