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INCT 2014: in Functional Complex Materials

Grant number: 14/50906-9
Support type:Research Projects - Thematic Grants
Duration: July 01, 2017 - June 30, 2023
Field of knowledge:Physical Sciences and Mathematics - Chemistry
Cooperation agreement: CNPq - INCTs
Principal Investigator:Fernando Galembeck
Grantee:Fernando Galembeck
Home Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
Co-Principal Investigators:Eduardo Galembeck ; Érico Teixeira Neto ; Fernando Aparecido Sigoli ; Italo Odone Mazali ; Luciana Wasnievski da Silva de Luca Ramos ; Marcos Nogueira Eberlin ; Maria do Carmo Gonçalves ; Oswaldo Luiz Alves
Associated grant(s):17/26858-2 - Multi-user equipment approved in grant 14/50906-9 - cryotransfer holder for TEM, AP.EMU
Associated scholarship(s):19/14795-1 - Development of moisture, rainfall and water volume sensors for embedded environmental monitoring systems based on high performance conducting graphite, BP.IC
18/25140-3 - Environmental nanoscience - understanding the impacts of nanomaterial eco-corona formation on toxicity and working towards a Brazil-EU nanosafety research e-infrastructure, BE.PQ
18/07853-2 - Influence of the structural design of CeO2 porous nanorods decorated with bimetallic nanoparticles upon the optimization of water gas shift reaction, BP.MS


This new INCT proposal is being presented by the same team that has concluded the previous project. This new proposal contains great changes and preserves the main performance rules characteristic from the first term of the project, which determined a very positive feedback from the evaluators concerning to results on all project approaches. On the other side, based on results obtained, this proposal intends to present a more precisely focus and to answer to the big changes in science and technology which developed in the last six years since the previous proposal. The basis of this proposal is to guarantee an intense and high quality scientific activity coming from the R&D participant groups, validated by the interest raised by their results with partners, innovative companies? Professionals, the ones that make and implement public policies and with the public. The viability of conversion of new scientific knowledge on products and processes depends of the knowledge generated, the scientists? Familiarity with the economic and social context on which they actuate and of their capacity to dialogue with companies? Professionals, on all sectors of the economy. At the first INCT program, the INOMAT participants obtained scientific results that answered important scientific questions and opened new research frontiers. At the same time, they engaged on working with companies on several ways: consulting. R&D partnership projects, technology transfer, and by execution of complex technological services. The scientific and technological results obtained were plentiful and of high quality, placing INOMAT members on a distinguished position on the science frontiers and on the Brazilian innovation scenario. INOMAT members have been participating on products and processes development, working with professionals from different industrial sectors. Besides that, INOMAT presence on scientific and technological diffusion has offered the access to knowledge and to innovative high quality activities to a large number of people, including more than one million students from fundamental and high school. The main objective of this new proposal is to create new functional complex materials and to incorporate them to innovative products, as well as to create their respective production processes, together with the evaluation of the environmental and toxicological risks possibly associated with these materials. The activities linked to material creation will extend to all the fundamental, theoretical and experimental research work which leads to a new candidate material to become the basis for an innovative product, The incorporation of new materials to products results in radical innovations and also in incremental improvements which are possible due to the incorporation of new science to existing products, contributing to the sustainability of these products, of the manufacturing companies (of various origins and sizes) and of the Brazilian economic activity. The attention to the processes of production and transformation of materials, that was implicit on INOMAT previous project, turns to be the central focus on this new project, including advanced processes on micro and nanomanufacturing. Risk evaluation initiated previously on INOMAT and which has considerably grown during its