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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electricity on Rubber Surfaces: A New Energy Conversion Effect

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Author(s):
Burgo, Thiago A. L. [1] ; Batista, Bruno C. [2] ; Galembeck, Fernando [2]
Total Authors: 3
Affiliation:
[1] Univ Fed Santa Maria, Dept Phys, BR-97105900 Santa Maria, RS - Brazil
[2] Univ Estadual Campinas, Inst Chem, BR-13083970 Campinas, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: ACS OMEGA; v. 2, n. 12, p. 8940-8947, DEC 2017.
Web of Science Citations: 5
Abstract

This work describes the conversion of mechanical energy to electricity, by periodically stretching rubber tubing and allowing it to relax. The rubber surface shows periodic and reversible electrostatic potential variations, in phase with the tubing length. The potential change depends on the elastomer used: silicone loses charge when stretched and becomes strongly negative when relaxed, whereas the stretched natural rubber is positive, becoming negative when relaxed. Every other elastomeric material that was tested also showed periodic potential but followed different patterns. When the motion stops, the potential on the resting samples decreases quickly to zero. The potential oscillation amplitude decreases when the relative humidity decreases from 65 to 27%, but it is negligible when the rubber tubing is previously swollen with water or paraffin oil. Elastomer charging patterns do not present the well-known characteristics of piezo-, flexo-,or triboelectricity, and they are discussed considering rubber rheology, wear, and surface properties, including the possibility of surface piezoelectricity. The following mechanism is suggested: rubber stretching provokes chemical and morphology changes in its surface, followed by a change in the surface concentration of H+ and OH- ions adsorbed along with water. The possibility of the occurrence of similar variations in other systems (both inert and biological) is discussed, together with its implications for energy scavenging from the environment. (AU)

FAPESP's process: 14/50906-9 - INCT 2014: in Functional Complex Materials
Grantee:Fernando Galembeck
Support Opportunities: Research Projects - Thematic Grants