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(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

RECENT ADVANCES ON HYDROAMINATION OF UNSATURATED COMPOUNDS

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Author(s):
Luiz F. T. Novaes [1] ; Julio C. Pastre [2]
Total Authors: 2
Affiliation:
[1] Universidade Estadual de Campinas. Instituto de Química. Departamento de Química Orgânica - Brasil
[2] Universidade Estadual de Campinas. Instituto de Química. Departamento de Química Orgânica - Brasil
Total Affiliations: 2
Document type: Journal article
Source: Química Nova; v. 40, n. 8, p. 932-945, 2017-09-00.
Abstract

This review presents thermodynamics and kinetics aspects of the hydroamination reaction, recent advancements on this field for non-activated alkenes, alkynes and allenes, employing transition metal catalysis or organocatalysis, including activation by hydrogen bonding or Brønsted acids. Selected syntheses that contain a strategic hydroamination step will be discussed, and advancements on the asymmetric version will also be highlighted. The full coverage of scientific activity about hydroamination is beyond this review, therefore the examples presented are from the last ten years, except when there are historical reasons for the discussion of previous works. (AU)

FAPESP's process: 15/08199-6 - Application of Dioxiranes in continuous flow, synthesis of Actinoranone and decalin fragment of Azadirachtin
Grantee:Luiz Fernando Toneto Novaes
Support Opportunities: Scholarships in Brazil - Doctorate
FAPESP's process: 14/25770-6 - New frontiers in cross-coupling reactions promoted by palladium: combining enantioselective catalysis, C-H activations, new materials and in flux reactions aiming at high efficiency and sustainability in synthetic processes
Grantee:Carlos Roque Duarte Correia
Support Opportunities: Research Projects - Thematic Grants
FAPESP's process: 14/26378-2 - Development of methodologies and synthetic processes employing a new technological platform: micro and meso reactor assisted synthesis of natural products and derivatives with potential pharmacological activity
Grantee:Júlio Cezar Pastre
Support Opportunities: Research Grants - Young Investigators Grants