execution, becomes an integrant part of this new proposal considering the consolidation and intensification of research about nanomaterials biofunctionalities, including nanotoxicology nanobiotechnology and applications on health and on environmental improvement. Themes: new materials, their production processes and their impact on human health and environment constitute a very broad universe. On this project, themes were delimited and defined by their expected results and their compatibility with the research lines of the groups that compose this INCT. The themes were chosen according to the opportunities they present, obeying the following criteria: 1) feasibility of leading to important scientific contributions, considering the current state of the art, the position of the group in charge by the research line on the international scenario, the material resources available and the interaction of the themes chosen with the other ones considered on this project; 2) feasibility of converting results obtained on new products and processes, considering the interactions among the research groups, entrepreneurs and new or existing companies, and also considering risks eventually created by new products and processes; 3) synergies among the different themes and research lines considered, which recommend their incorporation to the new project. The research themes are grouped as follow: i) synthesis and characterization of materials; ii) manufacturing and processing materials (including micro- and nanofabrication); iii) interactions with biosystems and applications in healthcare; iv) electroprocessing, electric charging of materials and tribology, wherein the detailed research plans are presented in an attachment to this online form. The level of detail of all documentation is consistent with the size limit of the attached file, as listed by the INCT call. The budget is shared among all allowed items. The biggest part is destined to different categories scholarships mainly for PDJ and includes scholarships for scientific and technological diffusion. An important amount was destined to the acquisition of for an Auger microprobe, great potential major equipment for materials characterization with nanometric spatial resolution and a large capacity of chemical speciation yet not available in Brazil. About one fifth of the budget was allocated for operational and small capital expenses of the research groups participating on the INCT. Less than a tenth part is reserved to fund scientific diffusion and management activities. (AU)

Scientific publications (35)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DE QUEIROZ, THIAGO B.; CABRERA-BAEZ, MICHAEL; MENEGASSO, PAULO; MARTINEZ, EDUARDO D.; GARCIA FLORES, ALI F.; RETTORI, CARLOS; URBANO, RICARDO R. Probing Surface Effects on alpha-NaYF4 Nanoparticles by Nuclear Magnetic Resonance. Journal of Physical Chemistry C, v. 124, n. 17, p. 9523-9535, APR 30 2020. Web of Science Citations: 0.
VELLO, TATIANA PARRA; STRAUSS, MATHIAS; RODRIGUES COSTA, CARLOS ALBERTO; CORREA, CATIA CRISPILHO; BOF BUFON, CARLOS CESAR. Deterministic control of surface mounted metal-organic framework growth orientation on metallic and insulating surfaces. Physical Chemistry Chemical Physics, v. 22, n. 10, p. 5839-5846, MAR 14 2020. Web of Science Citations: 0.
POZZOLI, GUILHERME L.; MERCES, LEANDRO; YASSITEPE, EMRE; DE MORAIS, VITORIA B.; DE CAMARGO, DAVI H. S.; BUFON, CARLOS C. BOF. Charge Transport and Gradient Doping in Nanostructured Polypyrrole Films for Applications in Photocurrent Generation. ACS APPLIED NANO MATERIALS, v. 3, n. 3, p. 3060-3070, MAR 2020. Web of Science Citations: 0.
NAWAZ, ALI; MERCES, LEANDRO; DE ANDRADE, DENISE M.; DE CAMARGO, DAVI H. S.; BOF BUFON, CARLOS C. Edge-driven nanomembrane-based vertical organic transistors showing a multi-sensing capability. NATURE COMMUNICATIONS, v. 11, n. 1 FEB 12 2020. Web of Science Citations: 0.
ALBANO, LUIZ G. S.; VELLO, TATIANA P.; DE CAMARGO, DAVI H. S.; DA SILVA, RICARDO M. L.; PADILHA, ANTONIO C. M.; FAZZIO, ADALBERTO; BUFON, CARLOS C. B. Ambipolar Resistive Switching in an Ultrathin Surface-Supported Metal-Organic Framework Vertical Heterojunction. Nano Letters, v. 20, n. 2, p. 1080-1088, FEB 2020. Web of Science Citations: 1.
POSSATO, BRUNA; HAUCH CHRISPIM, PEDRO BRANCO; ALVES, JACQUELINE QUERINO; BARBOSA RAMOS, LOYANNE CARLA; MARQUES, ELISE; DE OLIVEIRA, ARTHUR CAVALCANTE; DA SILVA, ROBERTO SANTANA; BARBOZA FORMIGA, ANDRE LUIZ; NIKOLAOU, SOFIA. Anticancer activity and DNA interaction of ruthenium acetate clusters bearing azanaphthalene ancillary ligands. Polyhedron, v. 176, JAN 15 2020. Web of Science Citations: 0.
