| Full text | |
| Author(s): |
Wang, Jie
[1]
;
Shang, Ming
[1]
;
Lundberg, Helena
[1]
;
Feu, Karla S.
[1]
;
Hecker, Scott J.
[2]
;
Qin, Tian
[1]
;
Blackmond, Donna G.
[1]
;
Baran, Phil S.
[1]
Total Authors: 8
|
| Affiliation: | [1] Scripps Res Inst TSRI, Dept Chem, North Torrey Pines Rd, La Jolla, CA 92037 - USA
[2] Medicines Co, 3013 Sci Pk Rd, San Diego, CA 92121 - USA
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | ACS CATALYSIS; v. 8, n. 10, p. 9537-9542, OCT 2018. |
| Web of Science Citations: | 32 |
| Abstract | |
A simple method for the conversion of carboxylic acids to boronic esters via redox-active esters (RAEs) is reported using copper catalysis. The scope of this transformation is broad, and compared with the known protocols available, it represents the most inexpensive, rapid, and operationally simple option. In addition to a full exploration of the scope, a kinetic study was performed to elucidate substrate and reagent concentration dependences. (AU) | |
| FAPESP's process: | 17/08128-7 - Total Synthesis of Eremantholide A and C |
| Grantee: | Karla Santos Feu |
| Support Opportunities: | Scholarships abroad - Research Internship - Post-doctor |