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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Revisiting the Long-Range Perlin Effect in a Conformationally Constrained Oxocane

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Author(s):
Salome, Kahlil S. [1] ; Tormena, Claudio F. [1]
Total Authors: 2
Affiliation:
[1] Univ Campinas UNICAMP, Inst Chem, POB 6154, BR-13083970 Campinas, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of Organic Chemistry; v. 83, n. 17, p. 10501-10504, SEP 7 2018.
Web of Science Citations: 2
Abstract

Unusual (1)J(CH) values for an oxocane derivative were recently reported, highlighting the unexpected long-range Perlin effect for the (1)J(CH). According to our theoretical and experimental results listed in this paper, the previous published data cannot be supported. Moreover, when comparing the previously studied oxocane derivative with analogous molecules, we realized that the difference between J-couplings actually comes from the increase in the (1)J(C-Hax) instead of decreasing of (1)J(C-Heq), as suggested. (AU)

FAPESP's process: 15/08541-6 - Nuclear magnetic resonance spectroscopy: beyond molecular structure assignment
Grantee:Claudio Francisco Tormena
Support Opportunities: Research Projects - Thematic Grants