GALICO, DIOGO A.; MARIN, RICCARDO; BRUNET, GABRIEL; ERRULAT, DYLAN; HEMMER, EVA; SIGOLI, FERNANDO A.; MOILANEN, JANI O.; MURUGESU, MURALEE. Triplet-State Position and Crystal-Field Tuning in Opto-Magnetic Lanthanide Complexes: Two Sides of the Same Coin. CHEMISTRY-A EUROPEAN JOURNAL, v. 25, n. 64, p. 14625-14637, NOV 18 2019. Web of Science Citations: 0.
DOS SANTOS PEREIRA, ANNA KARLA; NAKAHATA, DOUGLAS HIDEKI; MANZANO, CARLOS MARROTE; SIMONI, DEBORAH DE ALENCAR; PEREIRA, DOUGLAS HENRIQUE; LUSTRI, WILTON ROGERIO; BARBOZA FORMIGA, ANDRE LUIZ; CORBI, PEDRO PAULO. Synthesis, crystallographic studies, molecular modeling and in vitro biological studies of silver(I) complexes with aminoadamantane ligands. Polyhedron, v. 173, NOV 15 2019. Web of Science Citations: 1.
GUERRA, RENAN B.; HUAMANI, LUIS S. C.; TENORIO, JUAN C.; GUIMARAES, WILLIAN M.; BONACIN, JULIANO A.; BARBOZA FORMIGA, ANDRE LUIZ. Analysis of solvent-accessible voids and proton-coupled electron transfer of 2,6-bis(1H-imidazol-2-yl)pyridine and its hydrochloride. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, v. 75, n. 10, p. 1359+, OCT 2019. Web of Science Citations: 0.
PETIOTE, LANOUSSE; CABRAL, FILIPE M.; FORMIGA, ANDRE L. B.; MAZALI, ITALO O.; SIGOLI, FERNANDO A. A series of three isostructural 1D lanthanide coordination network based on 4,4 `,4 `'-((benzene-1,3,5-triyltris(methylene))tris(oxy))tribenzoate ligand: Synthesis, crystal structure and photophysical properties. Inorganica Chimica Acta, v. 494, p. 21-29, AUG 1 2019. Web of Science Citations: 1.
ERRULAT, DYLAN; MARIN, RICCARDO; GALICO, DIOGO A.; HARRIMAN, KATIE L. M.; PIALAT, AMELIE; GABIDULLIN, BULAT; IIKAWA, FERNANDO; COUTO, JR., ODILON D. D.; MOILANEN, JANI O.; HEMMER, EVA; SIGOLI, FERNANDO A.; MURUGESU, MURALEE. A Luminescent Thermometer Exhibiting Slow Relaxation of the Magnetization: Toward Self-Monitored Building Blocks for Next-Generation Optomagnetic Devices. ACS CENTRAL SCIENCE, v. 5, n. 7, p. 1187-1198, JUL 24 2019. Web of Science Citations: 6.
PAIVA, VICTOR T. C.; SANTOS, LEANDRA P.; DA SILVA, DOUGLAS S.; BURGO, THIAGO A. L.; GALEMBECK, FERNANDO. Conduction and Excess Charge in Silicate Glass/Air Interfaces. Langmuir, v. 35, n. 24, p. 7703-7712, JUN 18 2019. Web of Science Citations: 1.
RODRIGUES, EMILLE M.; GALICO, DIOGO A.; MAZALI, ITALO O.; SIGOLI, FERNANDO A. Self-supported films of poly(methyl methacrylate) (PMMA) containing Tm-III-doped upconverting core@shell nanoparticles as high sensitivity temperature optical probe. SENSORS AND ACTUATORS A-PHYSICAL, v. 291, p. 1-6, JUN 1 2019. Web of Science Citations: 0.
GALICO, D. A.; SOUZA, E. R.; MAZALI, I. O.; SIGOLI, F. A. High relative thermal sensitivity of luminescent molecular thermometer based on dinuclear [Eu-2(mba)(4)(mu-mba)(2)(H2O)(2)] complex: The role of inefficient intersystem crossing and LMCT. Journal of Luminescence, v. 210, p. 397-403, JUN 2019. Web of Science Citations: 0.
SANTOS, LEANDRA P.; DA SILVA, DOUGLAS S.; BATISTA, BRUNO C.; MOREIRA, KELLY S.; BURGO, THIAGO A. L.; GALEMBECK, FERNANDO. Mechanochemical transduction and hygroelectricity in periodically stretched rubber. Polymer, v. 171, p. 173-179, MAY 8 2019. Web of Science Citations: 2.
