| Full text | |
| Author(s): |
de Souza, Juliana M.
[1]
;
Brocksom, Timothy J.
[2, 1]
;
McQuade, D. Tyler
[3]
;
de Oliveira, Kleber T.
[1]
Total Authors: 4
|
| Affiliation: | [1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP - Brazil
[2] Univ Fed ABC, Ctr Ciencias Nat & Humanas, BR-09210580 Santo Andre, SP - Brazil
[3] Virginia Commonwealth Univ, Dept Chem & Life Sci Engn, Med Coll Virginia Campus, Richmond, VA 23284 - USA
Total Affiliations: 3
|
| Document type: | Journal article |
| Source: | Journal of Organic Chemistry; v. 83, n. 15, p. 7574-7585, AUG 3 2018. |
| Web of Science Citations: | 5 |
| Abstract | |
We have investigated the continuous flow photo oxidation of several conjugated dienes and subsequent rearrangement using a practical and safe continuous-flow homemade engineered setup. End-to-end approaches involving endoperoxidation, Kornblum-DeLaMare rearrangement, and additional rearrangements are comprehensively detailed with optimization, scope, and scale-up to obtain useful hydroxyenones, furans, and 1,4-dicarbonyl building blocks. (AU) | |
| FAPESP's process: | 11/13993-2 - Methodologies for the synthesis of bioactive terpenes |
| Grantee: | Timothy John Brocksom |
| Support Opportunities: | Regular Research Grants |
| FAPESP's process: | 13/07276-1 - CEPOF - Optics and Photonic Research Center |
| Grantee: | Vanderlei Salvador Bagnato |
| Support Opportunities: | Research Grants - Research, Innovation and Dissemination Centers - RIDC |
| FAPESP's process: | 18/00106-7 - Photocatalyzed Reactions by using porphyrins and continuous flow conditions: Arylations of heterocycles and activated olefins. |
| Grantee: | Kleber Thiago de Oliveira |
| Support Opportunities: | Regular Research Grants |
| FAPESP's process: | 15/21110-4 - Exploiting Photocatalyzed Reactions Under Continuous Flow Conditions by using Porphyrinoid Systems: (C-FlowPhotoChem) |
| Grantee: | Kleber Thiago de Oliveira |
| Support Opportunities: | Regular Research Grants |