BRESSAN, LUCAS P.; ROBLES-NAJAR, JESSICA; ADAMO, CRISTINA B.; QUERO, REVERSON F.; COSTA, BRENDA M. C.; DE JESUS, DOSIL P.; DA SILVA, JOSE A. F. 3D-printed microfluidic device for the synthesis of silver and gold nanoparticles. Microchemical Journal, v. 146, p. 1083-1089, MAY 2019. Web of Science Citations: 2.
MATIAS, TIAGO A.; REIN, FRANCISCA N.; ROCHA, REGINALDO C.; BARBOZA FORMIGA, ANDRE LUIZ; TOMA, HENRIQUE E.; ARAKI, KOITI. Effects of a strong pi-accepting ancillary ligand on the water oxidation activity of weakly coupled binuclear ruthenium catalysts. DALTON TRANSACTIONS, v. 48, n. 9, p. 3009-3017, MAR 7 2019. Web of Science Citations: 0.
CARDOZO, CLAUDIA; MENDOZA, AXEL; FARIAS, GABRIELA; BARBOZA FORMIGA, ANDRE LUIZ; PENA, DEISY; FUENTES, FRANMERLY; ARCE, ALEJANDRO; OTERO, YOMAIRA. Synthesis of rhenacyclopentadienes and eta(2):eta(2)-diyne complexes from a labile dirhenium carbonyl and pi-conjugated 1,7-octadiynes: Structural and photophysical characterization. JOURNAL OF ORGANOMETALLIC CHEMISTRY, v. 881, p. 34-44, FEB 15 2019. Web of Science Citations: 0.
AMSTALDEN, MARIA-CECILIA KRAHENBUEHL; OLIVEIRA, JOSE DIOGO; STRAUSS, MATHIAS; MAZALI, ITALO ODONE; MACHADO, DAISY; THEISEN, THAIS HOLTZ; LANCELLOTTI, MARCELO. Analysis of the effects of mesoporous silica particles SBA-15 and SBA-16 in Streptococcus pneumoniae transformation process. Folia Microbiologica, v. 64, n. 1, p. 127-132, JAN 2019. Web of Science Citations: 0.
FERNANDO GALEMBECK; ANDRÉ GALEMBECK; LEANDRA P. DOS SANTOS. NPK: ESSENTIALS FOR SUSTAINABILITY. Química Nova, v. 42, n. 10, p. 1199-1207, Out. 2019. Web of Science Citations: 0.
FERNANDO GALEMBECK; THIAGO A.L. BURGO; DOUGLAS S. DA SILVA; LEANDRA P. SANTOS. Materials from renewable resources: new properties and functions. Anais da Academia Brasileira de Ciências, v. 91, n. 4, p. -, 2019. Web of Science Citations: 0.
GALICO, DIOGO ALVES; MAZALI, ITALO ODONE; SIGOLI, FERNANDO APARECIDO. A highly sensitive luminescent ratiometric thermometer based on europium(III) and terbium(III) benzoylacetonate complexes chemically bonded to ethyldiphenylphosphine oxide functionalized polydimethylsiloxane. NEW JOURNAL OF CHEMISTRY, v. 42, n. 23, p. 18541-18549, DEC 7 2018. Web of Science Citations: 9.
BIBI, NAHEED; RATIER DE ARRUDA, EDUARDO GUIMARAES; DOMINGO, ALEX; OLIVEIRA, ALINE ALVES; GALUPPO, CAROLINA; PHUNG, QUAN MANH; ORRA, NAIMA MOHAMMED; BERON, FANNY; PAESANO, JR., ANDREA; PIERLOOT, KRISTINE; BARBOZA FORMIGA, ANDRE LUIZ. Switching the Spin-Crossover Phenomenon by Ligand Design on Imidazole-Diazineiron(II) Complexes. Inorganic Chemistry, v. 57, n. 23, p. 14603-14616, DEC 3 2018. Web of Science Citations: 6.
CABRAL, F. M.; GALICO, D. A.; MAZALI, I. O.; SIGOLI, F. A. Crystal structure and temperature dependence of the photophysical properties of the [Eu(tta)(3)(pyphen)] complex. Inorganic Chemistry Communications, v. 98, p. 29-33, DEC 2018. Web of Science Citations: 4.
SANTOS, LEANDRA P.; CAMPO, YAN A. S.; DA SILVA, DOUGLAS S.; BURGO, THIAGO A. L.; GALEMBECK, FERNANDO. Rubber Surface Change and Static Charging under Periodic Stress. COLLOIDS AND INTERFACES, v. 2, n. 4 DEC 2018. Web of Science Citations: 3.
SANTINOM, ADRIANA; DA SILVA, MATEUS A.; VILLA, JAVIER E. L.; POPPI, RONEI J.; MAZALI, ITALO O.; DOS SANTOS, DIEGO P. Surface-enhanced Raman scattering (SERS) as probe of plasmonic near-field resonances. VIBRATIONAL SPECTROSCOPY, v. 99, p. 34-43, NOV 2018. Web of Science Citations: 4.
GASPAR, RAFAEL D. L.; FORTES, PAULA R.; MAZALI, ITALO O.; SIGOLI, FERNANDO A.; RAIMUNDO, IVO M. Optical Temperature Sensors Based On Europium(III) Beta-Diketonate Complexes Chemically Bonded To Functionalized Polydimethylsiloxane. CHEMISTRYSELECT, v. 3, n. 37, p. 10491-10501, OCT 9 2018. Web of Science Citations: 2.
RODRIGUES, E. M.; GALICO, D. A.; LEMES, M. A.; BETTINI, J.; NETO, E. T.; MAZALI, I. O.; MURUGESU, M.; SIGOLI, F. A. One pot synthesis and systematic study of the photophysical and magnetic properties and thermal sensing of alpha and beta-phase NaLnF(4) and beta-phase core@shell nanoparticles. NEW JOURNAL OF CHEMISTRY, v. 42, n. 16, p. 13393-13405, AUG 21 2018. Web of Science Citations: 6.
BIBI, NAHEED; GUERRA, RENAN BARRACH; SANTA CRUZ HUAMANI, LUIS ENRIQUE; BARBOZA FORMIGA, ANDRE LUIZ. Crystal structure, electrochemical and spectroscopic investigation of mer-tris[2-(1H-imidazol-2yl-kappa N-3)pyrimidine-kappa N-1]ruthenium(II) bis(hexafluoridophosphate) trihydrate. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, v. 74, n. 7, p. 874+, JUL 2018. Web of Science Citations: 2.
GALEMBECK, FERNANDO. From Aqueous Dispersions to Functional Materials: Capillarity and Electrostatic Adhesion. CHEMICAL RECORD, v. 18, n. 7-8, SI, p. 1054-1064, JUL 2018. Web of Science Citations: 1.
MOROZESK, MARIANA; FRANQUI, LIDIANE S.; MANSANO, ADRISLAINE S.; MARTINEZ, DIEGO STEFANI T.; FERNANDES, MARISA N. Interactions of oxidized multiwalled carbon nanotube with cadmium on zebrafish cell line: The influence of two co-exposure protocols on in vitro toxicity tests. AQUATIC TOXICOLOGY, v. 200, p. 136-147, JUL 2018. Web of Science Citations: 5.
GALEMBECK, FERNANDO. Synergy in food, energy and advanced materials production from biomass. Pure and Applied Chemistry, v. 90, n. 1, p. 109-119, JAN 2018. Web of Science Citations: 1.
BURGO, THIAGO A. L.; BATISTA, BRUNO C.; GALEMBECK, FERNANDO. Electricity on Rubber Surfaces: A New Energy Conversion Effect. ACS OMEGA, v. 2, n. 12, p. 8940-8947, DEC 2017. Web of Science Citations: 5.
SANTOS, ELIAS DE BARROS; MOHER, PALEAH; FERLIN, STACY; FOSTIER, ANNE HELENE; MAZALI, ITALO ODONE; TELMER, KEVIN; BROLO, ALEXANDRE GUIMARAES. Proof of concept for a passive sampler for monitoring of gaseous elemental mercury in artisanal gold mining. SCIENTIFIC REPORTS, v. 7, NOV 28 2017. Web of Science Citations: 2.

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Filed patent(s) as a result of this research project

Solicitação em análise e dentro do prazo legal de sigilo previsto na legislação BR1020170274721 - Universidade Estadual de Campinas (UNICAMP) . Solicitação em análise e dentro do prazo legal de sigilo previsto na legislação - December 2017, 19